The weakest acid is
So, the correct option is A.
Carboxylic acids are acidic because they lose and form carboxylate ion:
The stability of the carboxylate ion decides the strength of the acid.
Groups that withdraw electrons, like , show the effect. They stabilize the carboxylate ion and increase acidity.
Groups that donate electrons, like alkyl groups, show the effect. They destabilize the carboxylate ion and decrease acidity.
Now compare the given acids:
has three chlorine atoms, so it is very strongly acidic.
has one chlorine atom, so it is more acidic than acetic acid.
has one methyl group, which decreases acidity slightly.
has a larger alkyl group, isopropyl group, which shows a stronger effect than methyl group. So it decreases acidity the most.
Hence, the weakest acid is: