Official NTA Question PaperFull Solved Paper2025Morning Shift
JEE Main 2025 28th January Morning Shift Question Paper with Solutions
Official solved question paper for Joint Entrance Examination (Main). Review all 75 questions, official answer keys, and detailed step-by-step solutions below, or attempt online with timer and negative marking.
Q 1PhysicsSection B • Numericalunits and measurements
+4 / -1
A tiny metallic rectangular sheet has length and breadth of 5 mm and 2.5 mm , respectively. Using a specially designed screw gauge which has pitch of 0.75 mm and 15 divisions in the circular scale, you are asked to find the area of the sheet. In this measurement, the maximum fractional error will be 100x where x is _______ .
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 3
Official Correct Answer:3
Step-by-Step Solution:
Given, L = 5 mm, B = 2.5 mm
We know, least count of a screw gauge,
L.C.=No.ofdivisiononcircularscalePitchlength
⇒L.C.=150.75=0.05mm
We know, A=LB
By taking ln on both sides,
⇒lnA=lnL+lnB
by differentiating both sides,
⇒AdA=LdL+BdB
Here, dL=dB=0.05mm (L.C.)
So fractional error,
AdA=50.05+2.50.05
=1001+1002=1003=100x (given)
Hence, x=3.
Q 2PhysicsSection A • MCQwork power and energy
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A bead of mass ' m ' slides without friction on the wall of a vertical circular hoop of radius ' R ' as shown in figure. The bead moves under the combined action of gravity and a massless spring (k) attached to the bottom of the hoop. The equilibrium length of the spring is ' R '. If the bead is released from top of the hoop with (negligible) zero initial speed, velocity of bead, when the length of spring becomes ' R ', would be (spring constant is ' k ', g is accleration due to gravity)
A
2Rg+mkR2
B
3Rg+mkR2
C
2Rg+m4kR2
D
2gR+mkR2
Official Correct Answer:Option (B)
Step-by-Step Solution:
When mass is at position A,
Elongation of spring, x1=2R−R=R
(As equilibrium length of spring is R)
h1=2R
v1=0 (As the bead is released from zero initial speed)
When mass is at position B,
x2=R−R=0
h2=R/2,v2=v
So using energy conservation,
E1∘=Ef
⇒21kx12+21mv12+mgh1=21kx22+21mv22+mgh2
⇒21kR2+mg(2R)=21k(o)+21mv2+mg2R
⇒21kR2+2mgR−2mgR=21mv2
⇒21mv2=21kR2+23mgR
⇒v2=mkR2+3gR
⇒v=mkR2+3gR
Q 3PhysicsSection A • MCQproperties of matter
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In the experiment for measurement of viscosity ' η ' of given liquid with a ball having radius R, consider following statements.
A. Graph between terminal velocity V and R will be a parabola.
B. The terminal velocities of different diameter balls are constant for a given liquid.
C. Measurement of terminal velocity is dependent on the temperature.
D. This experiment can be utilized to assess the density of a given liquid.
E. If balls are dropped with some initial speed, the value of η will change.
Choose the correct answer from the options given below:
A
C, D and E Only
B
A, B and E Only
C
A, C and D Only
D
B, D and E Only
Official Correct Answer:Option (C)
Step-by-Step Solution:
We know, terminal velocity of a sphere of radius R in a liquid of viscosity η,
v=92ηR2(σ−ρ) .... (1)
where, σ = mass of density of sphere
ρ = density of liquid
we can see, v∝R2 (for constant η,σ & ρ)
Hence, graph between v and R is parabola.
As v depends on R so the terminal velocities of different diameter balls will be different.
We know, the viscosity of a liquid usually decreases as the temperature increases and v∝η1
So terminal velocity depends on the temperature. T↑⇒η↓⇒v↑
As the equation v=92vR2(σ−ρ) involves density of liquid ρ. So the experiment can be utilized to asses it.
From (1), η=92vR2(σ−ρ)
Here, η does not depend on initial speed of the sphere. Hence, option 3 is correct.
Q 4PhysicsSection B • Numericalrotational motion
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The moment of inertia of a solid disc rotating along its diameter is 2.5 times higher than the moment of inertia of a ring rotating in similar way. The moment of inertia of a solid sphere which has same radius as the disc and rotating in similar way, is n times higher than the moment of inertia of the given ring. Here, n= ________ Consider all the bodies have equal masses.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 4
Official Correct Answer:4
Step-by-Step Solution:
Given, I1=2.5I2 and I3=nI2
we know, I1=4MR12,I2=2MR22,I3=52MR32
⇒4MR12=2.52MR22⇒R12=5R22
Now, I3=nI2
⇒52MR12=n2MR22 (As R3=R1)
⇒52×5R22=2nR22⇒n=4
Q 5PhysicsSection A • MCQwaves
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Given below are two statements: one is labelled as AssertionA and the other is labelled as Reason R
Assertion A: A sound wave has higher speed in solids than gases.
Reason R: Gases have higher value of Bulk modulus than solids.
In the light of the above statements, choose the correct answer from the options given below
A
Both A and R are true and R is the correct explanation of A
B
A is false but R is true
C
A is true but R is false
D
Both A and R are true but R is NOT the correct explanation of A
Official Correct Answer:Option (C)
Step-by-Step Solution:
We know, speed of sound in a medium v=ρB where B = bulk modulus, ρ = density of the medium
Since, solids and liquids are much more difficult to compress than gases so they have much higher values of bulk modulus.
i.e., Bsolid>Bliquid>Bgas
Generally solids and liquids have higher mass densities (ρ) than gases. But corresponding increase in bulk modulus is much higher.
So, vsolid>vliquid>vgas
Hence, option 3 is correct.
