Official NTA Question PaperFull Solved Paper2014Morning Shift
JEE Main 2014 12th April Morning Shift Question Paper with Solutions
Official solved question paper for Joint Entrance Examination (Main). Review all 90 questions, official answer keys, and detailed step-by-step solutions below, or attempt online with timer and negative marking.
From the following combinations of physical constants (expressed through their usual symbols) the only combination, that would have the same value in different systems of units, is:
A
2πε02ch
B
2πε0Gme2e2
C
c2μ0ε0⋅he2G
D
ce22πμ0ε0⋅Gh
Official Correct Answer:Option (B)
Step-by-Step Solution:
To determine which combination of physical constants has the same value in different systems of units, we need to find the dimensionless quantity. A dimensionless quantity has dimensions of mass, length, time, and current all raised to the power zero, i.e., [M0L0T0I0]. We will perform dimensional analysis on each option using the following dimensions of the fundamental constants:
Speed of light, c: [LT−1]
Planck's constant, h: [ML2T−1] (since energy E=hν and ν has [T−1])
Elementary charge, e: [IT] (charge = current × time)
Gravitational constant, G: [M−1L3T−2] (from Newton's law of gravitation)
Permittivity of free space, ε0: [M−1L−3T4I2] (from Coulomb's law: F=4πε01r2q1q2)
Permeability of free space, μ0: [MLT−2I−2] (from the force between parallel currents)
Note that μ0ε0=c21, so the dimensions of μ0ε0 are [T2L−2].
Also, constants like 2π are dimensionless and do not affect the dimensional analysis.
Now, we evaluate each option:
Option A:2πε02ch
Dimensions of numerator ch:
[LT−1]×[ML2T−1]=[ML3T−2]
Dimensions of denominator ε02:
[M−1L−3T4I2]2=[M−2L−6T8I4]
Dimensions of fraction:
[M−2L−6T8I4][ML3T−2]=M1−(−2)L3−(−6)T−2−8I−4=[M3L9T−10I−4]
This is not dimensionless.
Option B:2πε0Gme2e2
Dimensions of numerator e2:
[IT]2=[I2T2]
Dimensions of denominator ε0Gme2:
ε0:[M−1L−3T4I2],
G:[M−1L3T−2],
me2:[M]2=[M2],
so ε0×G×me2=[M−1L−3T4I2]×[M−1L3T−2]×[M2]=M−1−1+2L−3+3T4−2I2=[M0L0T2I2]
Dimensions of fraction:
[T2I2][I2T2]=[I2−2T2−2]=[M0L0T0I0]
This is dimensionless.
Option C:c2μ0ε0⋅he2G
First part: c2μ0ε0,
dimensions of μ0ε0: [T2L−2],
dimensions of c2: [L2T−2],
so fraction: [L2T−2][T2L−2]=T2−(−2)L−2−2=[T4L−4]
Second part: he2G,
dimensions of G: [M−1L3T−2],
dimensions of he2: h:[ML2T−1], e2:[I2T2], so he2=[ML2T−1]×[I2T2]=[ML2TI2],
fraction: [ML2TI2][M−1L3T−2]=M−1−1L3−2T−2−1I−2=[M−2LT−3I−2]
Note that μ0ε0=c21=c1, so the expression simplifies to ce22π⋅c1⋅Gh=c2e22π⋅Gh
Dimensions of denominator c2e2:
c2:[L2T−2], e2:[I2T2], so c2e2=[L2T−2]×[I2T2]=[L2I2]
Dimensions of Gh:
h:[ML2T−1], G:[M−1L3T−2], so fraction: [M−1L3T−2][ML2T−1]=M1−(−1)L2−3T−1−(−2)=[M2L−1T]
Product: [L2I2]1×[M2L−1T]=[M2L−3TI−2]
This is not dimensionless.
Only Option B is dimensionless and thus has the same value in different systems of units. Hence, the correct answer is Option B.
Q 2PhysicsSection A • MCQmotion in a straight line
+4 / -1
A person climbs up a stalled escalator in 60 s. If standing on the same but escalator running with constant velocity he takes 40 s. How much time is taken by the person to walk up the moving escalator?
A
37 s
B
27 s
C
24 s
D
45 s
Official Correct Answer:Option (C)
Step-by-Step Solution:
Let the length of the escalator be d. We need to find the time taken by the person to walk up the moving escalator.
First, when the escalator is stalled (not moving), the person climbs the entire length d in 60 seconds. So, the speed of the person relative to the escalator is vp=60d.
Second, when the person stands still on the moving escalator, it takes 40 seconds to cover the same distance d. So, the speed of the escalator is ve=40d.
Now, when the person walks up the moving escalator, both the person and the escalator are moving in the same upward direction. Therefore, the effective speed of the person relative to the ground is the sum of their individual speeds: vp+ve.
The time t taken to cover distance d at this combined speed is:
t=vp+ved
Substitute the expressions for vp and ve:
t=60d+40dd
Factor d out of the denominator:
t=d(601+401)d
Cancel d from numerator and denominator (since d=0):
t=601+4011
Now, compute the denominator. Find the sum 601+401. The least common multiple of 60 and 40 is 120. Rewrite each fraction:
601=1202,401=1203
Add them:
1202+1203=1205=241
So,
t=2411=24 seconds
Hence, the time taken by the person to walk up the moving escalator is 24 seconds. Comparing with the options, Option C is 24 s.
So, the answer is 24 seconds.
Q 3PhysicsSection A • MCQwork energy and power
+4 / -1
A bullet of mass 4 g is fired horizontally with a speed of 300 m/s into 0.8 kg block of wood at rest on a table. If the coefficient of friction between the block and the table is 0.3, how far will the block slide approximately?
A
0.19 m
B
0.379 m
C
0.569 m
D
0.758 m
Official Correct Answer:Option (B)
Step-by-Step Solution:
First, we have a bullet of mass 4 g fired horizontally at 300 m/s into a wooden block of mass 0.8 kg at rest. The bullet embeds into the block, making this an inelastic collision. We use conservation of momentum to find the velocity of the block-bullet system right after the collision.
Convert the bullet's mass to kilograms: mass of bullet, mb=4 g = 0.004 kg. Mass of block, mbl=0.8 kg. Initial velocity of bullet, ub=300 m/s. Initial velocity of block, ubl=0 m/s. Let v be the common velocity after collision.
Conservation of momentum:
mbub+mblubl=(mb+mbl)v
Substitute the values:
(0.004×300)+(0.8×0)=(0.004+0.8)v
1.2+0=0.804v
1.2=0.804v
Solve for v:
v=0.8041.2=8041200
Simplify the fraction by dividing numerator and denominator by 12:
804÷121200÷12=67100
So, v=67100 m/s ≈ 1.4925 m/s.
Now, the block-bullet system slides on the table with initial velocity v=67100 m/s and comes to a stop due to friction. The coefficient of friction is μ=0.3. The friction force opposes the motion.
The normal force N equals the weight of the system since the table is horizontal. Total mass, m=mb+mbl=0.004+0.8=0.804 kg. Using g=9.8 m/s², weight = mg=0.804×9.8 N.
Friction force, f=μN=μmg=0.3×0.804×9.8.
By Newton's second law, friction causes deceleration a:
f=ma
0.3×0.804×9.8=0.804a
The mass 0.804 cancels out:
a=0.3×9.8=2.94 m/s2
So, deceleration a=−2.94 m/s² (negative indicates opposition to motion).
We need to find the distance s the block slides before stopping. Initial velocity u=v=67100 m/s, final velocity vf=0 m/s, acceleration a=−2.94 m/s².
Use the equation of motion:
vf2=u2+2as
Substitute the values:
02=(67100)2+2×(−2.94)×s
0=448910000−5.88s
Solve for s:
5.88s=448910000
s=4489×5.8810000
Convert 5.88 to a fraction: 5.88=100588=25147.
s=448910000×5.881=448910000×14725
s=4489×14710000×25
Calculate numerator: 10000×25=250000.
Calculate denominator: 4489×147. Break it down:
4489×100=448900
4489×40=179560
4489×7=31423
Add them: 448900+179560=628460, then 628460+31423=659883.
So,
s=659883250000≈0.37878 m
Approximately, s≈0.379 m.
Comparing with the options, 0.379 m corresponds to Option B.
Hence, the correct answer is Option B.
Q 4PhysicsSection A • MCQwork energy and power
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A spring of unstretched length l has a mass m with one end fixed to a rigid support. Assuming spring to be made of a uniform wire, the kinetic energy possessed by it if its free end is pulled with uniform velocity v is:
A
21mv2
B
mv2
C
31mv2
D
61mv2
Official Correct Answer:Option (D)
Step-by-Step Solution:
A spring of unstretched length l and mass m is fixed at one end and pulled at the free end with a uniform velocity v. The spring is made of a uniform wire, so its mass per unit length is constant. We need to find the kinetic energy of the entire spring.
Since the spring is uniform, its mass distribution is linear along its unstretched length. Let the mass per unit length be μ=lm. Consider a small element of the spring at a distance s from the fixed end in the unstretched state. The mass of this element is dm=μds=lmds.
When the free end is pulled with uniform velocity v, the spring stretches uniformly. The displacement of a point originally at distance s from the fixed end is proportional to s. If the displacement of the free end (at s=l) is δ(t)=vt (since velocity is constant), then the displacement of a point at s is u(s,t)=lsδ(t)=lsvt.
The velocity of this point is the time derivative of displacement: v(s)=∂t∂u=lsv.
The kinetic energy of the small element is dK=21dm[v(s)]2. Substituting dm and v(s):
dK=21(lmds)(lsv)2
Simplify the expression:
dK=21⋅lm⋅l2s2v2ds=21⋅l3mv2s2ds
To find the total kinetic energy, integrate dK over the entire length of the spring from s=0 to s=l:
K=∫0ldK=∫0l21⋅l3mv2s2ds
Factor out the constants:
K=21⋅l3mv2∫0ls2ds
Evaluate the integral:
∫0ls2ds=[3s3]0l=3l3
Substitute back:
K=21⋅l3mv2⋅3l3=21⋅3mv2=61mv2
Hence, the kinetic energy possessed by the spring is 61mv2. Comparing with the options, this corresponds to Option D.
So, the answer is Option D.
Q 5PhysicsSection A • MCQlaws of motion
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Three masses m, 2m and 3m are moving in the x-y plane with speeds 3u, 2u and u respectively as shown in the figure. The three masses collide at the same point at P and stick together. The velocity of the resulting mass will be:
A
12u(i^+3j^)
B
12u(i^−3j^)
C
12u(−i^+3j^)
D
12u(−i^−3j^)
Official Correct Answer:Option (D)
Step-by-Step Solution:
Mass m: v1=3ui^
Mass 2m: v2=2u(−cos60∘i^−sin60∘j^)=−ui^−u3j^
Mass 3m: v3=u(−cos60∘i^+sin60∘j^)=−2ui^+2u3j^
A particle of mass 1 unit is moving in a circular path of radius a, with a constant velocity v as shown in the figure. The centre of circle is marked by 'C'. The angular momentum from the origin O can be written as:
A
va(1+cos2θ)
B
va(1+cosθ)
C
vacos2θ
D
va
Official Correct Answer:Option (A)
Step-by-Step Solution:
If the position vector from the origin makes an angle θ with the x-axis, the angle subtended at the center C(a,0) is 2θ due to circle geometry.
The velocity v is tangential to the circle, and the perpendicular distance from the origin to this tangent is r⊥=a+acos2θ.
L=mvr⊥ (with m=1): L=va(1+cos2θ)
Q 7PhysicsSection A • MCQgravitation
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Two hypothetical planets of masses m1 and m2 are at rest when they are infinite distance apart. Because of the gravitational force they move towards each other along the line joining their centres. What is their speed when their separation is 'd'? (Speed of m1 is v1 and that of m2 is v2)
A
v1=v2
B
v1=m2d(m1+m2)2G, v2=m1d(m1+m2)2G
C
v1=m1d(m1+m2)2G, v2=m2d(m1+m2)2G
D
v1=m2m12G, v2=m2m22G
Official Correct Answer:Option (B)
Step-by-Step Solution:
Since no external force acts on the two-planet system, the net linear momentum is conserved. Initially, both planets are at rest at infinite separation, so the total initial momentum is zero.
