The mean free path and the average speed of oxygen molecules at 300 K and 1 atm are m and 600 m/s, respectively. Find the frequency of its collisions.
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Official solved question paper for Joint Entrance Examination (Main). Review all 75 questions, official answer keys, and detailed step-by-step solutions below, or attempt online with timer and negative marking.
The mean free path and the average speed of oxygen molecules at 300 K and 1 atm are m and 600 m/s, respectively. Find the frequency of its collisions.
/s
/s
/s
/s
A small mirror of mass m is suspended by a massless thread of length . Then the small angle through which the thread will be deflected when a short pulse of laser of energy E falls normal on the mirror (c = speed of light in vacuum and g = acceleration due to gravity)
Two liquids A and B have and as contact angles in a capillary tube. If , then identify the correct statement:
K is negative, then liquid A and liquid B have convex meniscus
K is negative, then liquid A and liquid B have concave meniscus
K is negative, then liquid A has concave meniscus and liquid B has convex meniscus
K is zero, then liquid A has convex meniscus and liquid B has concave meniscus
Which of the following are correct expressions for torque acting on a body?
A.
B.
C.
D.
E.
( )
Choose the correct answer from the options given below :
B, D and E Only
C and D Only
B, C, D and E Only
A, B, D and E Only
In a Young's double slit experiment, the slits are separated by 0.2 mm. If the slits separation is increased to 0.4 mm, the percentage change of the fringe width is:
0%
100%
50%
25%
An alternating current is represented by the equation ampere. The RMS value of current and the frequency of the given alternating current are
A, 100 Hz
A, 100 Hz
100 A, 50 Hz
A, 50 Hz
Consider the sound wave travelling in ideal gases of He, , and . All the gases have the same ratio , where P is the pressure and is the density. The ratio of the speed of sound through the gases is given by
In an electromagnetic system, the quantity representing the ratio of electric flux and magnetic flux has dimension of , where value of 'Q' and 'R' are
When an object is placed 40 cm away from a spherical mirror an image of magnification is produced. To obtain an image with magnification of , the object is to be moved:
40 cm away from the mirror.
80 cm away from the mirror.
20 cm towards the mirror.
20 cm away from the mirror.
Given below are two statements:
Assertion A: In photoelectric effect, on increasing the intensity of incident light the stopping potential increases.
Reason R: Increase in intensity of light increases the rate of photoelectrons emitted, provided the frequency of incident light is greater than threshold frequency.
Choose the correct answer:
Both A and R are true but R is NOT the correct explanation of A
A is false but R is true
A is true but R is false
Both A and R are true and R is the correct explanation of A
If and represent the angular momentum and linear momentum respectively of a particle of mass 'm' having position vector . The direction of force is
Opposite to the direction of
Opposite to the direction of
Opposite to the direction of
Opposite to the direction of
A body of mass m is suspended by two strings making angles and with the horizontal ceiling with tensions and simultaneously. and are related by . The angles and are
, with
, with
, with
, with
Current passing through a wire as function of time is given as A. The charge that will flow through the wire from s to s is:
0.06 C
0.02 C
0.07 C
0.04 C
Given below are two statements:
Assertion A: The kinetic energy needed to project a body of mass m from earth surface to infinity is , where R is the radius of earth.
Reason R: The maximum potential energy of a body is zero when it is projected to infinity from earth surface.
In the light of the above statements, choose the correct answer from the option given below
A False but R is true
Both A and R are true and R is the correct explanation of A
A is true but R is false
Both A and R are true but R is NOT the correct explanation of A
The Boolean expression can be realised with which of the following gate configurations.
A. One 3-input AND gate, 3 NOT gates and one 2-input OR gate, One 2-input AND gate,
B. One 3-input AND gate, 1 NOT gate, One 2-input NOR gate and one 2-input OR gate
C. 3-input OR gate, 3 NOT gates and one 2-input AND gate
Choose the correct answer:
B, C Only
A, B Only
A, B, C Only
A, C Only
In an experiment with a closed organ pipe, it is filled with water by th of its volume. The frequency of the fundamental note will change by
25%
20%
%
%
Two simple pendulums having lengths and with negligible string mass undergo angular displacements and , from their mean positions, respectively. If the angular accelerations of both pendulums are same, then which expression is correct?
Two infinite identical charged sheets and a charged spherical body of charge density '' are arranged as shown in figure. Then the correct relation between the electrical fields at A, B, C and D points is:

Two small spherical balls of mass 10g each with charges and , are attached to two ends of very light rigid rod of length 20 cm. The arrangement is now placed near an infinite non-conducting charge sheet with uniform charge density such that length of rod makes an angle of 30° with electric field generated by charge sheet. Net torque acting on the rod is: (Take )
112 Nm
1.12 Nm
2.24 Nm
11.2 Nm
Considering the Bohr model of hydrogen like atoms, the ratio of the radius orbit of the electron in and is
A circular ring and a solid sphere having same radius roll down on an inclined plane from rest without slipping. The ratio of their velocities when reached at the bottom of the plane is where x = ________.
Two slabs with square cross section of different materials (1, 2) with equal sides () and thickness and such that and . Considering lower edges of these slabs are fixed to the floor, we apply equal shearing force on the narrow faces. The angle of deformation is . If the shear moduli of material 1 is N/m, then shear moduli of material 2 is , where value of x is ________.
Distance between object and its image (magnified by ) is 30 cm. The focal length of the mirror used is cm, where magnitude of value of x is ________.
Four capacitors each of capacitance are connected as shown in the figure. The capacitance between points A and B is ________ .

Conductor wire ABCDE with each arm 10 cm in length is placed in magnetic field of Tesla, perpendicular to its plane. When conductor is pulled towards right with constant velocity of 10 cm/s, induced emf between points A and E is ________ mV.

XY is the membrane/partition between two chambers 1 and 2 containing sugar solutions of concentration and () mol . For the reverse osmosis to take place identify the correct condition. (Here and are pressures applied on chamber 1 and 2)
(A) Membrane/Partition ; Cellophane,
(B) Membrane/Partition ; Porous.
(C) Membrane/Partition ; Parchment paper,
(D) Membrane/Partition : Cellophane,
Choose the correct answer from the options given below :
B and D only
A and D only
A and C only
C only
Let us consider a reversible reaction at temperature, T. In this reaction, both and were observed to have positive values. If the equilibrium temperature is , then the reaction becomes spontaneous at:
Which of the following molecules show/s paramagnetic behavior?
(A) (B) (C) (D) (E)
Choose the correct answer:
B only
A & C only
A & E only
A & D only
Aldol condensation is a popular and classical method to prepare -unsaturated carbonyl compounds. This reaction can be both intermolecular and intramolecular. Predict which one of the following is not a product of intramolecular aldol condensation?




One mole of an ideal gas expands isothermally and reversibly from 10 to 20 at 300 K. , q and work done in the process respectively are: (Given: , , , )
0, 21.84 kJ, -1.26 kJ
0, -17.18 kJ, 1.718 J
0, 21.84 kJ, 21,84 kJ
0, 1718 kJ, -1.718 kJ
Which one of the following complexes will have and B.M.?
For . for forward and backward reaction are 180 and 200 kJ mol respectively. If catalyst lowers for both reaction by 100 kJ mol. Which of the following statement is correct?
Catalyst does not alter the Gibbs energy change of a reaction.
Catalyst can cause non-spontaneous reactions to occur.
The enthalpy change for the reaction is +20 kJ mol.
The enthalpy change for the catalysed reaction is different from that of uncatalysed reaction.
Rate law for a reaction between A and B is given by . If concentration of A is doubled and concentration of B is halved from their initial value, the ratio of new rate of reaction to the initial rate of reaction is
Number of stereoisomers possible for the complexes, and are respectively (py = pyridine, ox = oxalate)
3 & 3
2 & 2
2 & 3
1 & 2
The major product (A) formed in the following reaction sequence is:
Nitrobenzene A





On charging the lead storage battery, the oxidation state of lead changes from to at the anode and from to at the cathode. The values of are respectively:
+4, +2, 0, +2
+2, 0, +2, +4
0, +2, +4, +2
+2, 0, 0, +4
Given below are two statements:
Statement I: Nitrogen forms oxides with +1 to +5 oxidation states due to the formation of bond with oxygen.
Statement II: Nitrogen does not form halides with +5 oxidation state due to the absence of d-orbital in it.
In the light of given statements, choose the correct answer from the options given below.
Statement I is true but Statement II is false
Both Statement I and Statement II are false
Statement I is false but Statement II is true
Both Statement I and Statement II are true
Benzene is treated with oleum to produce compound (X) which when further heated with molten sodium hydroxide followed by acidification produces compound (Y). The compound Y is treated with zinc metal to produce compound (Z). Identify the structure of compound (Z) from the following option.




Identify the pair of reactants that upon reaction, with elimination of HCl will give rise to the dipeptide Gly-Ala.