Q 6PhysicsSection A • MCQray optics
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A thin prism P1 with angle 4∘ made of glass having refractive index 1.54 , is combined with another thin prism P2 made of glass having refractive index 1.72 to get dispersion without deviation. The angle of the prism P2 in degrees is
A
1.5
B
16/3
C
3
D
4
Official Correct Answer:Option (C)
Step-by-Step Solution:
We know, for thin prism,
μ=AA+δ
where, μ = refractive index
A = Angle of prism
δ = Angle of deviation
We can write, μA=A+δ
⇒δ=(μ−1)A
given, δnet=0
⇒(μ1−1)A1−(μ2−1)A2=0
⇒(1.54−1)4−(1.72−1)A2=0
⇒A2=7254×4⇒A2=3∘
Q 7PhysicsSection B • Numericalproperties of matter
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In a measurement, it is asked to find modulus of elasticity per unit torque applied on the system. The measured quantity has dimension of [MaLbTc]. If b=3, the value of c is _________.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 0
Two iron solid discs of negligible thickness have radii R1 and R2 and moment of intertia I1 and I2, respectively. For R2=2R1, the ratio of I1 and I2 would be 1/x, where x= _______ .
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 16
Official Correct Answer:16
Step-by-Step Solution:
Let surface mass density = σ
So, M1=σ×πR12
M2=σ×πR22=σπ(2R1)2 (As R2=2R1
=4σπR12
⇒M2=4M1
I2I1=2M2R222M1R12=(M2M1)(R2R1)2
⇒I2I1=(4M1M1)(2R1R1)2=41×41=161=x1
Hence, x=16
Q 9PhysicsSection A • MCQatoms and nuclei
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Choose the correct nuclear process from the below options [ p : proton, n : neutron, e−: electron, e+: positron, v: neutrino, vˉ: antineutrino]
A
n→p+e++v
B
n→p+e−+vˉ
C
n→p+e++vˉ
D
n→p+e−+v
Official Correct Answer:Option (B)
Step-by-Step Solution:
We know, theoretical equation for β− decay,
Hence, option 2 is correct.
Q 10PhysicsSection A • MCQelectrostatics
+4 / -1
Three infinitely long wires with linear charge density λ are placed along the x−axis,y−axis and z− axis respectively. Which of the following denotes an equipotential surface?
A
(x2+y2)(y2+z2)(z2+x2)= constant
B
xyz= constant
C
xy+yz+zx= constant
D
(x+y)(y+z)(z+x)= constant
Official Correct Answer:Option (A)
Step-by-Step Solution:
Electric field due to infinitely long wire
E=−r2kλr
We know, V=−∫E.dr
=−∫r−2kλr.dr
v=∫r2kλdr=2kλlnr+c
Net potential due to all wires,
V=v1+v2+v3
=2kλln(x2+y2)+2kλln(y2+z2)+2kλln(z2+x2)+c
for equipotential surface, v=c
⇒2kλ[ln(x2+y2.y2+z2.z2+x2)]=c
⇒(x2+y2).(y2+z2).(z2+x2)=c
⇒(x2+y2)(y2+z2)(z2+x2)=c
where, c = constant.
Q 11PhysicsSection A • MCQheat and thermodynamics
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A Carnot engine (E) is working between two temperatures 473 K and 273 K . In a new system two engines - engine E1 works between 473 K to 373 K and engine E2 works between 373 K to 273 K .
If η12,η1 and η2 are the efficiencies of the engines E,E1 and E2, respectively, then
A
η12=η1η2
B
η12=η1+η2
C
η12≥η1+η2
D
η12<η1+η2
Official Correct Answer:Option (D)
Step-by-Step Solution:
We know, efficiency of a carnot engine, η or e=1−THTC
where, TC = temperature of cold sink
TH = temperature of hot source
So, η12=1−473273=473200=0.423
η1=1−473373=473100=0.211
η2=1−373273=373100=0.268
Here, η1+η2=0.211+0.268=0.479>0.423
So, η12<η1+η2
Q 12PhysicsSection B • Numericalwave optics
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A double slit interference experiment performed with a light of wavelength 600 nm forms an interference fringe pattern on a screen with 10 th bright fringe having its centre at a distance of 10 mm from the central maximum. Distance of the centre of the same 10 th bright fringe from the central maximum when the source of light is replaced by another source of wavelength 660 nm would be ________ mm .
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 11
Official Correct Answer:11
Step-by-Step Solution:
In Young's double slit experiment, the distance of nth maxima from central maxima is given by,
Y=dnλD
Here, n,D & d are same for both the cases.
So, Y∝λ
⇒Y2Y1=λ2λ1⇒Y210=660600=111
⇒Y2=11mm.
Q 13PhysicsSection A • MCQcenter of mass
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The center of mass of a thin rectangular plate (fig - x ) with sides of length a and b, whose mass per unit area (σ) varies as σ=abσ0x (where σ0 is a constant), would be __________.
A
(32a,32b)
B
(32a,2b)
C
(31a,2b)
D
(2a,2b)
Official Correct Answer:Option (B)
Step-by-Step Solution:
σ=abσ0x
Let's consider a strip of infinitesimal width dx at x distance away from O.
As σ depends only on x i.e. it's constant for a specific value of x so centre of mass of the strip will be (x,2b).
Now, we know,
COM=(∫dm∫xdm,∫dm∫ydm)
=(∫σdA∫xσdA,∫σdA∫2bσdA)
=(∫abσ0xbdx∫xbdxabσ0x,∫σdA2b∫σdA)
For whole plate, x varies from o to a.
So, =COM=(aσ0∫0axdxaσ0∫0ax2dx,2b)
=(21[x2]0a31[x3]0a,2b)
=(32a2a3,2b)
⇒COM=(32a,2b)
Q 14PhysicsSection A • MCQelectrostatics
+4 / -1
A particle of mass ' m ' and charge ' q ' is fastened to one end ' A ' of a massless string having equilibrium length l, whose other end is fixed at point ' O '. The whole system is placed on a frictionless horizontal plane and is initially at rest. If uniform electric field is switched on along the direction as shown in figure, then the speed of the particle when it crosses the x-axis is
A
2mqEl
B
4mqEl
C
mqEl
D
m2qEl
Official Correct Answer:Option (C)
Step-by-Step Solution:
In ΔOMA,OAOM=cos60∘=21
⇒OM=2l (as OA=l)
MN=ON−OM=l−2l=2l
Using work − energy theorem,
Wall=Δk
⇒Wc=kf−ki
⇒qE2l=21mv2−o (As vi=o and w=FS)
⇒v2=mqEl
⇒v=mqEl
Q 15PhysicsSection A • MCQmagnetics
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Consider a long thin conducting wire carrying a uniform current I. A particle having mass "M" and charge " q " is released at a distance " a " from the wire with a speed v0 along the direction of current in the wire. The particle gets attracted to the wire due to magnetic force. The particle turns round when it is at distance x from the wire. The value of x is [ μ0 is vacuum permeability]
A
a[1−2qμ0Imvo]
B
ae−qμoI4πmvo
C
a[1−qmvμoI]
D
2a
Official Correct Answer:Option (B)
Step-by-Step Solution:
For A→B
V=−vxi+vyj
B=2πrμ0I(−k)
∵F=q(v×B)
So, F=2πrqμ0I[[(−vx)i+vyj]×(−k)]
=2πrqμ0I[vx(i×k)−vy(j×k)]
F=2πrqμ0I[−vxj−vyi]
⇒Fx=2πr−μ0Iqvy
⇒max=2πr−μ0Iqvy
⇒vxdrdvx=2πm−μ0Iqrvy
⇒vyvxdvx=2πm−μ0Iqrdr
Since, vx2+vy2=v02
⇒vy=v02−vx2
⇒∫0v0v02−vx2vxdvx=2πm−μ0Iq∫ax′rdr
Let v02−vx2=z2
⇒−2vxdvx=2zdz
when vx=0,z=v0
vx=v0,z=0
⇒∫v00zzdz=−2πmμ0Iq∫ax′rdr
⇒−v0=2πmμ0Iqln(ax′)
⇒ln(ax′)=−μ0Iq2πmv0
⇒x′=acμ0Iq−2πmv0 .... (1)
Now, for B→C
v=−vxi−vyj
B=2πrμ0I(−k)
F=q(v×B)=2πrqμ0I[vx(i×k)+vy(j×k)]
⇒F=2πrμ0Iq[−vxj+vyi]
⇒Fx=2πrμ0Iqvy
⇒vxdrdvx=2πmμ0Iqrvy
∫v00v02−vx2vxdvx=2πmμ0Iq∫x′xrdr
Let v02−vx2=z2
−2vxdvx=2zdz
vx=v0⇒z=0
vx=0⇒z=v0
⇒−∫0v0zzdz=2πmμ0Iq[lnr]x′x
⇒−v0=2πmμ0Iqln(x′x)
⇒x=x′e−μ0Iq2πmv0 .... (2)
From (1) & (2), x=ae−μ0Iq4πmv0
Q 16PhysicsSection A • MCQproperties of matter
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Consider following statements:
A. Surface tension arises due to extra energy of the molecules at the interior as compared to the molecules at the surface, of a liquid.
B. As the temperature of liquid rises, the coefficient of viscosity increases.
C. As the temperature of gas increases, the coefficient of viscosity increases
D. The onset of turbulence is determined by Reynold's number.
E. In a steady flow two stream lines never intersect.
Choose the correct answer from the options given below:
A
B, C, D Only
B
C, D, E Only
C
A, D, E Only
D
A, B, C Only
Official Correct Answer:Option (B)
Step-by-Step Solution:
(A) Surface tension arises due to the extra potential energy of the molecules at the surface of a liquid compared to the molecules in the interior.
(B) When a liquid is heated, the kinetic energy of it molecules increases, causing them to move more freely and overcome the intermolecular forces that contribute to viscosity, thus lowering it.
(C) Higher temperature in gas means faster moving molecules, resulting in more collisions and therefore an increase in viscosity.
(D) Reynold's number =VisousforceInertialforce
Re=μρVD,
v = velocity of flow
D = Diameter of pipe
If, Re<2000, flow is laminar flow
2000<Re<3000⇒ transition region
Re>3000⇒ turbulant flow.
(E) Tangent at a point to the streamline gives the direction of net velocity of the flow. If the two streamlines intersect each other. It signifies two directions of velocity which cannot be possible. Thus, two streamlines cannot intersect each other. Hence, option 2 is correct.
Q 17PhysicsSection A • MCQray optics
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A hemispherical vessel is completely filled with a liquid of refractive index μ. A small coin is kept at the lowest point (O) of the vessel as shown in figure. The minimum value of the refractive index of the liquid so that a person can see the coin from point E (at the level of the vessel) is _________.
A
23
B
23
C
3
D
2
Official Correct Answer:Option (D)
Step-by-Step Solution:
from ΔOCB,tanθ=OCCB=RR=1
⇒θ=45∘
We know, sinc=μ1
for minimum μ, sinc maximum ⇒ C maximum
Here, cmax=θ=45∘
So, μ=sin45∘1=211
⇒μ=2
Q 18PhysicsSection A • MCQelectronic devices
+4 / -1
Which of the following circuits has the same output as that of the given circuit?
A
B
C
D
Official Correct Answer:Option (A)
Step-by-Step Solution:
Y=A.B+A.B=A(B+B)=AI
⇒Y=A
1.
(As A.A=A
Hence, option 1 is correct.
Q 19PhysicsSection A • MCQcurrent electricity
+4 / -1
Find the equivalent resistance between two ends of the following circuit
A
r
B
6r
C
3r
D
9r
Official Correct Answer:Option (D)
Step-by-Step Solution:
Here, VA=VC & VB=VD
So,
So resistances are in parallel combination.
We know, Rp1=R11+R21+R31
⇒Rp1=r3+r3+r3=r9
⇒Rp=9r
Q 20PhysicsSection A • MCQcapacitor
+4 / -1
Two capacitors C1 and C2 are connected in parallel to a battery. Charge-time graph is shown below for the two capacitors. The energy stored with them are U1 and U2, respectively. Which of the given statements is true?
A
C2>C1,U2>U1
B
C1>C2,U1>U2
C
C2>C1,U2<U1
D
C1>C2,U1<U2
Official Correct Answer:Option (A)
Step-by-Step Solution:
Since parallel combination, so v is same for both
we know, q=cv
⇒q∝C (for constant v)
we can see in the graph,
at final state, q2>q1,
so c2>c1
Now, as u=21cv2⇒u∝c (for constant v)
⇒u2>u1
Hence, option 1 is correct.
Q 21PhysicsSection A • MCQdual nature of radiation
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A proton of mass ' mP ' has same energy as that of a photon of wavelength ' λ '. If the proton is moving at non-relativistic speed, then ratio of its de Broglie wavelength to the wavelength of photon is.
A
c1mpE
B
c1mp2E
C
2c1mpE
D
c12mpE
Official Correct Answer:Option (D)
Step-by-Step Solution:
We know, Eproton=λhc=E
Eproton=E (given)
⇒KEproton=21mPv2=E
So, λphotonλproton=hc/Eh/p=ph×hcE
=2mPEcE (As P=2mK.E.)
λphotonλproton=c12mPE
Q 22PhysicsSection A • MCQwork power and energy
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Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R
Assertion A: In a central force field, the work done is independent of the path chosen.
Reason R: Every force encountered in mechanics does not have an associated potential energy.
In the light of the above statements, choose the most appropriate answer from the options given below
A
A is false but R is true
B
Both A and R are true but R is NOT the correct explanation of A
C
A is true but R is false
D
Both A and R are true and R is the correct explanation of A
Official Correct Answer:Option (B)
Step-by-Step Solution:
In a central force field, the work done is independent of the path chosen, this is true because central forces are conservative forces. Every force encountered in mechanics does not have an associated potential energy this is also true because not all forces are conservative. Hence, option 2 is correct.
Q 23PhysicsSection A • MCQelectromagnetic waves
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Due to presence of an em-wave whose electric component is given by E=100sin(ωt−kx)NC−1 a cylinder of length 200 cm holds certain amount of em-energy inside it. If another cylinder of same length but half diameter than previous one holds same amount of em-energy, the magnitude of the electric field of the corresponding em-wave should be modified as
A
50sin(ωt−kx)NC−1
B
400sin(ωt−kx)NC−1
C
200sin(ωt−kx)NC−1
D
25sin(ωt−kx)NC−1
Official Correct Answer:Option (C)
Step-by-Step Solution:
We know,
Energy density =21ε0E2C
⇒VolumeEnergy=21ε0E2C
⇒Energy=21ε0Ec2xvol
Given that, (Energy)1=(Energy)2
⇒21ε0E12cxπR12L1=21ε0E22cxπR22L2
⇒E12R12L1=E22R22L1(asL1=L2)
⇒E12R12=E22R22
⇒E1R1=E2R2
⇒E1R1=E2(2R1)(AsR2=2R1)
⇒E2=2E1=2×100
⇒E2=200N/C
Hence, option (3) is correct.
Q 24PhysicsSection A • MCQcurrent electricity
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A wire of resistance R is bent into an equilateral triangle and an identical wire is bent into a square. The ratio of resistance between the two end points of an edge of the triangle to that of the square is
A
8/9
B
9/8
C
32/27
D
27/32
Official Correct Answer:Option (C)
Step-by-Step Solution:
We know, R=ρAl⇒R∝l
Side length of triangle =3l
Side length of square =4l
So,
⇒(Req)1=32R+3R32R×3R and (Req)2=43R+4R43R×4R
=92R2×3R3=92R and (Req)2=163R2−R=163R
Hence, (Req)2(Req)1=163R92R=2732
Q 25PhysicsSection A • MCQheat and thermodynamics
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For a particular ideal gas which of the following graphs represents the variation of mean squared velocity of the gas molecules with temperature?
A
B
C
D
Official Correct Answer:Option (C)
Step-by-Step Solution:
We know, for an ideal gas,
Vrms=M3RT
⇒Vms=Vrms2=M3RT
⇒Vms∝T
⇒Vms∝T
i.e. mean squared velocity is directly proportional to temperature.
⇒Vms=(M3R)T
by comparing it with y=mx (straight line)
Hence, option 3 is correct.
Q 26ChemistrySection B • Numericalthermodynamics
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The formation enthalpies, ΔHf⊖ for H(g) and O(g) are 220.0 and 250.0kJmol−1, respectively, at 298.15 K , and ΔHf⊖ for H2O(g) is −242.0kJmol−1 at the same temperature. The average bond enthalpy of the O−H bond in water at 298.15 K is _______ kJmol−1 (nearest integer).
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 466
Q 27ChemistrySection B • Numericalsome basic concepts of chemistry
+4 / -1
Quantitative analysis of an organic compound (X) shows following % composition.
C : 14.5%
Cl : 64.46%
H: 1.8 %
(Empirical formula mass of the compound (X) is _________ ×10−1
(Given molar mass in gmol−1 of C:12,H:1,O:16,Cl:35.5)
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 1655
Official Correct Answer:1655
Step-by-Step Solution:
Empiricial formula =C2H3Cl3O2 Mass =165.5 Mass =1655×10−1
Q 28ChemistrySection A • MCQthermodynamics
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Ice and water are placed in a closed container at a pressure of 1 atm and temperature 273.15 K . If pressure of the system is increased 2 times, keeping temperature constant, then identify correct observation from following
A
Liquid phase disappears completely.
B
The amount of ice decreases.
C
The solid phase (ice) disappears completely.
D
Volume of system increases .
Official Correct Answer:Option (C)
Step-by-Step Solution:
If pressure is made two time then mixture of ice and water will completely convert into water (liquid) form.
Q 29ChemistrySection B • Numericalsome basic concepts of chemistry
+4 / -1
The molarity of a 70% (mass/mass) aqueous solution of a monobasic acid (X) is _________ ×10−1 M (Nearest integer)
[Given: Density of aqueous solution of (X) is 1.25gmL−1
Molar mass of the acid is 70gmol−1 ]
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 125
Official Correct Answer:125
Step-by-Step Solution:
Assuming 100 gm solution contain 70 gm solute.
Volume of 100 gm solution will be 1.25100ml.
Molarity =100/1.2570/70×1000=12.5 or 125×10−1
Q 30ChemistrySection B • Numericalelectrochemistry
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Given below is the plot of the molar conductivity vs concentration for KCl in aqueous solution.
If, for the higher concentration of KCl solution, the resistance of the conductivity cell is 100Ω, then the resistance of the same cell with the dilute solution is ' x ' Ω
The value of x is _________ (Nearest integer)
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 150
Statement I: In the oxalic acid vs KMnO4 (in the presence of dil H2SO4 ) titration the solution needs to be heated initially to 60∘C, but no heating is required in Ferrous ammonium sulphate (FAS) vs KMnO4 titration (in the presence of dil H2SO4)
Statement II: In oxalic acid vs KMnO4 titration, the initial formation of MnSO4 takes place at high temperature, which then acts as catalyst for further reaction. In the case of FAS vs KMnO4, heating oxidizes Fe2+ into Fe3+ by oxygen of air and error may be introduced in the experiment.
In the light of the above statements, choose the correct answer from the options given below
A
Statement I is false but Statement II is true
B
Statement I is true but Statement II is false
C
Both Statement I and Statement II are true
D
Both Statement I and Statement II are false
Official Correct Answer:Option (C)
Step-by-Step Solution:
For the titration: Oxalic acid v/s KMnO4
2MnO4−+5(COO)22−+16H+→10CO2+2Mn2++8H2O
This reaction is slow at room temperature, but becomes fast at 60∘C. Manganese(II) ions catalyse the reaction; thus, the reaction is autocatalytic; once manganese(II) ions are formed, it becomes faster and faster.
The titration of FAS v/s KMnO4 do not require heating because at higher temperature the oxidation of Fe+2 to Fe+3 by atmospheric O2 will be prominent.
Q 34ChemistrySection A • MCQaldehydes ketones and carboxylic acids
+4 / -1
The compounds that produce CO2 with aqueous NaHCO3 solution are:
Choose the correct answer from the options given below:
A
A and C Only
B
A, B and E Only
C
A and B Only
D
A, C and D Only
Official Correct Answer:Option (D)
Step-by-Step Solution:
A,C,D produce CO2 with aqueous NaHCO3 solution.
A,C,D acids are stronger acid than H2CO3 (Carbonic acid)
Q 35ChemistrySection A • MCQchemical kinetics and nuclear chemistry
+4 / -1
For a given reaction R→P,t1/2 is related to [A]0 as given in table.
Given: log2=0.30
Which of the following is true?
A. The order of the reaction is 1/2.
B. If [A]0 is 1 M , then t1/2 is 20010min
C. The order of the reaction changes to 1 if the concentration of reactant changes from 0.100 M to 0.500 M.
D. t1/2 is 800 min for [A]0=1.6M
Choose the correct answer from the options given below:
A
A and C Only
B
A, B and D Only
C
A and B Only
D
C and D Only
Official Correct Answer:Option (B)
Step-by-Step Solution:
t1/2∝A0n−11(t1/2)2(t1/2)1=(A0)1n−1(A0)2n−1100200=(0.1000.025)n−12=(41)n−1⇒t1/2∝A0t1/2200=(1)1/2(0.1)1/2t1/2=20010 min n−1=−21n=21( order ) when A0=1M
*Ist order kinetics have t1/2 independent of their concentration. So upon changing the concentration t1/2 should not change for first order reaction.
t1/2200=(1.6)1/2(0.1)1/2 when A0=1.6Mt1/2=800min
Q 36ChemistrySection A • MCQatomic structure
+4 / -1
In a multielectron atom, which of the following orbitals described by three quantum numbers will have same energy in absence of electric and magnetic fields?
A. n=1,l=0,m1=0
B. n=2,l=0,m1=0
C. n=2,I=1,m1=1
D. n=3,l=2,m1=1
E. n=3,l=2,m1=0
Choose the correct answer from the options given below:
A
B and C Only
B
C and D Only
C
A and B Only
D
D and E Only
Official Correct Answer:Option (D)
Step-by-Step Solution:
orbital
A:n=1,ℓ=0,mℓ=0
1s
B:n=2,ℓ=0,mℓ=0
2s
C:n=3,ℓ=1,mℓ=1
3p
D:n=3,ℓ=2,mℓ=1
3d
E:n=3,ℓ=2,mℓ=0
3d
In absence of electric and magnetic fields, all orbitals of 3d are degenerate
Q 37ChemistrySection A • MCQperiodic classification of elements
+4 / -1
The incorrect decreasing order of atomic radii is
A
Si>P>Cl>F
B
Mg>Al>C>O
C
Al>B>N>F
D
Be>Mg>Al>Si
Official Correct Answer:Option (D)
Step-by-Step Solution:
Correct order of atomic radii : Be<Mg>Al>Si
Q 38ChemistrySection A • MCQperiodic classification of elements
+4 / -1
Consider the following elements In,Tl,Al,Pb,Sn and Ge .
The most stable oxidation states of elements with highest and lowest first ionisation enthalpies, respectively, are
A
+4 and +1
B
+4 and +3
C
+1 and +4
D
+2 and +3
Official Correct Answer:Option (A)
Step-by-Step Solution:
Among Al,In,Tl,Ge,Sn,Pb, the metal having highest IE1 is Ge and lowest IE1 is In.
Most stable oxidation state of Ge is +4 and In is +3 .
Q 39ChemistrySection A • MCQbiomolecules
+4 / -1
Given below are two statements:
Statement I : D-glucose pentaacetate reacts with 2,4 -dinitrophenylhydrazine
Statement II : Starch, on heating with concentrated sulfuric acid at 100∘C and 2−3atmosphere pressure produces glucose.
In the light of the above statements, choose the correct answer from the options given below
A
Statement I is true but Statement II is false
B
Both Statement I and Statement II are true
C
Statement I is false but Statement II is true
D
Both Statement I and Statement II are false
Official Correct Answer:Option (C)
Step-by-Step Solution:
Statement I: D-glucose pentaacetate does not react with 2,4-dinitrophenylhydrazine (DNPH). This is because D-glucose pentaacetate is a derivative where all the hydroxyl groups of D-glucose have been acetylated, eliminating the presence of a free aldehyde group. Since DNPH reacts specifically with free aldehyde or ketone groups to form hydrazones, D-glucose pentaacetate does not participate in this reaction.
Statement II: Starch, when heated with concentrated sulfuric acid at 100°C and under a pressure of 2-3 atmospheres, undergoes hydrolysis. This process breaks the glycosidic linkages in starch, resulting in the production of glucose. This statement is accurate as starch is a polysaccharide composed of glucose units and can be broken down into glucose under these conditions.
The correct information based on the statements is:
Statement I is false, as D-glucose pentaacetate does not react with 2,4-dinitrophenylhydrazine due to the absence of a free aldehyde group.
Statement II is true, as the described method effectively converts starch into glucose.
Q 40ChemistrySection A • MCQaldehydes ketones and carboxylic acids
+4 / -1
Both acetaldehyde and acetone (individually) undergo which of the following reactions?
A. Iodoform Reaction
B. Cannizaro Reaction
C. Aldol Condensation
D. Tollen's Test
E. Clemmensen Reduction
Choose the correct answer from the options given below:
A
C and E Only
B
A, B and D Only
C
A, C and E Only
D
B, C and D Only
Official Correct Answer:Option (C)
Step-by-Step Solution:
S.No.
Name of Reaction
Acetaldehyde Image
Acetone Image
1
Iodoform reaction
⊕ve
⊕ve
2
Cannizaro
⊖ve
⊖ve
3
Aldol reaction
⊕ve
⊕ve
4
Tollen's test
⊕ve
⊖ve
5
Clemmensen reduction
⊕ve
⊕ve
Ans. (2) A, C and E only.
Q 41ChemistrySection A • MCQd and f block elements
+4 / -1
The metal ion whose electronic configuration is not affected by the nature of the ligand and which gives a violet colour in non-luminous flame under hot condition in borax bead test is
A
Cr3+
B
Ti3+
C
Ni2+
D
Mn2+
Official Correct Answer:Option (C)
Step-by-Step Solution:
Ni+2 gives violet coloured bead in non-luminous flame under hot conditions. Ni+2 has d8 configuration which does not depend on nature of ligand present in octahedral complex.
Ni+2:t2g6eg2
Q 42ChemistrySection A • MCQredox reactions
+4 / -1
Which of the following oxidation reactions are carried out by both K2Cr2O7 and KMnO4 in acidic medium?
A. Γ−→I2
B. S2−→S
C. Fe2+→Fe3+
D. I−→IO3−
E. S2O32−→SO42−
Choose the correct answer from the options given below :
A
A, B and C Only
B
C, D and E Only
C
B, C and D Only
D
A, D and E Only
Official Correct Answer:Option (A)
Step-by-Step Solution:
I−H+I2I−OH−IO3−
S−2H+SS2O32−OH−SO42−
Fe+2⟶Fe+3S2O32−H+S↓+SO42−
Q 43ChemistrySection A • MCQalcohols phenols and ethers
+4 / -1
Given below are two statements :
Statement I :
Statement II : In , intramolecular substitution takes place first by involving lone pair of electrons on nitrogen.
In the light of the above statements, choose the most appropriate answer from the options given below
A
Both Statement I and Statement II are correct
B
Statement I is incorrect but Statement II is correct
C
Both Statement I and Statement II are incorrect
D
Statement I is correct but Statement II is incorrect
Official Correct Answer:Option (A)
Step-by-Step Solution:
Rate of (a) is faster than (b) because of its intramolecular substitution.
Q 44ChemistrySection A • MCQredox reactions
+4 / -1
Match the List - I with List - II
List - I (Redox Reaction)
List - II (Type of Redox Reaction)
(A)
CH4(g)+2O2(g)ΔCO2(g)+2H2O(l)
(I)
Disproportionation reaction
(B)
2NaH(s)Δ2Na(s)+H2(g)
(II)
Combination reaction
(C)
V2O5(s)+5Ca(s)Δ2V(s)+5CaO(s)
(III)
Decomposition reaction
(D)
2H2O2(aq)⟶Δ2H2O(l)+O2(g)
(IV)
Displacement reaction
Choose the correct answer from the options given below:
A
A-III, B-IV, C-I, D-II
B
A-IV, B-I, C-II, D-III
C
A-II, B-III, C-I, D-IV
D
A-II, B-III, C-IV, D-I
Official Correct Answer:Option (D)
Step-by-Step Solution:
(A) Combustion of hydrocarbon
(B) Decomposition into gaseous product.
(C) Displacement of ' V ' by ' Ca ' atom.
(D) Disproportionation of H2O2−1 into O−2 and O∘ oxidation states.
Q 45ChemistrySection A • MCQionic equilibrium
+4 / -1
A weak acid HA has degree of dissociation x . Which option gives the correct expression of ( pH - pKa)?
Q 46ChemistrySection A • MCQchemical bonding and molecular structure
+4 / -1
Consider ' n ' is the number of lone pair of electrons present in the equatorial position of the most stable structure of ClF3. The ions from the following with ' n ' number of unpaired electrons are
A. V3+
B. Ti3+
C. Cu2+
D. Ni2+
E. Ti2+
Choose the correct answer from the options given below:
Q 48ChemistrySection A • MCQbasics of organic chemistry
+4 / -1
The correct order of stability of following carbocations is :
A
A > B > C > D
B
C > B > A > D
C
B > C > A > D
D
C > A > B > D
Official Correct Answer:Option (D)
Step-by-Step Solution:
Solution :-
C is aromatic due to ⊕ve charge hence it is most stable
A have more resonance structure
B have less resonance structure
D have only hyper conjugation
Consider First Aromaticity > Resonance > Hyper conjugation
Ans. D <B<A<C
Q 49ChemistrySection A • MCQsolutions
+4 / -1
What is the freezing point depression constant of a solvent, 50 g of which contain 1 g non volatile solute (molar mass 256gmol−1 ) and the decrease in freezing point is 0.40 K ?
A
4.43Kkgmol−1
B
3.72Kkgmol−1
C
5.12Kkgmol−1
D
1.86Kkgmol−1
Official Correct Answer:Option (C)
Step-by-Step Solution:
ΔTf0.4Kb=Kb⋅m=Kb50×10−32561=5.12Kkg/mol
Q 50ChemistrySection B • Numericalaldehydes ketones and carboxylic acids
+4 / -1
A molecule ("P") on treatment with acid undergoes rearrangement and gives ("Q"). ("Q") on ozonolysis followed by reflux under alkaline condition gives (" R "). The structure of (" R ") is given below.
The structure of ("P") is
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
Note : In question about molecule "P" is not clarified, weather it is alcohol or alkene and as in question language rearrangement product is asking hence according to question language ans. is either (2) or (4). As alkene also undergoes rearrangement in presence of acid but option (2) also fulfil all conditions.
Q 51MathematicsSection B • Numericalmatrices and determinants
+4 / -1
Let M denote the set of all real matrices of order 3×3 and let S={−3,−2,−1,1,2}. Let
S1={A=[aij]∈M:A=AT and aij∈S,∀i,j},S2={A=[aij]∈M:A=−AT and aij∈S,∀i,j},S3={A=[aij]∈M:a11+a22+a33=0 and aij∈S,∀i,j}.
If n(S1∪S2∪S3)=125α, then α equls __________.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 1613
Official Correct Answer:1613
Step-by-Step Solution:
a11a21a31a12a22a32a13a23a33
No. of elements in S1:A=AT⇒53×53
No. of elements in S2:A=−AT⇒0
since no zero in S2
No. of elements in S3⇒
a11+a22+a33=0⇒(1,2,−3)⇒31 or (1,1,−2)⇒3 or (−1,−1,2)⇒3⎭⎬⎫⇒12×56
Let the equation of the circle, which touches x-axis at the point (a,0),a>0 and cuts off an intercept of length b on y−axis be x2+y2−αx+βy+γ=0. If the circle lies below x−axis, then the ordered pair (2a,b2) is equal to
∣z1−z2∣=∣z2∣⇒ΔABO is isosceles with angles 6π,6π&32π
Q 54MathematicsSection A • MCQsets and relations
+4 / -1
The relation R={(x,y):x,y∈Z and x+y is even } is:
A
reflexive and transitive but not symmetric
B
reflexive and symmetric but not transitive
C
an equivalence relation
D
symmetric and transitive but not reflexive
Official Correct Answer:Option (C)
Step-by-Step Solution:
R={(x,y):x,y∈z and x+y is even }
reflexive x+x=2x even
symmetric of x+y is even, then (y+x) is also even
transitive of x+y is even &y+z is even then x+z is also even
So, relation is an equivalence relation.
Q 55MathematicsSection A • MCQdefinite integration
+4 / -1
If ∫−2π2π(1+ex)96x2cos2xdx=π(απ2+β),α,β∈Z, then (α+β)2 equals
A
196
B
100
C
64
D
144
Official Correct Answer:Option (B)
Step-by-Step Solution:
\int_\limits{-\frac{\pi}{2}}^{\frac{\pi}{2}} \frac{96 x^2 \cos ^2 x}{\left(1+e^x\right)} d x \quad (Apply King Property)
∫02π96x2cos2x=48∫02πx2(1+cos2x)dx48[(3x3)0π/2+∫02πx12cosII2xdx]⇒ On solving π(2π2−12)⇒α=2,β=−12⇒(α+β)2=100
Q 56MathematicsSection B • Numericalvector algebra
+4 / -1
Let a=i^+j^+k^,b=2i^+2j^+k^ and d=a×b. If c is a vector such that a⋅c=∣c∣, ∣c−2a∣2=8 and the angle between d and c is 4π, then ∣10−3b⋅c∣+∣d×c∣2 is equal to _________.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 6
Let ABCD be a trapezium whose vertices lie on the parabola y2=4x. Let the sides AD and BC of the trapezium be parallel to y-axis. If the diagonal AC is of length 425 and it passes through the point (1,0), then the area of ABCD is
A
875
B
8125
C
225
D
475
Official Correct Answer:Option (D)
Step-by-Step Solution:
A(at12,2at1)&C(t12a,−t12a) Length AC=a(t1+t11)2=425,t1+t11=±25⇒t1=2 or 21,A(21,1),D(41,−1),B(4,4),C(4,−4) So, area of trapezium =21(8+2)(4−41)=475