From conservation of linear momentum, m1v1−m2v2=0, v2=m2m1v1…(1)
As gravity is a conservative force, the total mechanical energy of the system remains constant.
Total initial energy at r=∞ is Ei=0.
At separation d, the total energy is Ef=Kf+Uf=21m1v12+21m2v22−dGm1m2
Equating Ei=Ef: 21m1v12+21m2v22=dGm1m2
Substituting the value of v2 from equation (1):
21m1v12+21m2(m2m1v1)2=dGm1m2
21m1v12(1+m2m1)=dGm1m2
21m1v12(m2m1+m2)=dGm1m2
v12=d(m1+m2)2Gm22
v1=m2d(m1+m2)2G
By symmetry or by substituting v1 back into equation (1):
v2=m1d(m1+m2)2G
Q 8PhysicsSection A • MCQproperties of matter
+4 / -1
Steel ruptures when a shear of 3.5×108 N m−2 is applied. The force needed to punch a 1 cm diameter hole in a steel sheet 0.3 cm thick is nearly:
A
1.4×104 N
B
2.7×104 N
C
3.3×104 N
D
1.1×104 N
Official Correct Answer:Option (C)
Step-by-Step Solution:
The steel ruptures when the shear stress reaches 3.5×108 N m−2. To punch a hole, we need to apply a force that causes this shear stress over the area being sheared.
When punching a hole of diameter 1 cm in a sheet of thickness 0.3 cm, the sheared area is the lateral surface area of the cylindrical hole. This area is calculated as the circumference of the hole multiplied by the thickness of the sheet.
First, convert all measurements to meters for consistency. The diameter is 1 cm, which is 0.01 m, so the radius r is half of that: r=20.01=0.005 m. The thickness t is 0.3 cm, which is 0.003 m.
The circumference of the hole is 2πr. Therefore, the sheared area A is:
A=2πrt
Substituting the values:
A=2×π×0.005×0.003
First, multiply the numerical parts:
0.005×0.003=0.000015
Then:
A=2×π×0.000015=0.00003π
Using π≈3.1416,
A≈0.00003×3.1416=0.000094248 m2
In scientific notation, A≈9.4248×10−5 m2.
The shear stress τ is related to the force F and area A by:
τ=AF
At rupture, τ=3.5×108 N m−2. Solving for F:
F=τ×A
Substituting the values:
F=(3.5×108)×(9.4248×10−5)
First, multiply the coefficients:
3.5×9.4248=32.9868
Then multiply the powers of 10:
108×10−5=103
So:
F≈32.9868×103=32986.8 N
Which is 3.29868×104 N. Rounding to two significant figures, as in the options, gives approximately 3.3×104 N.
Alternatively, using exact values:
A=2πrt=2×π×0.005×0.003=2×π×1.5×10−5=3π×10−5 m2
Then:
F=(3.5×108)×(3π×10−5)=3.5×3×π×108−5=10.5π×103=10500π N
With π≈3.1416,
F≈10500×3.1416=32986.8 N≈3.3×104 N
Comparing with the options, 3.3×104 N corresponds to option C.
Hence, the correct answer is Option C.
Q 9PhysicsSection A • MCQproperties of matter
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A cylindrical vessel of cross-section A contains water to a height h. There is a hole in the bottom of radius 'a'. The time in which it will be emptied is:
A
πa22Agh
B
πa22Agh
C
πa222Agh
D
2πa2Agh
Official Correct Answer:Option (B)
Step-by-Step Solution:
We are given a cylindrical vessel with cross-sectional area A filled with water to a height h. There is a hole at the bottom with radius a, so the area of the hole is πa2. We need to find the time taken for the vessel to empty completely.
According to Torricelli's theorem, the speed of efflux v of water through the hole is given by v=2gh, where g is the acceleration due to gravity and h is the height of water above the hole at any instant.
The volume flow rate of water through the hole is the product of the area of the hole and the speed of efflux. Since the volume is decreasing, we write:
dtdV=−(πa2)2gh
Here, V is the volume of water in the vessel. For a cylinder, V=Ah. Differentiating both sides with respect to time t:
dtdV=Adtdh
Setting the two expressions for dtdV equal:
Adtdh=−πa22gh
We can rearrange this equation to separate the variables h and t. First, express 2gh as 2gh:
Adtdh=−πa22gh
Bring terms involving h to one side and t to the other:
Adh=−πa22ghdt
Divide both sides by h and rearrange:
dt=−πa22gAhdh
Simplify the right side:
dt=−πa22gAh−1/2dh
To find the total time T for the vessel to empty, integrate both sides. At t=0, h=h (initial height). At t=T, h=0 (vessel empty). So:
∫0Tdt=−πa22gA∫h0h−1/2dh
The left side integrates to T. For the right side, reversing the limits of integration removes the negative sign:
T=πa22gA∫0hh−1/2dh
Now, integrate h−1/2:
∫h−1/2dh=1/2h1/2=2h1/2
Evaluate the definite integral:
∫0hh−1/2dh=[2h]0h=2h−20=2h
Substitute back:
T=πa22gA×2h
Simplify:
T=πa22g2Ah
Express h and 2g in terms of gh:
T=πa22A⋅2gh=πa22A2gh
Now, 2gh=21gh, so:
T=πa22A⋅21gh=2πa22Agh
Simplify 22:
22=22×22=222=2
Thus:
T=πa22Agh
Comparing with the options, this matches option B.
Hence, the correct answer is Option B.
Q 10PhysicsSection A • MCQproperties of matter
+4 / -1
Two soap bubbles coalesce to form a single bubble. If V is the subsequent change in volume of contained air and S change in total surface area, T is the surface tension and P atmospheric pressure, then which of the following relation is correct?
A
4PV + 3ST = 0
B
3PV + 4ST = 0
C
2PV + 3ST = 0
D
3PV + 2ST = 0
Official Correct Answer:Option (B)
Step-by-Step Solution:
To solve this problem, we need to find the correct relation between the change in volume (V), change in surface area (S), surface tension (T), and atmospheric pressure (P) when two soap bubbles coalesce into one. We start by recalling the physics of soap bubbles.
A soap bubble has an excess pressure inside due to surface tension. Since a soap bubble has two surfaces (inner and outer), the excess pressure is given by ΔP=r4T, where r is the radius. Therefore, the pressure inside a bubble is Pinside=P+r4T, with P being atmospheric pressure.
Let the two initial bubbles have radii r1 and r2. After coalescing, they form a single bubble of radius r. The air inside is conserved, and assuming constant temperature, we use the ideal gas law. The number of moles of air is conserved.
For the first bubble, the number of moles is:
n1=RT(P+r14T)⋅34πr13
For the second bubble:
n2=RT(P+r24T)⋅34πr23
The total initial moles are:
n1+n2=RT34π[(P+r14T)r13+(P+r24T)r23]
Simplifying the terms inside the brackets:
(P+r14T)r13=Pr13+4Tr12
(P+r24T)r23=Pr23+4Tr22
So:
n1+n2=RT34π[Pr13+4Tr12+Pr23+4Tr22]
For the final single bubble:
n=RT(P+r4T)⋅34πr3=RT34π[Pr3+4Tr2]
Since moles are conserved, n1+n2=n:
Pr13+4Tr12+Pr23+4Tr22=Pr3+4Tr2
Rearranging:
Pr13+Pr23−Pr3+4Tr12+4Tr22−4Tr2=0
P(r13+r23−r3)+4T(r12+r22−r2)=0...(1)
Now, define the changes. The change in volume of contained air, V, is the final volume minus the initial total volume. The volume of a bubble is 34πr3, so:
V=34πr3−(34πr13+34πr23)=34π(r3−r13−r23)
Solving for r3−r13−r23:
r3−r13−r23=4π3V...(2)
The change in total surface area, S, is defined as the final surface area minus the initial total surface area. For a soap bubble, the surface area is often considered as the area of one surface (e.g., the outer surface), which is 4πr2. Thus:
Initial total surface area = 4πr12+4πr22=4π(r12+r22)
Final surface area = 4πr2
So:
S=4πr2−4π(r12+r22)=4π(r2−r12−r22)
Solving for r2−r12−r22:
r2−r12−r22=4πS...(3)
Note that equation (1) contains r13+r23−r3 and r12+r22−r2. Using equations (2) and (3):
r13+r23−r3=−(r3−r13−r23)=−4π3V
r12+r22−r2=−(r2−r12−r22)=−4πS
Substitute these into equation (1):
P(−4π3V)+4T(−4πS)=0
−4π3PV−4π4TS=0
Simplify the second term:
−4π3PV−πTS=0
Multiply both sides by −1:
4π3PV+πTS=0
To eliminate denominators, multiply both sides by 4π:
4π⋅4π3PV+4π⋅πTS=0
3PV+4TS=0
Since TS=ST, we write:
3PV+4ST=0
This matches option B.
Hence, the correct answer is Option B.
Q 11PhysicsSection A • MCQthermal properties of matter
+4 / -1
Hot water cools from 60°C to 50°C in the first 10 minutes and to 42°C in the next 10 minutes. The temperature of the surroundings is:
A
25°C
B
10°C
C
15°C
D
20°C
Official Correct Answer:Option (B)
Step-by-Step Solution:
According to Newton's law of cooling, the rate of cooling is proportional to the difference between the temperature of the body and the surroundings. The formula for the average rate of cooling over a time interval is given by:
tT1−T2=k(2T1+T2−Ts)
where T1 is the initial temperature, T2 is the final temperature, t is the time interval, Ts is the temperature of the surroundings, and k is a constant.
For the first 10 minutes:
Initial temperature T1=60∘C
Final temperature T2=50∘C
Time t=10 minutes
Rate of cooling 1060−50=1∘C per minute
Average temperature 260+50=55∘C
So, the equation becomes:
1=k(55−Ts)(Equation 1)
For the next 10 minutes:
Initial temperature T1=50∘C
Final temperature T2=42∘C
Time t=10 minutes
Rate of cooling 1050−42=0.8∘C per minute
Average temperature 250+42=46∘C
So, the equation becomes:
0.8=k(46−Ts)(Equation 2)
We now have two equations:
1=k(55−Ts)
0.8=k(46−Ts)
To solve for Ts, divide Equation 1 by Equation 2:
Bring all terms involving Ts to one side and constants to the other. Add 1.25Ts to both sides:
57.5=55−Ts+1.25Ts
57.5=55+0.25Ts
Subtract 55 from both sides:
57.5−55=0.25Ts
2.5=0.25Ts
Solve for Ts:
Ts=0.252.5=0.25×1002.5×100=25250=10
So, the temperature of the surroundings is 10∘C.
Verification: Substitute Ts=10 into Equation 1:
1=k(55−10)=k×45⟹k=451
Now substitute into Equation 2:
0.8=451×(46−10)=451×36=4536=54=0.8
This matches, confirming the solution.
Hence, the correct answer is Option B.
Q 12PhysicsSection A • MCQheat and thermodynamics
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A Carnot engine absorbs 1000 J of heat energy from a reservoir at 127°C and rejects 600 J of heat energy during each cycle. The efficiency of engine and temperature of sink will be:
A
20% and −43°C
B
40% and −33°C
C
50% and −20°C
D
70% and −10°C
Official Correct Answer:Option (B)
Step-by-Step Solution:
A Carnot engine absorbs 1000 J of heat energy from a reservoir at 127°C and rejects 600 J of heat energy during each cycle. We need to find the efficiency of the engine and the temperature of the sink.
First, recall that the efficiency (η) of any heat engine is given by the ratio of the work done to the heat absorbed. The work done by the engine is the difference between the heat absorbed and the heat rejected. So:
Heat absorbed, Q1=1000J
Heat rejected, Q2=600J
Work done, W=Q1−Q2=1000−600=400J
Efficiency, η=Q1W=1000400
Simplifying the fraction: 1000400=0.4
To express as a percentage: 0.4×100=40%
So, the efficiency is 40%.
For a Carnot engine, efficiency is also related to the absolute temperatures of the source and sink. The formula is:
η=1−T1T2
where T1 is the absolute temperature of the source (in Kelvin) and T2 is the absolute temperature of the sink (in Kelvin).
The source temperature is given as 127°C. Convert this to Kelvin by adding 273:
T1=127+273=400K
We know η=40%=0.4 (in decimal form). Substitute into the formula:
0.4=1−400T2
Solve for T2:
Rearrange: 400T2=1−0.4
400T2=0.6
Multiply both sides by 400: T2=0.6×400
T2=240K
Convert T2 from Kelvin to Celsius by subtracting 273:
T2(in °C)=240−273=−33°C
Therefore, the efficiency is 40% and the temperature of the sink is -33°C.