Given below are the pairs of group 13 elements showing their relation in terms of atomic radius. and . Identify the elements present in the incorrect pair and in that pair find out the element (X) that has higher ionic radius () than the other one. The atomic number of the element (X) is
31
49
13
81
An organic compound (X) with molecular formula is not readily oxidised. On reduction it gives which reacts with HBr to give a bromide (Z) which is converted to Grignard reagent. This Grignard reagent on reaction with (X) followed by hydrolysis gives 2,3-dimethylbutan-2-ol. Compounds (X), (Y) and (Z) respectively are:
, ,
, ,
, ,
, ,
Predict the major product of the following reaction sequence:





Given below are two statements:
Statement I: The dipole moment of is greater than .
Statement II: bond length of is greater than bond length of .
In the light of the above statements, choose the correct answer from the options given below
Statement I is false and Statement II is true
Both Statement I and Statement II are false
Statement I is true but Statement II is false
Both Statement I and Statement II are true
Pair of transition metal ions having the same number of unpaired electrons is:
,
,
,
,
Which one of the following about an electron occupying the 1s orbital in a hydrogen atom is incorrect? (Bohr's radius is represented by )
The probability density of finding the electron is maximum at the nucleus
The electron can be found at a distance from the nucleus
The 1s orbital is spherically symmetrical
The total energy of the electron is maximum when it is at a distance from the nucleus
In Dumas' method for estimation of nitrogen 1g of an organic compound gave 150 mL of nitrogen collected at 300K temperature and 900 mm Hg pressure. The percentage composition of nitrogen in the compound is ________ % (nearest integer). (Aqueous tension at 300 K = 15 mm Hg)
acts as an oxidising agent in acidic medium. 'X' is the difference between the oxidation states of Mn in reactant and product. 'Y' is the number of 'd' electrons present in the brown red precipitate formed at the end of the acetate ion test with neutral ferric chloride. The value of X + Y is ________.
Fortification of food with iron is done using . The mass in grams of the required to achieve 12 ppm of iron in 150 kg of wheat is ________ (Nearest Integer) [Given: Molar mass of Fe, S and O respectively are 56, 32 and 16 g mol]
The pH of a 0.01 M weak acid HX () is found to be 5. Now the acid solution is diluted with excess of water so that the pH of the solution changes to 6. The new concentration of the diluted weak acid is given as M. The value of x is ________ (nearest integer).
The total number of hydrogen bonds of a DNA-double Helix strand whose one strand has the following sequence of bases is ________.
5' - G - G - C - A - A - A - T - C - G - G - C - T - A - 3'
Let be defined as and . If the range of the function is , then is equal to
68
29
2
56
Consider the sets , , , and . The total number of one-one functions from the set D to the set C is:
15120
19320
17160
18290
Let and be the sets consisting of the first 2025 terms of two arithmetic progressions. Then is
3814
4027
3761
4003
For an integer , if the arithmetic mean of all coefficients in the binomial expansion of is 16, then the distance of the point from the line is:
The probability, of forming a 12 persons committee from 4 engineers, 2 doctors and 10 professors containing at least 3 engineers and at least 1 doctor, is:
Let the shortest distance between the lines and be . Then the positive value of is
42
46
48
40
If , where , then is equal to
18
20
19
17
Let be differentiable function such that for all . Then the area of the region bounded by and the coordinate axes is
2
Let A and B be two distinct points on the line . Both A and B are at a distance from the foot of perpendicular drawn from the point on the line L. If O is the origin, then is equal to:
49
47
21
62
Let be a continuous function satisfying and for all . If , then is equal to
540
385
420
215
upto 40 terms is equal to
43890
41880
33980
40870
In the expansion of , , if the ratio of term from the end to the term from the beginning is , then the value of is:
4060
1040
2300
4960
Considering the principal values of the inverse trigonometric functions, , , is equal to
Consider two vectors and , . The angle between them is given by . Let , where is parallel to and is perpendicular to . Then the value is equal to
14
10
Let the three sides of a triangle are on the lines , and . Then the distance of its orthocentre from the orthocentre of the triangle formed by the lines , and is
5
20
The value of is equal to
The length of the latus-rectum of the ellipse, whose foci are and and eccentricity is , is
Consider the equation , where is a natural number. Then the number of all distinct values of n, for which the given equation has integral roots, is equal to
7
8
6
5
A box contains 10 pens of which 3 are defective. A sample of 2 pens is drawn at random and let X denote the number of defective pens. Then the variance of X is
If , then the value of is:
If the area of the region is A, then 3A is equal to ________.
Let . If for some , , then the sum of the diagonal elements of the matrix is equal to ________.
Let , and . Then is equal to ________.
Let C be the circle , and be two ellipses whose centres lie at the origin and major axes lie on x-axis and y-axis respectively. Let the straight line touch the curves C, and at , and respectively. Given that P is the mid-point of the line segment QR and , the value of is equal to ________.
Let m and n be the number of points at which the function , , is not differentiable and not continuous, respectively. Then is equal to ________.