Q 60MathematicsSection A • MCQprobability
+4 / -1
Three defective oranges are accidently mixed with seven good ones and on looking at them, it is not possible to differentiate between them. Two oranges are drawn at random from the lot. If x denote the number of defective oranges, then the variance of x is
A
26/75
B
14/25
C
18/25
D
28/75
Official Correct Answer:Option (D)
Step-by-Step Solution:
Probability distribution xix=0x=1x=2pi10C27C2=904210C27C1×3C1=904210C23C2=906
Q 64MathematicsSection A • MCQquadratic equation and inequalities
+4 / -1
The sum, of the squares of all the roots of the equation x2+∣2x−3∣−4=0, is
A
6(2−2)
B
3(3−2)
C
3(2−2)
D
6(3−2)
Official Correct Answer:Option (A)
Step-by-Step Solution:
x2+∣2x−3∣−4=0 Case I:x≥23x2+2x−3−4=0x2+2x−7=0x=22−1
Case II:x<23x2+3−2x−4=0x2−2x−1=0x=1−2
Sum of squares =(22−1)2+(1−2)2=8−42+1+1−22+2=6(2−2)∴(3)
Q 65MathematicsSection B • Numericalbinomial theorem
+4 / -1
If α=1+r=1∑6(−3)r−112C2r−1,
then the distance of the point (12,3) from the line αx−3y+1=0 is ________.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 5
Official Correct Answer:5
Step-by-Step Solution:
ααα=1+r=1∑6(−1)r−112C2r−13r−1=1+r=1∑612C2r−13i(3i)2t−1i= iota, let 3i=x=1+3i1(12C1x+12C3x3+….12C11x11)=1+3i1(2(1+3i)12−(1−3i)12)=1+3i1(2(−2ω2)12−(2ω)12)=1 so distance of (12,3) from x−3y+1=0 is 212−3+1=5
Q 66MathematicsSection A • MCQsequences and series
+4 / -1
Let ⟨an⟩ be a sequence such that a0=0,a1=21 and 2an+2=5an+1−3an,n=0,1,2,3,…. Then k=1∑100ak is equal to
In (1) Put y=−x⇒f(0)=f(x)+f(−x)+1+72x2−1=2(3a+2)x2+2b+1+72x2
−1=(2(3a+2)+72)x2+1−2⇒6a+4+72=0a=−75
So f(x)=−71x2−43x−1
⇒∣f(x)∣=2814x2+21x+28
Now, 28∑i=15∣f(i)∣=28(∣f(1)∣+∣f(2)∣+…+∣f(5)∣)
28⋅281⋅675=675
Q 68MathematicsSection A • MCQprobability
+4 / -1
Two number k1 and k2 are randomly chosen from the set of natural numbers. Then, the probability that the value of ik1+ik2,(i=−1) is non-zero, equals
A
43
B
21
C
41
D
32
Official Correct Answer:Option (A)
Step-by-Step Solution:
ik1+ik2=0ik1→4 option for i,−1,−i,1
Total cases ⇒4×4=16
Unfovourble cases ⇒ik1+ik2=0
⎩⎨⎧1,−1−1,1i,−i−i,i⎭⎬⎫
4 Cases ⇒ Probability =1616−4=43
Q 69MathematicsSection A • MCQpermutations and combinations
+4 / -1
Let nCr−1=28,nCr=56 and nCr+1=70. Let A(4cost,4sint),B(2sint,−2cost) and C(3r−n,r2−n−1) be the vertices of a triangle ABC, where t is a parameter. If (3x−1)2+(3y)2=α, is the locus of the centroid of triangle ABC , then α equals
Q 70MathematicsSection A • MCQpermutations and combinations
+4 / -1
The number of different 5 digit numbers greater than 50000 that can be formed using the digits 0 , 1,2,3,4,5,6,7, such that the sum of their first and last digits should not be more than 8 , is
A
5720
B
5719
C
4608
D
4607
Official Correct Answer:Option (D)
Step-by-Step Solution:
Case I 5−−−0
Case II 5−−−1
556667230120
Case IX 7−−−1
9×(8×8×8)=4608 but 50000 is not included, so total numbers 4608−1=4607
Q 71MathematicsSection A • MCQdifferential equations
+4 / -1
Let for some function y=f(x),∫0xtf(t)dt=x2f(x),x>0 and f(2)=3. Then f(6) is equal to
A
1
B
6
C
2
D
3
Official Correct Answer:Option (A)
Step-by-Step Solution:
∫0xtf(t)dt=x2+(x),x>0 Diff. both side w.r. to xxf(x)=x2f′(x)+2xf(x)−xf(x)=x2f′(x)∫f(x)f′(x)dx=∫x−1dxlogdf(x)=−logx+logcf(x)=xcf(2)=3⇒3=2c⇒c=6f(x)=x6f(6)=1∴(1)
Q 72MathematicsSection A • MCQarea under the curves
+4 / -1
The area (in sq. units) of the region {(x,y):0≤y≤2∣x∣+1,0≤y≤x2+1,∣x∣≤3} is
A
332
B
364
C
317
D
380
Official Correct Answer:Option (B)
Step-by-Step Solution:
Area =2[∫02(x2+1)dx+∫23(2x+1)dx]⇒364∴(2)
Q 73MathematicsSection A • MCQapplication of derivatives
+4 / -1
The sum of all local minimum values of the function
∴ Local minimum values at A&B37−7211⇒72168−11⇒72157
Q 74MathematicsSection B • Numericalellipse
+4 / -1
Let E1:9x2+4y2=1 be an ellipse. Ellipses Ei 's are constructed such that their centres and eccentricities are same as that of E1, and the length of minor axis of Ei is the length of major axis of Ei+1(i≥1). If Ai is the area of the ellipse Ei, then π5(i=1∑∞Ai), is equal to _______.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 54
Q 75MathematicsSection B • Numericallimits continuity and differentiability
+4 / -1
Let f(x)=⎩⎨⎧3x,min{1+x+[x],x+2[x]},5,x<00≤x≤2x>2
where [.] denotes greatest integer function. If α and β are the number of points, where f is not continuous and is not differentiable, respectively, then α+β equals _______ .
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 5