The complex with the highest number of unpaired electrons is:
So, the correct option is Option B.
For each complex, we check the oxidation state, electronic configuration, and nature of ligand.
In
Let the oxidation state of Co be .
So, Co is in oxidation state.
Cobalt has atomic number .
Here, acts as a strong field ligand for , so pairing takes place.
Electronic arrangement becomes:
Number of unpaired electrons .
In
Let oxidation state of Co be .
So again,
But is a weak field ligand, so pairing does not take place.
For octahedral high spin :
Number of unpaired electrons .
In
Let oxidation state of Ni be .
So,
is a weak field ligand. This complex is tetrahedral and has:
Number of unpaired electrons .
In
Let oxidation state of Ni be .
So,
is a strong field ligand, so pairing takes place. The complex is square planar.
Number of unpaired electrons .
Hence, the highest number of unpaired electrons is in:
Correct answer: Option B.