For each conversion, the number of Faradays required depends on the number of moles of electrons involved.
For A, mole of is converted to .
The oxidation half-reaction is:
So, moles of require .
Hence, mole of requires:
So, A-II.
For B, changes to .
Oxidation state of Mn in is .
Oxidation state of Mn in is .
So, change in oxidation state:
It gains electrons.
So, mole of requires:
So, B-IV.
For C, calcium is obtained from molten .
The cathode reaction is:
mole of Ca needs .
So, moles of Ca need:
So, C-I.
For D, FeO changes to .
In FeO, Fe is in oxidation state.
In , Fe is in oxidation state.
So, each Fe loses electron.
Hence, mole of FeO requires:
So, D-III.
The correct matching is:
Correct answer: Option A.