Comparing with the options:
A. 20% and -43°C
B. 40% and -33°C
C. 50% and -20°C
D. 70% and -10°C
Option B matches our calculated values.
Hence, the correct answer is Option B.
Q 13PhysicsSection A • MCQkinetic theory of gases
+4 / -1
At room temperature a diatomic gas is found to have an r.m.s. speed of 1930 ms−1. The gas is:
A
H2
B
Cl2
C
O2
D
F2
Official Correct Answer:Option (A)
Step-by-Step Solution:
The root mean square (r.m.s.) speed of a gas is given by the formula:
vrms=M3RT
where R is the universal gas constant, T is the temperature in Kelvin, and M is the molar mass of the gas in kg/mol. The r.m.s. speed is provided as 1930 m/s, and room temperature is taken as 300 K. The gas constant R is 8.314 J/(mol·K), which is equivalent to 8.314 kg·m²/(s²·mol·K) since 1 J = 1 kg·m²/s².
To identify the gas, we rearrange the formula to solve for the molar mass M:
To convert to grams per mole (g/mol), multiply by 1000:
M=0.0020088×1000=2.0088 g/mol
The molar mass is approximately 2.009 g/mol. Comparing this with the molar masses of the given diatomic gases:
Hydrogen (H₂): 2 g/mol
Chlorine (Cl₂): 71 g/mol (since Cl is 35.5 g/mol)
Oxygen (O₂): 32 g/mol
Fluorine (F₂): 38 g/mol
The calculated molar mass of 2.009 g/mol is very close to the molar mass of hydrogen gas (H₂), which is 2 g/mol. The slight difference can be attributed to approximations in room temperature or the gas constant, but it is evident that hydrogen is the gas.
To verify, the r.m.s. speed for hydrogen at 300 K can be calculated:
vrms=0.0023×8.314×300=0.0027482.6=3,741,300≈1934.5 m/s
This is close to the given 1930 m/s, considering typical approximations. The other gases have much lower r.m.s. speeds at the same temperature, confirming that hydrogen is the correct gas.
Hence, the correct answer is Option A.
Q 14PhysicsSection A • MCQoscillations
+4 / -1
Which of the following expressions corresponds to simple harmonic motion along a straight line, where x is the displacement and a, b, c are positive constants?
A
a+bx−cx2
B
bx2
C
a−bx+cx2
D
−bx
Official Correct Answer:Option (D)
Step-by-Step Solution:
To determine which expression corresponds to simple harmonic motion (SHM) along a straight line, we must recall the defining characteristic of SHM. In SHM, the acceleration of the particle is directly proportional to its displacement from a fixed point and is always directed opposite to the displacement. Mathematically, this is expressed as a=−ω2x, where ω is a positive constant and x is the displacement. Here, a represents acceleration, which is the second derivative of displacement with respect to time, a=dt2d2x.
The given expressions are functions of x, and we interpret them as representing acceleration a in terms of displacement x. Therefore, for SHM, the expression for acceleration must be linear in x and have a negative sign, ensuring the restoring force property. The constants a, b, and c are positive as per the question.
Now, let's evaluate each option:
Option A: a+bx−cx2
This expression is quadratic due to the −cx2 term. At x=0, the acceleration is a (a positive constant), which is not zero. However, in SHM, at the equilibrium position (x=0), acceleration must be zero. Additionally, the quadratic term makes the acceleration nonlinear, violating the proportionality condition a∝−x. Hence, this does not represent SHM.
Option B: bx2
This expression is quadratic and always non-negative since b>0 and x2≥0. At x=0, acceleration is zero, but for x=0, acceleration is positive. If x is positive, positive acceleration increases x further away from zero. If x is negative, positive acceleration pushes the particle towards more negative values initially but eventually towards zero, but the dependence is quadratic, not linear. The equation dt2d2x=bx2 is nonlinear and does not yield sinusoidal solutions characteristic of SHM. Thus, this is not SHM.
Option C: a−bx+cx2
This expression is also quadratic. At x=0, acceleration is a (positive), not zero, which contradicts SHM. The presence of a constant term and a quadratic term means acceleration is not proportional to −x. Therefore, this does not correspond to SHM.
Option D: −bx
This expression is linear in x and has a negative sign. Since b>0, we can write a=−bx. Comparing with a=−ω2x, we see that ω2=b, a positive constant. This satisfies the condition for SHM: acceleration is proportional to displacement and opposite in direction. The resulting differential equation is dt2d2x=−bx, or dt2d2x+bx=0, which has sinusoidal solutions like x=Asin(bt+ϕ), confirming SHM.
Hence, the correct answer is Option D.
Q 15PhysicsSection A • MCQwaves
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A source of sound A emitting waves of frequency 1800 Hz is falling towards ground with a terminal speed v. The observer B on the ground directly beneath the source receives waves of frequency 2150 Hz. The source A receives waves, reflected from ground of frequency nearly: (Speed of sound = 343 m/s)
A
2150 Hz
B
2500 Hz
C
1800 Hz
D
2400 Hz
Official Correct Answer:Option (B)
Step-by-Step Solution:
First, we are given that a source of sound A emits waves at a frequency of 1800 Hz and is falling towards the ground with a terminal speed v. An observer B on the ground directly beneath the source receives waves at a frequency of 2150 Hz. The speed of sound is 343 m/s. We need to find the frequency of the waves that source A receives after they are reflected from the ground.
To solve this, we use the Doppler effect formula for sound. The general formula when the source and observer are moving relative to each other is:
f′=f(vsound∓vsourcevsound±vobserver)
The signs depend on the directions of motion. For the first part, source A is moving towards the stationary observer B on the ground. Since the source is moving towards the observer, the observed frequency increases. The formula becomes:
fB=f(vsound−vsourcevsound)
Here, f=1800 Hz, fB=2150 Hz, and vsound=343 m/s. Plugging in the values:
2150=1800(343−v343)
Now, solve for v. Rearrange the equation:
18002150=343−v343
Simplify the left side:
18002150=1800÷502150÷50=3643
So:
3643=343−v343
Cross-multiply:
43×(343−v)=36×343
Calculate 36×343:
343×30=10290,343×6=2058,10290+2058=12348
Calculate 43×343:
343×40=13720,343×3=1029,13720+1029=14749
So:
14749−43v=12348
Rearrange to solve for v:
14749−12348=43v
2401=43v
v=432401
Simplify:
2401÷43=55.8372,but we keep it as a fraction:v=432401m/s
Note that 2401=343×7 because 343×7=2401. So:
v=43343×7m/s
Now, we need to find the frequency that source A receives from the waves reflected from the ground. The ground reflects the sound waves, and since the ground is stationary, the frequency of the reflected wave is the same as the frequency received by the ground. Observer B on the ground receives 2150 Hz, so the reflected wave has a frequency of 2150 Hz and is emitted by the stationary ground.
Source A is moving towards the ground (downwards) while the reflected wave is traveling upwards. So, for the reflected wave:
The source (ground) is stationary, so vsource=0.
The observer (source A) is moving towards the source (ground), so it is moving towards the sound wave.
The Doppler effect formula for a stationary source and an observer moving towards the source is:
f′′=freflected(vsoundvsound+vobserver)
Here, freflected=2150 Hz, vsound=343 m/s, and vobserver=v=432401 m/s. Plugging in:
f′′=2150(343343+v)=2150(1+343v)
Substitute v=43343×7:
f′′=2150(1+34343343×7)=2150(1+437)
Simplify inside the parentheses:
1+437=4343+437=4350
So:
f′′=2150×4350
Note that 2150=43×50 because 43×50=2150. Therefore:
f′′=43×50×4350=50×50=2500
Thus, the frequency that source A receives from the reflected waves is 2500 Hz.
Hence, the correct answer is Option B.
Q 16PhysicsSection A • MCQelectrostatics
+4 / -1
A spherically symmetric charge distribution is characterised by the following charge density variations: ρ(r)=ρo(1−Rr) for r<R, ρ(r)=0 for r≥R. Where r is the distance from the centre of the charge distribution and ρo is a constant. The electric field at an internal point (r<R) is:
A
4εoρo(3r−4Rr2)
B
εoρo(3r−4Rr2)
C
3εoρo(3r−4Rr2)
D
12εoρo(3r−4Rr2)
Official Correct Answer:Option (B)
Step-by-Step Solution:
To find the electric field at an internal point where r<R, we use Gauss's law due to the spherical symmetry. Gauss's law states that the flux through a closed surface is equal to the charge enclosed divided by ε0. We choose a spherical Gaussian surface of radius r centered at the same point as the charge distribution.
The electric field is radial and constant in magnitude on this surface, so the flux is E×4πr2. By Gauss's law:
E×4πr2=ε0Qenc
Solving for E:
E=4πε0r2Qenc
Now, we need to find Qenc, the charge enclosed within the sphere of radius r. The charge density is given by ρ(r′)=ρo(1−Rr′) for r′<R. Since r<R, we integrate the charge density over the volume inside radius r. Using spherical coordinates, the volume element is dV′=4πr′2dr′, so:
Qenc=∫0rρ(r′)dV′=∫0rρo(1−Rr′)×4πr′2dr′
Factor out the constants:
Qenc=4πρo∫0r(1−Rr′)r′2dr′
Expand the integrand:
Qenc=4πρo∫0r(r′2−Rr′3)dr′
Integrate term by term:
∫0rr′2dr′=[3r′3]0r=3r3
∫0rRr′3dr′=R1[4r′4]0r=4Rr4
So the integral becomes:
∫0r(r′2−Rr′3)dr′=3r3−4Rr4
Therefore:
Qenc=4πρo(3r3−4Rr4)
Substitute Qenc back into the expression for E:
E=4πε0r24πρo(3r3−4Rr4)=ε0r2ρo(3r3−4Rr4)
Simplify by dividing each term by r2:
E=ε0ρo(3r2r3−4Rr2r4)=ε0ρo(3r−4Rr2)
Comparing with the options, this matches option B:
εoρo(3r−4Rr2)
Hence, the correct answer is Option B.
Q 17PhysicsSection A • MCQcapacitor
+4 / -1
The space between the plates of a parallel plate capacitor is filled with a 'dielectric' whose 'dielectric constant' varies with distance as per the relation: K(x)=Ko+λx (λ = a constant). The capacitance C, of the capacitor, would be related to its vacuum capacitance Co for the relation:
A
C=ln(1+Koλd)λdCo
B
C=dln(1+Koλd)λCo
C
C=ln(1+λd/Ko)λdCo
D
C=dln(1+Ko/λd)λCo
Official Correct Answer:Option (C)
Step-by-Step Solution:
The capacitance of a parallel plate capacitor with a varying dielectric constant can be found by considering the capacitor as composed of infinitesimal capacitors in series. The dielectric constant is given by K(x)=Ko+λx, where x is the distance from one plate, and the plates are separated by a distance d. The vacuum capacitance is Co=dεoA, where A is the plate area and εo is the permittivity of free space.
For an infinitesimal capacitor of thickness dx at position x, the capacitance is dC=dxK(x)εoA. Since these infinitesimal capacitors are in series, the reciprocal of the total capacitance C is the integral of the reciprocals of the infinitesimal capacitances:
C1=∫0ddC1dx=∫0dK(x)εoAdx
Substituting K(x)=Ko+λx:
C1=∫0d(Ko+λx)εoAdx=εoA1∫0dKo+λxdx
To solve the integral, use the substitution u=Ko+λx. Then du=λdx, so dx=λdu. The limits change: when x=0, u=Ko; when x=d, u=Ko+λd. The integral becomes:
Recall that Co=dεoA, so εoA=Cod. Substituting this in:
C1=Cod1⋅λ1ln(1+Koλd)=λCodln(1+Koλd)
Solving for C:
C=ln(1+Koλd)λCod=ln(1+Koλd)λdCo
Comparing with the options, this matches Option C.
Hence, the correct answer is Option C.
Q 18PhysicsSection A • MCQcurrent electricity
+4 / -1
The circuit shown here has two batteries of 8.0 V and 16.0 V and three resistors 3Ω, 9Ω and 9Ω and a capacitor of 5.0 μF. How much is the current I in the circuit in steady state?
A
1.6 A
B
0.67 A
C
2.5 A
D
0.25 A
Official Correct Answer:Option (B)
Step-by-Step Solution:
The two batteries are connected in opposition. The net electromotive force (EMF) of the loop is ϵnet=16.0 V−8.0 V=8.0 V
Rtotal=3Ω+9Ω=12Ω (in steady state)
I=Rtotalϵnet
I=128.0
I=32 A≈0.67 A
Q 19PhysicsSection A • MCQcurrent electricity
+4 / -1
In the experiment of calibration of voltmeter, a standard cell of e.m.f. 1.1 volt is balanced against 440 cm of potential wire. The potential difference across the ends of resistance is found to balance against 220 cm of the wire. The corresponding reading of voltmeter is 0.5 volt. The error in the reading of volmeter will be:
A
−0.15 volt
B
0.15 volt
C
0.5 volt
D
−0.05 volt
Official Correct Answer:Option (D)
Step-by-Step Solution:
In a potentiometer, potential difference is proportional to balancing length.
First, find potential gradient:
k=4401.1=0.0025 V/cm
Now for 220 cm:
Vtrue=k×220=0.0025×220=0.55 V
So actual voltage = 0.55 V
Given voltmeter reading = 0.5 V
Now error:
VError=Vmeasured−Vtrue=0.5−0.55=−0.05
Negative sign means the voltmeter is reading less.
Finalanswer:Error=−0.05 V
Q 20PhysicsSection A • MCQmoving charges and magnetism
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A positive charge 'q' of mass 'm' is moving along the +x axis. We wish to apply a uniform magnetic field B for time Δt so that the charge reverses its direction crossing the y axis at a distance d. Then:
A
B=qdmv and Δt=vπd
B
B=2qdmv and Δt=2vπd
C
B=qd2mv and Δt=2vπd
D
B=qd2mv and Δt=vπd
Official Correct Answer:Option (C)
Step-by-Step Solution:
A positive charge q of mass m is moving along the positive x-axis with velocity v. To reverse its direction and make it cross the y-axis at a distance d from the origin, a uniform magnetic field B is applied for a time Δt. The force on a moving charge in a magnetic field is given by F=q(v×B), which acts as a centripetal force, causing circular motion. Since the charge is positive and initially moving in the +x direction, to curve it upwards and cross the y-axis at a positive distance d, the magnetic field must be directed along the negative z-axis (into the plane).
The magnetic force provides the centripetal force: qvB=rmv2, where r is the radius of the circular path. Solving for r:
qvB=rmv2
r=qBmv
Reversing direction requires the charge to traverse a semicircular path. After half a circle, the charge is diametrically opposite its starting point. Assuming it starts at the origin (0,0), after a semicircle, it crosses the y-axis at (0,d). The distance from the origin to this point is d, and since the center of the circle is at (0,r) (as the initial velocity is horizontal and force is vertical), the y-coordinate after semicircle is 2r. Thus:
d=2r
Substituting r=qBmv:
d=2×qBmv
Solving for B:
d=qB2mv
qBd=2mv
B=qd2mv
The time Δt to traverse a semicircle is the distance divided by speed. The arc length of a semicircle is πr, and speed is constant v, so:
Δt=vπr
Substituting r=2d from d=2r:
Δt=vπ×2d=2vπd
Thus, B=qd2mv and Δt=2vπd. Comparing with the options:
Q 21PhysicsSection A • MCQmoving charges and magnetism
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Consider two thin identical conducting wires covered with very thin insulating material. One of the wires is bent into a loop and produces magnetic field B1, at its centre when a current I passes through it. The ratio B1 : B2 is:
A
1:1
B
1 : 3
C
1 : 9
D
9 : 1
Official Correct Answer:Option (B)
Step-by-Step Solution:
The magnetic field at the center of a circular loop is defined as B=2aμ0nI
Number of turns (n) = 3
Radius (R) = a/3 (since the same wire length L=2πa now forms 3 loops, L=3×2πR⟹R=a/3)
Current per turn = I/3
B2=2⋅(a/3)μ0⋅3⋅(I/3)
B2=2⋅(a/3)μ0⋅I=2a3μ0I
B2B1=3μ0I/2aμ0I/2a=31
Q 22PhysicsSection A • MCQalternating current
+4 / -1
A sinusoidal voltage V(t) = 100 sin(500t) is applied across a pure inductance of L = 0.02H. The current through the coil is:
A
10 cos(500t)
B
−10 cos(500t)
C
10 sin(500t)
D
−10 sin(500t)
Official Correct Answer:Option (B)
Step-by-Step Solution:
We are given a sinusoidal voltage V(t)=100sin(500t) applied across a pure inductance of L=0.02H. We need to find the current through the coil.
For a pure inductor, the relationship between voltage and current is given by:
V(t)=Ldtdi
Substituting the given values:
100sin(500t)=0.02⋅dtdi
Now, solve for dtdi:
dtdi=0.02100sin(500t)
Calculate the numerical value:
0.02100=5000
So,
dtdi=5000sin(500t)
To find the current i(t), integrate both sides with respect to t:
i(t)=∫5000sin(500t)dt
The integral of sin(500t) is −500cos(500t), because the derivative of cos(500t) is −500sin(500t), so the antiderivative of sin(500t) is −500cos(500t). Therefore:
i(t)=5000⋅(−500cos(500t))+C
where C is the constant of integration.
Simplify the expression:
i(t)=−5005000cos(500t)+C
i(t)=−10cos(500t)+C
In AC circuits with pure inductance, the average current over a full cycle is zero, and there is no DC component. Therefore, we can assume the constant C=0. Additionally, the current in an inductor lags the voltage by 90∘ (or 2π radians). Since the voltage is a sine function, the current should be a negative cosine function, which matches the form above without a constant term.
Thus, the current is:
i(t)=−10cos(500t)
Comparing with the options:
A. 10cos(500t)
B. −10cos(500t)
C. 10sin(500t)
D. −10sin(500t)
Our solution matches option B.
Hence, the correct answer is Option B.
Q 23PhysicsSection A • MCQelectromagnetic waves
+4 / -1
A lamp emits monochromatic green light uniformly in all directions. The lamp is 3% efficient in converting electrical power to electromagnetic waves and consumes 100 W of power. The amplitude of the electric field associated with the electromagnetic radiation at a distance of 5 m from the lamp will be nearly:
A
1.34 V/m
B
2.68 V/m
C
4.02 V/m
D
5.36 V/m
Official Correct Answer:Option (B)
Step-by-Step Solution:
The lamp consumes 100 W of electrical power and is 3% efficient in converting this power to electromagnetic waves. Therefore, the radiant power emitted as light is calculated as follows:
Radiant power = Efficiency × Consumed power = (3/100) × 100 W = 3 W.
This power is emitted uniformly in all directions, so at a distance of 5 m, it spreads over the surface of a sphere with radius 5 m. The surface area of a sphere is given by 4πr2. Substituting r=5 m:
Surface area = 4π(5)2=4π×25=100π m².
The intensity I is the power per unit area, so:
I=Surface areaRadiant power=100π3 W/m2.
For an electromagnetic wave, the intensity I is related to the amplitude of the electric field E0 by the formula:
I=21ϵ0cE02,
where ϵ0 is the permittivity of free space (8.85×10−12 C²/N·m²) and c is the speed of light (3×108 m/s). Rearranging for E02:
Adding these: 314.16+94.248=408.408, then 408.408+8.6394=417.0474.
Now multiply by 10−3:
417.0474×10−3=0.4170474.
So,
E02=0.41704743≈7.193.
Taking the square root:
E0≈7.193≈2.6815 V/m.
Rounding to two decimal places, E0≈2.68 V/m.
Hence, the amplitude of the electric field is nearly 2.68 V/m, which corresponds to option B.
Q 24PhysicsSection A • MCQray optics
+4 / -1
The refractive index of the material of a concave lens is μ. It is immersed in a medium of refractive index μ1. A parallel beam of light is incident on the lens. The path of the emergent rays when μ1>μ is:
A
B
C
D
Official Correct Answer:Option (A)
Step-by-Step Solution:
When the refractive index of the surrounding medium is greater than that of the lens, the nature of the lens reverses. As shown in option (A), the concave lens stops diverging light and instead acts as a converging lens, causing the parallel incident rays to meet at a point.
Q 25PhysicsSection A • MCQwave optics
+4 / -1
Interference pattern is observed at 'P' due to superimposition of two rays coming out from a source 'S' as shown in the figure. The value of 'l' for which maxima is obtained at 'P' is: (R is perfect reflecting surface)
A
l=3−12nλ
B
l=2(3−1)(2n−1)λ
C
l=4(2−3)(2n−1λ)3
D
l=3−1(2n−1)λ
Official Correct Answer:Option (C)
Step-by-Step Solution:
The direct path traveled by the first ray is x1=SP=2l
For the second ray reflected from surface R, let the point of reflection be O. SO=OP=cos30∘l=32l
The total path length of the reflected ray is x2=SO+OP=34l
The geometric path difference between the two rays is Δxgeom=x2−x1=34l−2l=2l(32−3)
Reflection from the perfect reflecting surface R (denser medium) introduces a phase change of π, which is equivalent to an additional path difference of 2λ. The net path difference is Δx=Δxgeom+2λ
Δx=2l(32−3)+2λ
For constructive interference (maxima) at point P: Δx=nλ
2l(32−3)+2λ=nλ
2l(32−3)=(n−21)λ=2(2n−1)λ
l=4(2−3)(2n−1)λ3
Q 26PhysicsSection A • MCQwave optics
+4 / -1
In an experiment of single slit diffraction pattern, first minimum for red light coincides with first maximum of some other wavelength. If wavelength of red light is 6600 A˚, then wavelength of first maximum will be:
A
3300 A˚
B
4400 A˚
C
5500 A˚
D
6600 A˚
Official Correct Answer:Option (B)
Step-by-Step Solution:
In a single slit diffraction experiment, the position of minima and maxima are determined by specific conditions. For the first minimum of red light, the condition is given by:
asinθ=nλ
where a is the slit width, θ is the angle from the central maximum, λ is the wavelength, and n is the order of the minimum. For the first minimum, n=1. Given the wavelength of red light λr=6600A˚, we have:
asinθ=1⋅6600=6600A˚(Equation 1)
For the first maximum of another light with wavelength λ, the condition is approximately:
asinθ=(m+21)λ
where m is the order of the maximum. For the first maximum, m=1, so:
asinθ=(1+21)λ=23λ(Equation 2)
The problem states that the first minimum for red light coincides with the first maximum of the other light. This means the angular position θ is the same for both, so sinθ is identical. Therefore, the expressions for asinθ from Equation 1 and Equation 2 must be equal:
6600=23λ
Solving for λ:
λ=6600×32
Performing the multiplication:
λ=36600×2=313200=4400A˚
Thus, the wavelength of the other light for which the first maximum coincides with the first minimum of red light is 4400 Å.
Comparing with the options:
A. 3300 Å
B. 4400 Å
C. 5500 Å
D. 6600 Å
Hence, the correct answer is Option B.
Q 27PhysicsSection A • MCQdual nature of matter and radiation
+4 / -1
A beam of light has two wavelengths of 4972 A˚ and 6216 A˚ with a total intensity of 3.6×10−3 Wm−2 equally distributed among the two wavelengths. The beam falls normally on an area of 1 cm2 of a clean metallic surface of work function 2.3 eV. Assume that there is no loss of light by reflection and that each capable photon ejects one electron. The number of photoelectrons liberated in 2 s is approximately:
A
6×1011
B
9×1011
C
11×1011
D
15×1011
Official Correct Answer:Option (B)
Step-by-Step Solution:
A beam of light has two wavelengths: 4972 Å and 6216 Å. The total intensity is 3.6×10−3 W/m², equally distributed between the two wavelengths. This means each wavelength has an intensity of half the total, so intensity for 4972 Å is 1.8×10−3 W/m² and for 6216 Å is also 1.8×10−3 W/m².
The beam falls normally on an area of 1 cm². First, convert area to square meters: 1 cm² = 1×10−4 m². The power (energy per second) for each wavelength is intensity multiplied by area.
For 4972 Å: power = (1.8×10−3)×(1×10−4)=1.8×10−7 W.
For 6216 Å: power = (1.8×10−3)×(1×10−4)=1.8×10−7 W.
We need the number of photoelectrons liberated in 2 seconds. The energy delivered by each wavelength in 2 seconds is power multiplied by time.
For 4972 Å: energy = (1.8×10−7)×2=3.6×10−7 J.
For 6216 Å: energy = (1.8×10−7)×2=3.6×10−7 J.
Each photon has energy Ephoton=λhc, where h is Planck's constant (6.626×10−34 J s), c is the speed of light (3×108 m/s), and λ is the wavelength in meters.
Convert wavelengths to meters:
4972 Å = 4972×10−10 m = 4.972×10−7 m.
6216 Å = 6216×10−10 m = 6.216×10−7 m.
Calculate photon energy for 4972 Å:
Eph1=4.972×10−7(6.626×10−34)×(3×108)=4.972×10−71.9878×10−25=4.972×10−71.9878×10−25=3.9976×10−19 J.
Calculate photon energy for 6216 Å:
Eph2=6.216×10−7(6.626×10−34)×(3×108)=6.216×10−71.9878×10−25=6.216×10−71.9878×10−25=3.1987×10−19 J.
The work function of the metal is 2.3 eV. Convert to joules using 1 eV=1.602×10−19 J:
Work function ϕ=2.3×1.602×10−19=3.6846×10−19 J.
Compare photon energies with work function:
For 4972 Å: Eph1=3.9976×10−19 J > 3.6846×10−19 J, so photons can eject electrons.
For 6216 Å: Eph2=3.1987×10−19 J < 3.6846×10−19 J, so photons cannot eject electrons.
Only photons of 4972 Å contribute to photoelectrons. The number of photons for 4972 Å is the energy delivered divided by energy per photon:
Since each capable photon ejects one electron, the number of photoelectrons is 9.003×1011, approximately 9×1011.
Hence, the correct answer is Option B.
Q 28PhysicsSection A • MCQsemiconductor devices and logic gates
+4 / -1
For LED's to emit light in visible region of electromagnetic light, it should have energy band gap in the range of:
A
0.1eV to 0.4eV
B
0.5eV to 0.8eV
C
0.9eV to 1.6eV
D
1.7eV to 3.0eV
Official Correct Answer:Option (D)
Step-by-Step Solution:
To determine the energy band gap required for LEDs to emit light in the visible region, we need to recall that the visible spectrum ranges from approximately 400 nm (violet) to 700 nm (red). The energy E of a photon is related to its wavelength λ by the formula:
E=λhc
where h is Planck's constant (4.135667662×10−15 eV·s), c is the speed of light (3×108 m/s), and λ is the wavelength in meters. However, it is convenient to use nanometers for wavelength and the approximation hc≈1240 eV·nm, so the formula simplifies to:
E (in eV)=λ (in nm)1240
Now, calculate the energy for the shortest visible wavelength (400 nm, violet light, highest energy):
Eviolet=4001240=3.1 eV
Next, calculate the energy for the longest visible wavelength (700 nm, red light, lowest energy):
Ered=7001240≈1.771 eV
Thus, the energy range for visible light photons is approximately 1.771 eV to 3.1 eV. For an LED to emit visible light, its energy band gap must match the energy of the photons in this range because the emitted photon energy equals the band gap energy.
Comparing this range with the given options:
Option A: 0.1 eV to 0.4 eV → Too low (corresponds to infrared, not visible)
Option B: 0.5 eV to 0.8 eV → Too low (corresponds to infrared)
Option C: 0.9 eV to 1.6 eV → Too low (1.6 eV is about 775 nm, which is in the infrared; 1.6 eV is less than the 1.771 eV required for red light)
Option D: 1.7 eV to 3.0 eV → This covers energies from 1.7 eV (about 729 nm, near red) to 3.0 eV (about 413 nm, violet). While 3.0 eV is slightly less than 3.1 eV (400 nm), it still covers most of the visible spectrum, including blue and violet regions (since 413 nm is violet). The lower limit of 1.7 eV is very close to the 1.771 eV for red light.
Therefore, the band gap range for visible LEDs is 1.7 eV to 3.0 eV, which corresponds to Option D.
Hence, the correct answer is Option D.
Q 29PhysicsSection A • MCQatoms and nuclei
+4 / -1
A piece of bone of an animal from a ruin is found to have 14C activity of 12 disintegrations per minute per gm of its carbon content. The 14C activity of a living animal is 16 disintegrations per minute per gm. How long ago nearly did the animal die? (Given half life of 14C is t1/2 = 5760 years)
A
1672 years
B
2391 years
C
3291 years
D
4453 years
Official Correct Answer:Option (B)
Step-by-Step Solution:
The activity of radioactive carbon-14 decreases over time due to decay. The initial activity when the animal was alive is given as A0=16 disintegrations per minute per gram, and the current activity of the bone is A=12 disintegrations per minute per gram. The half-life of carbon-14 is t1/2=5760 years.
The decay follows the exponential law: A=A0e−λt, where λ is the decay constant and t is the time elapsed since death. Substituting the given values:
12=16e−λt
Divide both sides by 16:
1612=e−λt
Simplify the fraction:
43=e−λt
Take the natural logarithm of both sides:
ln(43)=ln(e−λt)
The right side simplifies to −λt:
ln(43)=−λt
Multiply both sides by -1:
−ln(43)=λt
Using the property −ln(a)=ln(1/a), rewrite as:
ln(34)=λt
Therefore:
t=λln(34)
Now, find the decay constant λ using the half-life formula t1/2=λln(2). Solving for λ:
λ=t1/2ln(2)=5760ln(2)
Substitute this into the equation for t:
t=5760ln(2)ln(34)=ln(34)×ln(2)5760
So:
t=5760×ln(2)ln(34)
Compute the numerical value. First, calculate ln(4/3):
34≈1.3333,ln(1.3333)≈0.287682
Next, ln(2)≈0.693147:
ln(2)ln(4/3)=0.6931470.287682≈0.415037
Now multiply by 5760:
t=5760×0.415037≈2390.613
Rounding to the nearest whole number gives approximately 2391 years.
Comparing with the options, 2391 years corresponds to option B.
Hence, the correct answer is Option B.
Q 30PhysicsSection A • MCQcommunication systems
+4 / -1
For sky wave propagation, the radio waves must have a frequency range in between:
A
1MHz to 2MHz
B
5MHz to 25MHz
C
35MHz to 40MHz
D
45MHz to 50MHz
Official Correct Answer:Option (B)
Step-by-Step Solution:
Sky wave propagation involves radio waves being reflected back to Earth by the ionosphere. For this reflection to occur effectively, the frequency of the radio waves must lie within a specific range. If the frequency is too low, the waves get absorbed by the ionosphere, especially in the D layer during the day. If the frequency is too high, the waves penetrate the ionosphere and do not return to Earth.
The critical frequency, denoted as fc, is the maximum frequency at which a radio wave can be reflected back to Earth when sent vertically upwards. It is calculated using the formula:
fc=9Nmax
where Nmax is the maximum electron density in the ionosphere. A typical value for Nmax is 1012 electrons per cubic meter. Substituting this value:
fc=9×1012
Since 1012=(1012)1/2=106 (because 12×21=6), we get:
fc=9×106 Hz
Converting Hz to MHz (where 106 Hz = 1 MHz), this becomes:
fc=9 MHz
However, for oblique incidence (waves sent at an angle), the maximum usable frequency (MUF) is higher than fc and is given by:
MUF=cosθfc
where θ is the angle of incidence. For long-distance communication, θ is large, so cosθ is small, allowing MUF to be significantly higher than fc. Typically, the MUF can reach up to about 25-30 MHz under favorable conditions.
The effective frequency range for sky wave propagation is generally from 3 MHz to 30 MHz. Frequencies below 3 MHz are prone to absorption, while frequencies above 30 MHz tend to penetrate the ionosphere. Now, examining the options:
Option A: 1 MHz to 2 MHz - This is too low; absorption occurs in the D layer.
Option B: 5 MHz to 25 MHz - This falls within the typical 3 MHz to 30 MHz range.
Option C: 35 MHz to 40 MHz - This is too high; waves penetrate the ionosphere.
Option D: 45 MHz to 50 MHz - This is also too high; penetration occurs.
Therefore, the correct frequency range for sky wave propagation is given in Option B.
Hence, the correct answer is Option B.
Q 31ChemistrySection A • MCQsome basic concepts of chemistry
+4 / -1
The amount of BaSO4 formed upon mixing 100 mL of 20.8% BaCl2 solution with 50 mL of 9.8% H2SO4 solution will be: (Ba = 137, Cl = 35.5, S = 32, H = 1 and O = 16)
A
23.3 g
B
11.65 g
C
30.6 g
D
33.2 g
Official Correct Answer:Option (B)
Step-by-Step Solution:
BaCl2+H2SO4→BaSO4+2HCl
Weight of BaCl2=20.8 g; weight of H2SO4=9.8%=4.9gm ,
BaCl20.1+H2SO40.05→BaSO40.05+2HCl
Weight of BaSO4=0.05×233=11.65 g
Q 32ChemistrySection A • MCQatomic structure
+4 / -1
If m and e are the mass and charge of the revolving electron in the orbit of radius r for hydrogen atom, the total energy of the revolving electron will be:
A
21re2
B
−re2
C
rme2
D
−21re2
Official Correct Answer:Option (D)
Step-by-Step Solution:
To find the total energy of the electron revolving in a hydrogen atom, we consider the Bohr model where the electron moves in a circular orbit of radius r around the proton. The electron has mass m and charge e, while the proton has charge +e. The electrostatic force of attraction provides the necessary centripetal force for circular motion.
The electrostatic force between the electron and proton is given by Coulomb's law. Since the charges are opposite, the magnitude is 4πϵ01r2e⋅e=4πϵ01r2e2. This force acts as the centripetal force, which is rmv2, where v is the orbital speed of the electron.
Setting these equal:
rmv2=4πϵ01r2e2
Multiply both sides by r to simplify:
mv2=4πϵ01re2
Solve for v2:
v2=4πϵ01mre2
The kinetic energy K of the electron is 21mv2. Substitute the expression for v2:
K=21m(4πϵ01mre2)
The m cancels out:
K=21⋅4πϵ01re2
The potential energy U for the electrostatic attraction is negative and given by −4πϵ01re2.
The total energy E is the sum of kinetic and potential energy:
E=K+U=(21⋅4πϵ01re2)+(−4πϵ01re2)
Factor out 4πϵ01re2:
E=4πϵ01re2(21−1)
Simplify the term in parentheses:
21−1=−21
So:
E=4πϵ01re2×(−21)=−21⋅4πϵ01re2
In atomic physics, it is common to use units where the constant 4πϵ01 is set to 1 (as in cgs units). Thus, the expression simplifies to:
E=−21re2
Comparing with the options, this matches option D.
Hence, the correct answer is Option D.
Q 33ChemistrySection A • MCQatomic structure
+4 / -1
The de-Broglie wavelength of a particle of mass 6.63 g moving with a velocity of 100 ms−1 is:
A
10−33 m
B
10−35 m
C
10−31 m
D
10−25 m
Official Correct Answer:Option (A)
Step-by-Step Solution:
The de-Broglie wavelength λ of a particle is given by the formula λ=ph, where h is Planck's constant and p is the momentum of the particle. Momentum p is calculated as p=m×v, where m is the mass and v is the velocity. So, the formula becomes λ=mvh.
We are given the mass m=6.63 grams and velocity v=100 meters per second. However, the SI unit for mass is kilograms, so we must convert grams to kilograms. Since 1 kilogram = 1000 grams, we have:
m=10006.63=0.00663 kg
This can also be written as m=6.63×10−3 kg. The velocity v=100 m/s remains as is. Planck's constant h is 6.63×10−34 Joule seconds (J s), and since Joule is kg m² s⁻², the units are consistent.
Now substitute the values into the formula:
λ=m×v6.63×10−34=(6.63×10−3)×1006.63×10−34
First, compute the denominator: m×v=(6.63×10−3)×100. Since 100=102, we have:
m×v=6.63×10−3×102=6.63×10−3+2=6.63×10−1
Now the expression is:
λ=6.63×10−16.63×10−34
Simplify by dividing the numerical coefficients and the powers of 10 separately. The numerical part is 6.636.63=1. The exponent part is 10−110−34=10−34−(−1)=10−34+1=10−33. Therefore:
λ=1×10−33 m
So, the de-Broglie wavelength is 10−33 meters. Comparing with the options, this matches option A.
Hence, the correct answer is Option A.
Q 34ChemistrySection A • MCQatomic structure
+4 / -1
Excited hydrogen atom emits light in the ultraviolet region at 2.47×1015 Hz. With this frequency, the energy of a single photon is: (h = 6.63×10−34 Js)
A
8.041×10−40 J
B
2.680×10−19 J
C
1.640×10−18 J
D
6.111×10−17 J
Official Correct Answer:Option (C)
Step-by-Step Solution:
The energy of a single photon is calculated using the formula E=hν, where h is Planck's constant and ν is the frequency of the light.
Given:
Frequency, ν=2.47×1015 Hz
Planck's constant, h=6.63×10−34 J s
Substitute the values into the formula:
' in math mode at position 1:̲
E = (6.63 \tim…" style="color:#cc0000">$
E = (6.63 \times 10^{-34}) \times (2.47 \times 10^{15})$
First, multiply the coefficients:
' in math mode at position 1:̲
6.63 \times 2.…" style="color:#cc0000">$
6.63 \times 2.47$
Break it down step by step:
' in math mode at position 1:̲
6.63 \times 2.…" style="color:#cc0000">$
6.63 \times 2.47 = 6.63 \times (2 + 0.4 + 0.07)$
' in math mode at position 1:̲
= (6.63 \times…" style="color:#cc0000">$
= (6.63 \times 2) + (6.63 \times 0.4) + (6.63 \times 0.07)$
' in math mode at position 1:̲
= 13.26 + 2.65…" style="color:#cc0000">$
= 13.26 + 2.652 + 0.4641$
' in math mode at position 1:̲
= 16.3761" style="color:#cc0000">$
= 16.3761$
Now, multiply the powers of 10:
' in math mode at position 1:̲
10^{-34} \time…" style="color:#cc0000">$
10^{-34} \times 10^{15} = 10^{-34 + 15} = 10^{-19}$
Combine the results:
' in math mode at position 1:̲
E = 16.3761 \t…" style="color:#cc0000">$
E = 16.3761 \times 10^{-19} \text{ J}$
Convert to standard scientific notation by adjusting the decimal:
' in math mode at position 1:̲
16.3761 \times…" style="color:#cc0000">$
16.3761 \times 10^{-19} = 1.63761 \times 10^1 \times 10^{-19} = 1.63761 \times 10^{-18} \text{ J}$
Consider significant figures. Both given values (6.63 and 2.47) have three significant figures. Round 1.63761×10−18 to three significant figures:
The third digit is 3 (in 1.63), and the next digit 7≥5, so round up: 1.64×10−18 J.
Compare with the options:
A: 8.041×10−40 J
B: 2.680×10−19 J
C: 1.640×10−18 J
D: 6.111×10−17 J
The value 1.64×10−18 J matches option C (1.640×10−18 J).
Hence, the correct answer is Option C.
Q 35ChemistrySection A • MCQperiodic classification of elements
+4 / -1
Similarity in chemical properties of the atoms of elements in a group of the Periodic table is most closely related to:
A
atomic numbers
B
atomic masses
C
number of principal energy levels
D
number of valence electrons
Official Correct Answer:Option (D)
Step-by-Step Solution:
The chemical properties of the atoms of elements in a group of the periodic table is most closely related to the number of valence electrons. Atoms with same no. of valence electrons show similar properties.
Q 36ChemistrySection A • MCQperiodic classification of elements
+4 / -1
Which of the following arrangements represents the increasing order (smallest to largest) of ionic radii of the given species O2−, S2−, N3−, P3−?
A
O2− < N3− < S2− < P3−
B
O2− < P3− < N3− < S2−
C
N3 < O2− < P3− < S2−
D
N3− < S2− < O2− < P3−
Official Correct Answer:Option (A)
Step-by-Step Solution:
To determine the increasing order of ionic radii for the species O2-, S2-, N3-, and P3-, we need to analyze their positions in the periodic table and their electron configurations. Ionic radius depends on the number of electrons and the effective nuclear charge.
First, let's find the electron count for each ion:
Oxygen (atomic number 8) in O2- has 8 + 2 = 10 electrons.
Sulfur (atomic number 16) in S2- has 16 + 2 = 18 electrons.
Nitrogen (atomic number 7) in N3- has 7 + 3 = 10 electrons.
Phosphorus (atomic number 15) in P3- has 15 + 3 = 18 electrons.
This shows that O2- and N3- are isoelectronic (both have 10 electrons, like neon), while S2- and P3- are isoelectronic (both have 18 electrons, like argon).
For isoelectronic species, ionic radius decreases as nuclear charge (atomic number) increases because a higher nuclear charge pulls the electron cloud closer. Comparing O2- (atomic number 8) and N3- (atomic number 7):
N3- has lower nuclear charge (7) than O2- (8), so N3- has a larger ionic radius than O2-.
Thus, O2- < N3-.
Similarly, comparing S2- (atomic number 16) and P3- (atomic number 15):
P3- has lower nuclear charge (15) than S2- (16), so P3- has a larger ionic radius than S2-.
Thus, S2- < P3-.
Now, we compare across the two groups. O2- and N3- are in period 2 (principal quantum number n=2), while S2- and P3- are in period 3 (n=3). Ions in higher periods have larger radii due to more electron shells. Therefore, both S2- and P3- are larger than O2- and N3-.
Combining the comparisons:
O2- is the smallest (period 2, highest nuclear charge in its group).
N3- is next (period 2, larger than O2- due to lower nuclear charge).
S2- is next (period 3, smaller than P3- due to higher nuclear charge).
P3- is the largest (period 3, lowest nuclear charge in its group).
So the order is: O2- < N3- < S2- < P3-.
Comparing with the options:
A: O2- < N3- < S2- < P3-
B: O2- < P3- < N3- < S2-
C: N3- < O2- < P3- < S2-
D: N3- < S2- < O2- < P3-
Option A matches our derived order.
Hence, the correct answer is Option A.
Q 37ChemistrySection A • MCQchemical bonding and molecular structure
+4 / -1
Which of the following molecules has two sigma (σ) and two pi (π) bonds?
A
C2H4
B
N2 F2
C
C2H2Cl2
D
HCN
Official Correct Answer:Option (D)
Step-by-Step Solution:
To determine which molecule has two sigma (σ) and two pi (π) bonds, we need to analyze the bonding in each option. A sigma bond is formed by the head-on overlap of atomic orbitals and is present in all single bonds. A pi bond is formed by the sideway overlap of atomic orbitals and is found in double bonds (one π bond) or triple bonds (two π bonds).
Starting with option A: C₂H₄ (ethylene). The structure is H₂C=CH₂. The carbon-carbon double bond consists of one σ bond and one π bond. Each carbon is bonded to two hydrogen atoms via single bonds, which are σ bonds. So, there are four C-H σ bonds and one C-C σ bond, totaling five σ bonds. The double bond contributes one π bond. Therefore, C₂H₄ has five σ bonds and one π bond, which does not match the requirement of two σ and two π bonds.
Next, option B: N₂F₂ (dinitrogen difluoride). The common structure is F-N=N-F, with a double bond between the nitrogen atoms. The double bond has one σ and one π bond. Each nitrogen-fluorine bond is a single bond, which is a σ bond. So, there are two N-F σ bonds and one N-N σ bond, totaling three σ bonds. The double bond contributes one π bond. Therefore, N₂F₂ has three σ bonds and one π bond, which does not match.
Moving to option C: C₂H₂Cl₂ (dichloroethene). This has isomers, but both isomers have a carbon-carbon double bond. For example, in 1,2-dichloroethene (ClHC=CHCl), the C=C bond has one σ and one π bond. There are two C-Cl single bonds (σ bonds) and two C-H single bonds (σ bonds). So, total σ bonds are one (from C=C) + two (from C-Cl) + two (from C-H) = five σ bonds, and one π bond. The same count applies to the 1,1-dichloroethene isomer (H₂C=CCl₂). Therefore, C₂H₂Cl₂ has five σ bonds and one π bond, which does not match.
Finally, option D: HCN (hydrogen cyanide). The structure is H-C≡N. The carbon-nitrogen triple bond consists of one σ bond and two π bonds. The hydrogen-carbon bond is a single bond, which is a σ bond. So, total σ bonds are one (from H-C) + one (from C≡N) = two σ bonds. The triple bond contributes two π bonds. Therefore, HCN has two σ bonds and two π bonds, matching the requirement.
Hence, the correct answer is Option D.
Q 38ChemistrySection A • MCQthermodynamics
+4 / -1
The (S°) of the following substances are: CH4(g) 186.2 JK−1 mol−1, O2(g) 205.2 JK−1 mol−1, CO2(g) 213.6 JK−1 mol−1, H2O(g) 69.9 JK−1 mol−1. The entropy change (ΔS∘) for the reaction CH4(g) + 2O2(g) → CO2(g) + 2H2O(l) is:
A
−312.5 J K−1 mol−1
B
−242.8 JK−1 mol−1
C
−108.1 JK−1 mol−1
D
−37.6 J K−1 mol−1
Official Correct Answer:Option (B)
Step-by-Step Solution:
The standard molar entropies (S°) given are:
S∘(CH4(g))=186.2 J K−1 mol−1
S∘(O2(g))=205.2 J K−1 mol−1
S∘(CO2(g))=213.6 J K−1 mol−1
S∘(H2O(g))=69.9 J K−1 mol−1
However, the reaction is: CH4(g)+2O2(g)→CO2(g)+2H2O(l) which has water in liquid form as a product. The given entropy is labeled for H₂O(g), but the value 69.9 J K⁻¹ mol⁻¹ is typical for liquid water (H₂O(l)). Therefore, we will use this value for H₂O(l), assuming a labeling error. So, S∘(H2O(l))=69.9 J K−1 mol−1.
The standard entropy change for the reaction, ΔS°, is calculated as the difference between the sum of the standard entropies of the products and the sum of the standard entropies of the reactants:
ΔS∘=[∑Sproducts∘]−[∑Sreactants∘]
First, identify the products and reactants:
Products: 1 mol of CO₂(g) and 2 mol of H₂O(l).
Reactants: 1 mol of CH₄(g) and 2 mol of O₂(g).
Sum of standard entropies of products:
∑Sproducts∘=S∘(CO2)+2×S∘(H2O(l))
Substitute the values:
=213.6+2×69.9
Multiply 2 by 69.9:
2×69.9=139.8
Now add to 213.6:
213.6+139.8=353.4
So, ∑Sproducts∘=353.4 J K−1 mol−1
Sum of standard entropies of reactants:
∑Sreactants∘=S∘(CH4)+2×S∘(O2)
Substitute the values:
=186.2+2×205.2
Multiply 2 by 205.2:
2×205.2=410.4
Now add to 186.2:
186.2+410.4=596.6
So, ∑Sreactants∘=596.6 J K−1 mol−1
Now, calculate ΔS°:
ΔS∘=∑Sproducts∘−∑Sreactants∘=353.4−596.6
Subtract 596.6 from 353.4:
353.4−596.6=−243.2
So, ΔS∘=−243.2 J K−1 mol−1
Now, compare with the given options:
A. −312.5 J K−1 mol−1
B. −242.8 J K−1 mol−1
C. −108.1 J K−1 mol−1
D. −37.6 J K−1 mol−1
The calculated value is -243.2 J K⁻¹ mol⁻¹, which is closest to option B (-242.8 J K⁻¹ mol⁻¹). Considering possible rounding in the options or given values, and as the correct answer is indicated as option B, we select this option.
Hence, the correct answer is Option B.
Q 39ChemistrySection A • MCQthermodynamics
+4 / -1
The standard enthalpy of formation (ΔfH298∘) for methane, CH4 is −74.9 kJ mol−1. In order to calculate the average energy given out in the formation of a C-H bond from this it is necessary to know which one of the following?
A
The dissociation energy of the hydrogen molecule, H2.
B
The first four ionisation energies of carbon.
C
The dissociation energy of H2 and enthalpy and sublimation of carbon (graphite).
D
The first four ionisation energies of carbon and electron affinity of hydrogen.
Official Correct Answer:Option (C)
Step-by-Step Solution:
To calculate the average C−H bond energy from the standard enthalpy of formation of methane (ΔfH∘), one must convert the elements from their standard states into isolated gaseous atoms using Hess's Law. This requires knowing both the enthalpy of sublimation of carbon, C(graphite)→C(g), and the bond dissociation energy of hydrogen, H2(g)→2H(g).
Combining these values allows to determine the total atomization energy of methane (ΔHatomization). Dividing this total energy by 4 yields the average energy of a single C−H bond.
Q 40ChemistrySection A • MCQchemical equilibrium
+4 / -1
What happens when an inert gas is added to an equilibrium keeping volume unchanged?
A
More product will form
B
Less product will form
C
More reactant will form
D
Equilibrium will remain unchanged
Official Correct Answer:Option (D)
Step-by-Step Solution:
When an inert gas is added to a system at equilibrium with the volume kept unchanged, we need to analyze the effect on the equilibrium. An inert gas does not react with any of the reactants or products. Therefore, it does not participate in the chemical reaction.
The equilibrium constant for a reaction, denoted as Kc, is expressed in terms of concentrations. For a general reaction:
aA+bB⇌cC+dD
the equilibrium constant is:
Kc=[A]a[B]b[C]c[D]d
where [A], [B], [C], and [D] are the molar concentrations of the species. Concentration is defined as the number of moles per unit volume, so [A]=VnA, and similarly for others.
When an inert gas is added at constant volume:
The volume V remains the same.
The number of moles of the reactants and products (e.g., nA, nB, nC, nD) does not change because the inert gas does not react with them.
Therefore, the concentrations of the reactants and products remain unchanged. For example:
[A]new=VnA=[A]initial
and similarly for B, C, and D.
Since the concentrations are unchanged, the reaction quotient Qc (which has the same expression as Kc) remains equal to Kc:
Qc=[A]a[B]b[C]c[D]d=Kc
Because Qc=Kc, the system remains at equilibrium. There is no shift in the equilibrium position towards reactants or products.
Although the total pressure increases due to the addition of the inert gas, pressure changes only affect the equilibrium if the volume changes (which alters concentrations) or if the reaction involves a change in the number of moles of gas. Here, volume is constant, and the inert gas does not alter the mole numbers of the reacting species, so the equilibrium is unaffected.
Hence, the correct answer is Option D.
Q 41ChemistrySection A • MCQionic equilibrium
+4 / -1
The conjugate base of hydrazoic acid is:
A
N−3
B
N3−
C
N2−
D
HN3−
Official Correct Answer:Option (B)
Step-by-Step Solution:
Hydrazoic acid is a chemical compound with the formula HN₃. It is an acid, meaning it can donate a proton (H⁺ ion). The conjugate base of an acid is formed when the acid loses one proton (H⁺).
For hydrazoic acid (HN₃), the dissociation reaction can be written as:
HN3→H++N3−
When HN₃ loses a proton (H⁺), the remaining species is N₃⁻. Therefore, the conjugate base of hydrazoic acid is N₃⁻.
Now, let's examine the options:
Option A: N⁻³ (written as N−3) represents the nitride ion, which is not related to hydrazoic acid. The nitride ion is the conjugate base of ammonia (NH₃) after losing three protons, but hydrazoic acid loses only one proton.
Option B: N3− represents N₃⁻, which matches the conjugate base we derived from HN₃.
Option C: N2− represents N₂⁻, which is not the conjugate base of hydrazoic acid. Hydrazoic acid has three nitrogen atoms, so losing a proton should leave N₃⁻, not N₂⁻.
Option D: HN3− represents HN₃⁻, which implies the acid molecule with an extra electron. This is incorrect because the conjugate base is formed by losing a proton (H⁺), not gaining an electron.
Therefore, the conjugate base of hydrazoic acid is N₃⁻, which corresponds to Option B.
Hence, the correct answer is Option B.
Q 42ChemistrySection A • MCQhydrogen
+4 / -1
Hydrogen peroxide acts both as an oxidising and as a reducing agent depending upon the nature of the reacting species. In which of the following cases H2O2 acts as a reducing agent in acid medium?
A
MnO4−
B
Cr2O72−
C
SO32−
D
KI
Official Correct Answer:Option (A)
Step-by-Step Solution:
H2O2 acts as a reducing agent only in presence of strong oxidising agents (i.e., MnO4−).
2MnO4−+6H++5H2O2→2Mn2++8H2O+5O2
Q 43ChemistrySection A • MCQbasics of organic chemistry
+4 / -1
Which one of the following acids does not exhibit optical isomerism?
A
Lactic acid
B
Tartaric acid
C
Maleic acid
D
α-amino acids
Official Correct Answer:Option (C)
Step-by-Step Solution:
To determine which acid does not exhibit optical isomerism, we must recall that optical isomerism arises when a molecule has a chiral center, typically a carbon atom with four different substituents, and the molecule lacks a plane of symmetry. A chiral molecule is non-superimposable on its mirror image. Let's examine each option step by step.
Starting with option A: Lactic acid. Its molecular formula is CH3CH(OH)COOH. The central carbon atom (the one attached to the OH group) is bonded to four different groups: a hydrogen atom (H), a hydroxyl group (OH), a methyl group (CH3), and a carboxyl group (COOH). Since all four groups are distinct, this carbon is a chiral center. Therefore, lactic acid exhibits optical isomerism and exists as two enantiomers.
Next, option B: Tartaric acid. Its molecular formula is HOOCCH(OH)CH(OH)COOH. This molecule has two carbon atoms, each bonded to an OH group. Each of these carbons is attached to four different groups: H, OH, COOH, and the other CH(OH)COOH group. Thus, both carbons are chiral centers. Tartaric acid exists in three stereoisomeric forms: the d-form, the l-form (which are enantiomers and optically active), and the meso-form (which has a plane of symmetry and is optically inactive due to internal compensation). However, since tartaric acid can exist in optically active forms (the d- and l-enantiomers), it does exhibit optical isomerism.
Now, option C: Maleic acid. Maleic acid is the cis-isomer of butenedioic acid, with the formula HOOCCH=CHCOOH. The structure can be represented as:
HCOOH\C=C/COOHH
In maleic acid, the double bond between the two carbon atoms restricts rotation. Each carbon in the double bond is sp² hybridized and bonded to three atoms: one hydrogen (H), one carboxyl group (COOH), and the other carbon via the double bond. Since neither carbon has four substituents, there are no chiral centers. Additionally, the molecule is planar and has a plane of symmetry that bisects the double bond and aligns the two identical halves, making it achiral. Therefore, maleic acid does not exhibit optical isomerism.
Finally, option D: α-amino acids. These have the general formula R−CH(NH2)COOH, where the α-carbon is bonded to four groups: a hydrogen atom (H), an amino group (NH2), a carboxyl group (COOH), and a side chain (R). For most α-amino acids, R is different from H, NH2, and COOH, making the α-carbon a chiral center. For example, alanine (R = CH3) has a chiral center and exhibits optical isomerism. However, glycine is an exception where R = H, so the α-carbon has two identical H atoms and is not chiral. Despite glycine not exhibiting optical isomerism, the class of α-amino acids as a whole includes compounds that do exhibit optical isomerism (like alanine). Therefore, this option does not universally lack optical isomerism.
Comparing all options, lactic acid (A) and tartaric acid (B) exhibit optical isomerism due to chiral centers. α-amino acids (D) include some that exhibit optical isomerism. Maleic acid (C) has no chiral center and is achiral, so it does not exhibit optical isomerism.
Hence, the correct answer is Option C.
Q 44ChemistrySection A • MCQhydrocarbons
+4 / -1
on mercuration-demercuration produces the major product:
A
B
C
D
Official Correct Answer:Option (A)
Step-by-Step Solution:
The reagent Hg(OAc)2/H2O followed by NaBH4 adds an −OH group to the more substituted carbon of the alkene and an −H to the less substituted carbon.
Unlike acid-catalyzed hydration, this process occurs via a cyclic mercurinium ion intermediate, which prevents carbocation rearrangement.
For allylbenzene, the more substituted carbon in the vinyl group is the secondary carbon (C2).
The major product is therefore 1-phenylpropan-2-ol.
Q 45ChemistrySection A • MCQhydrocarbons
+4 / -1
In the presence of peroxide, HCl and HI do not give anti-Markownikoff's addition of alkenes because:
A
One of the steps is endothermic in HCl and HI
B
Both HCl and HI are strong acids
C
HCl is oxidizing and the HI is reducing
D
All the steps are exothermic is HCl and HI
Official Correct Answer:Option (A)
Step-by-Step Solution:
Anti-Markownikoff addition is possible only in case of HBr and not in HCl and HI. In HBr, both the chain initiation and propagation steps are exothermic, while in HCl, first step is exothermic, and second step is endothermic. In HI, the first step is heavily endothermic, and the second step is exothermic. Hence HCl and HI do not undergo anti-Markownikoff’s addition.
Q 46ChemistrySection A • MCQenvironmental chemistry
+4 / -1
Global warming is due to increase of:
A
methane and nitrous oxide in atmosphere
B
methane and CO2 in atmosphere
C
methane and O3 in atmosphere
D
methane and CO in atmosphere
Official Correct Answer:Option (B)
Step-by-Step Solution:
Global warming refers to the long-term rise in Earth's average surface temperature, primarily caused by the accumulation of greenhouse gases in the atmosphere. These gases trap heat from the sun, preventing it from escaping back into space, which leads to a warming effect known as the greenhouse effect.
Now, let us examine the options one by one:
Option A mentions methane and nitrous oxide. Methane (CH4) is a potent greenhouse gas, and nitrous oxide (N2O) also contributes to global warming. However, carbon dioxide (CO2) is the most significant greenhouse gas in terms of total emissions and long-term impact, so this pair is incomplete.
Option B mentions methane and CO2. Methane is a major greenhouse gas with high heat-trapping ability, though it has a shorter atmospheric lifetime than CO2. Carbon dioxide is the primary driver of global warming, accounting for the largest share of human-induced greenhouse gas emissions from sources like fossil fuel combustion and deforestation. Together, methane and CO2 represent two of the most critical gases responsible for global warming.
Option C mentions methane and ozone (O3). While ozone in the lower atmosphere (troposphere) acts as a greenhouse gas, its contribution is secondary compared to CO2. Ozone is also not directly emitted in large quantities but forms from other pollutants. This pair does not emphasize the dominant role of CO2.
Option D mentions methane and carbon monoxide (CO). Carbon monoxide is not a direct greenhouse gas. It can indirectly contribute to warming by reacting to form CO2 or ozone, but it is not a primary cause. Methane is relevant, but CO2's absence makes this pair incorrect.
Scientific consensus identifies carbon dioxide as the principal greenhouse gas, with methane being the second most significant. Human activities have substantially increased atmospheric concentrations of both, making them key contributors to global warming. Hence, Option B accurately identifies the increase of methane and CO2 as the cause.
So, the answer is Option B.
Q 47ChemistrySection A • MCQsolid state
+4 / -1
In a monoclinic unit cell, the relation of sides and angles are respectively:
A
a = b = c and α=β=γ=90°
B
a = b = c and α=β=γ=90°
C
a = b = c and β=γ=90° =α
D
a = b = c and α=β=γ=90°
Official Correct Answer:Option (C)
Step-by-Step Solution:
In crystallography, the monoclinic crystal system is one of the seven crystal systems. To solve this, we need to recall the defining characteristics of a monoclinic unit cell regarding the lengths of its edges (denoted as a, b, c) and the angles between them (denoted as α, β, γ).
First, for the sides (edge lengths) in a monoclinic unit cell, all three edges are of different lengths. This means that a is not equal to b, b is not equal to c, and a is not equal to c. So, we have a=b=c.
Second, for the angles, in a monoclinic system, two of the angles are exactly 90 degrees, and one angle is not equal to 90 degrees. Specifically, in the standard convention, the angle β (between the a-axis and c-axis) is not 90 degrees, while the angles α (between the b-axis and c-axis) and γ (between the a-axis and b-axis) are both 90 degrees. However, the labeling of axes can vary, and the monoclinic system can be described equivalently by having any one angle not equal to 90 degrees while the other two are 90 degrees, as long as the side lengths are unequal.
Now, let's examine the given options:
Option A states: a = b = c and α=β=γ=90°. This describes a tetragonal system, where two sides are equal and all angles are 90 degrees, which is not monoclinic.
Option B states: a = b = c and α=β=γ=90°. This describes an orthorhombic system, where all sides are unequal but all angles are 90 degrees, which is not monoclinic.
Option C states: a = b = c and β=γ=90° =α. This means the sides are all unequal, and angles β and γ are 90 degrees, while α is not 90 degrees. Although the standard monoclinic system has β not equal to 90 degrees (with α and γ at 90 degrees), this option describes a valid monoclinic system because the geometry is equivalent under a relabeling of axes. For example, if we swap the b and c axes, the non-right angle becomes α, matching this description. Thus, this option correctly represents the monoclinic system.
Option D states: a = b = c and α=β=γ=90°. This describes a triclinic system, where all angles are different and not 90 degrees, which is not monoclinic.
Therefore, after comparing all options, Option C matches the monoclinic unit cell characteristics when considering the flexibility in axis labeling.
Hence, the correct answer is Option C.
Q 48ChemistrySection A • MCQelectrochemistry
+4 / -1
How many electrons would be required to deposit 6.35 g of copper at the cathode during the electrolysis of an aqueous solution of copper sulphate? (Atomic mass of copper = 63.5u, NA = Avogadro's constant):
A
20NA
B
10NA
C
5NA
D
2NA
Official Correct Answer:Option (C)
Step-by-Step Solution:
To determine the number of electrons required to deposit 6.35 g of copper during electrolysis, we start by recalling the reaction at the cathode. Copper ions are reduced to copper metal: Cu2++2e−→Cu. This indicates that 1 mole of copper atoms (Cu) requires 2 moles of electrons for deposition.
The atomic mass of copper is given as 63.5 u, so the molar mass is 63.5 g/mol. We need to find the number of moles in 6.35 g of copper. The moles of copper are calculated as: moles of Cu=molar massmass=63.56.35.
Simplifying the fraction: 63.56.35=63.5÷6.356.35÷6.35=101=0.1. Thus, we have 0.1 moles of copper.
Since 1 mole of copper requires 2 moles of electrons, the moles of electrons needed for 0.1 moles of copper are: 0.1×2=0.2 moles of electrons.
Avogadro's constant, denoted as NA, represents the number of electrons in one mole of electrons. Therefore, the number of electrons required is: 0.2×NA.
Expressing 0.2 as a fraction: 0.2=102=51. So, the number of electrons is: 51×NA=5NA.
Comparing with the options:
A: 20NA
B: 10NA
C: 5NA
D: 2NA
The expression 5NA matches option C.
Hence, the correct answer is Option C.
Q 49ChemistrySection A • MCQchemical kinetics
+4 / -1
The rate coefficient (k) for a particular reactions is 1.3×10−4 M−1 s−1 at 100°C, and 1.3×10−3 M−1 s−1 at 150°C. What is the energy of activation (EA) (in kJ) for this reaction? (R = molar gas constant = 8.314 JK−1 mol−1)
A
16
B
60
C
99
D
132
Official Correct Answer:Option (B)
Step-by-Step Solution:
The activation energy (EA) can be found using the Arrhenius equation, which relates the rate constant (k) to temperature (T) and activation energy. The formula for two different temperatures is:
ln(k1k2)=REA(T11−T21)
where:
k1 and k2 are the rate constants at temperatures T1 and T2 respectively,
R is the gas constant (8.314 J K⁻¹ mol⁻¹),
EA is the activation energy in J/mol.
First, convert the temperatures from Celsius to Kelvin:
T1=100∘C+273=373K
T2=150∘C+273=423K
Given:
k1=1.3×10−4M−1s−1
k2=1.3×10−3M−1s−1
Calculate the ratio k1k2:
k1k2=1.3×10−41.3×10−3=10
Take the natural logarithm of the ratio:
ln(k1k2)=ln(10)≈2.302585
Now, compute the difference in the reciprocal temperatures:
Now rearrange the Arrhenius equation to solve for EA:
EA=T11−T21R⋅ln(k1k2)
Substitute the values:
EA=0.0003178.314×2.302585
First, compute the numerator:
8.314×2.302585=19.14369169
Now divide by the denominator:
EA=0.00031719.14369169≈60402.77J/mol
Alternatively, using the exact fraction:
EA=508.314×2.302585×157779
First, compute 8.314×157779=1311774.606
Then, 1311774.606×2.302585≈3020890.06
Then, divide by 50:
503020890.06=60417.8012J/mol
Both methods give approximately 60400 J/mol. Convert to kJ/mol by dividing by 1000:
EA≈60.4kJ/mol
Rounding to the nearest whole number, EA≈60kJ/mol.
Comparing with the options:
A. 16
B. 60
C. 99
D. 132
Hence, the correct answer is Option B.
Q 50ChemistrySection A • MCQp block elements
+4 / -1
Which of the following xenon-oxo compounds may not be obtained by hydrolysis of xenon fluorides?
A
XeO2F2
B
XeOF4
C
XeO3
D
XeO4
Official Correct Answer:Option (D)
Step-by-Step Solution:
To solve this question, we need to determine which xenon-oxo compound cannot be obtained through the hydrolysis of xenon fluorides. Xenon fluorides include XeF2, XeF4, and XeF6. Hydrolysis involves reacting these fluorides with water to form various xenon-oxygen compounds. Let's examine the hydrolysis products of each xenon fluoride step by step.
First, consider XeF2. When hydrolyzed, it decomposes to xenon gas, hydrogen fluoride, and oxygen or hydrogen peroxide. The reactions are:
2XeF2+2H2O→2Xe+4HF+O2
or alternatively,
XeF2+2H2O→Xe+2HF+H2O2
In both cases, no stable xenon-oxo compound is formed. Therefore, hydrolysis of XeF2 does not yield any of the listed oxo compounds.
Next, consider XeF4. It undergoes slow hydrolysis and disproportionation. The reaction is:
6XeF4+12H2O→4Xe+2XeO3+24HF+3O2
Here, xenon trioxide (XeO3) is produced as a stable product. Thus, hydrolysis of XeF4 yields XeO3.
Now, consider XeF6, which undergoes hydrolysis in stages:
Therefore, hydrolysis of XeF6 yields XeOF4, XeO2F2, and XeO3.
Summarizing the compounds obtained by hydrolysis:
XeO2F2 is obtained from hydrolysis of XeOF4 (which comes from XeF6).
XeOF4 is obtained from partial hydrolysis of XeF6.
XeO3 is obtained from hydrolysis of XeF4 or complete hydrolysis of XeF6.
Now, consider xenon tetroxide (XeO4). It is not prepared by hydrolysis of any xenon fluoride. Instead, it is synthesized by treating sodium perxenate (Na4XeO6) with concentrated sulfuric acid:
Na4XeO6+2H2SO4→XeO4+2Na2SO4+2H2O
No hydrolysis reaction of xenon fluorides produces XeO4.
Therefore, among the options, XeO4 may not be obtained by hydrolysis of xenon fluorides.
Hence, the correct answer is Option D.
Q 51ChemistrySection A • MCQd and f block elements
+4 / -1
Which one of the following exhibits the large number of oxidation states?
A
Ti(22)
B
V(23)
C
Cr(24)
D
Mn(25)
Official Correct Answer:Option (D)
Step-by-Step Solution:
The question asks which element exhibits the largest number of oxidation states among titanium (Ti, atomic number 22), vanadium (V, 23), chromium (Cr, 24), and manganese (Mn, 25). Oxidation states represent the hypothetical charges an atom would have if all bonds were ionic, and transition metals show variable oxidation states due to the involvement of both ns and (n-1)d electrons in bonding.
First, recall the electron configurations:
Titanium (Ti, 22): [Ar] 4s² 3d²
Vanadium (V, 23): [Ar] 4s² 3d³
Chromium (Cr, 24): [Ar] 4s¹ 3d⁵ (exception for half-filled stability)
Manganese (Mn, 25): [Ar] 4s² 3d⁵
Now, list the oxidation states each element can exhibit:
Titanium (Ti): The common oxidation states are +2 (losing 4s electrons), +3 (losing 4s and one 3d electron), and +4 (losing 4s and both 3d electrons). Less common states include 0 and +1, but typically, Ti shows 3 main oxidation states: +2, +3, +4.
Vanadium (V): The oxidation states include +2 (losing 4s electrons), +3 (losing 4s and one 3d electron), +4 (losing 4s and two 3d electrons), and +5 (losing 4s and all three 3d electrons). Less common states like +1 exist, but V primarily exhibits 4 oxidation states: +2, +3, +4, +5.
Chromium (Cr): Oxidation states range from +1 to +6. Specifically:
+1: losing the 4s electron (rare)
+2: losing the 4s electron
+3: losing 4s and one 3d electron
+4: losing 4s and two 3d electrons
+5: losing 4s and three 3d electrons
+6: losing 4s and all five 3d electrons (as in CrO₃)
Manganese (Mn): Oxidation states range from +1 to +7. Specifically:
+1: losing one 4s electron (in some complexes)
+2: losing both 4s electrons (e.g., MnCl₂)
+3: losing both 4s and one 3d electron (e.g., Mn₂O₃)
+4: losing both 4s and two 3d electrons (e.g., MnO₂)
+5: losing both 4s and three 3d electrons (e.g., K₃MnO₄)
+6: losing both 4s and four 3d electrons (e.g., K₂MnO₄)
+7: losing both 4s and all five 3d electrons (e.g., KMnO₄)
Manganese exhibits 7 oxidation states: +1, +2, +3, +4, +5, +6, +7. Additionally, manganese can show states like -3, -2, -1, and 0 in specific compounds, but the positive states from +1 to +7 are well-documented.
Comparing the number of oxidation states:
Ti: 3 main states (+2, +3, +4)
V: 4 main states (+2, +3, +4, +5)
Cr: 6 states (+1 to +6)
Mn: 7 states (+1 to +7)
Manganese exhibits the largest number of oxidation states (7) among the given options.
The reason for manganese having the highest number is its electron configuration ([Ar] 4s² 3d⁵). It can lose up to 7 electrons (both 4s and all five 3d electrons) to achieve the +7 state, and it also forms stable compounds in lower oxidation states due to the half-filled d-subshell stability.
Hence, the correct answer is Option D.
Q 52ChemistrySection A • MCQd and f block elements
+4 / -1
Copper becomes green when exposed to moist air for a long period. This is due to:
A
the formation of a layer of cupric oxide on the surface of copper.
B
the formation of a layer of basic carbonate of copper on the surface of copper.
C
the formation of a layer of cupric hydroxide on the surface of copper.
D
the formation of basic copper sulphate layer on the surface of the metal.
Official Correct Answer:Option (B)
Step-by-Step Solution:
Copper becomes green when exposed to moist air for a long period. This is due to the formation of a layer of basic carbonate of copper on the surface of copper.
Chemical Reaction: Cu+H2O+CO2+O2→Cu(OH)2+CuCO3
Q 53ChemistrySection A • MCQcoordination compounds
+4 / -1
Among the following species the one which causes the highest CFSE, Δ0 as a ligand is:
A
CN−
B
NH3
C
F−
D
CO
Official Correct Answer:Option (D)
Step-by-Step Solution:
The question asks which ligand causes the highest crystal field stabilization energy (CFSE), denoted as Δ₀, among CN⁻, NH₃, F⁻, and CO. CFSE depends on the magnitude of the crystal field splitting, Δ₀, which varies with the ligand. Ligands that cause larger Δ₀ lead to higher CFSE.
To determine the ligand that causes the largest Δ₀, we refer to the spectrochemical series. This series orders ligands based on their ability to split the d-orbitals in an octahedral field, from weakest to strongest field. The standard spectrochemical series is:
Option C: F⁻ is a weak field ligand and appears early in the series, causing small Δ₀.
Option B: NH₃ is stronger than F⁻ and appears after F⁻ in the series, so it causes a larger Δ₀ than F⁻.
Option A: CN⁻ is a strong field ligand and appears near the end of the series, causing large Δ₀.
Option D: CO is the strongest field ligand in this list and appears after CN⁻ in the series, meaning it causes the largest Δ₀.
CO causes the highest splitting because it is a strong π-acceptor ligand due to its empty π* orbitals, which allow for effective back-bonding with the metal, leading to greater stabilization and larger Δ₀ compared to CN⁻, NH₃, and F⁻.
Therefore, CO causes the highest CFSE, Δ₀.
Hence, the correct answer is Option D.
Q 54ChemistrySection A • MCQcoordination compounds
+4 / -1
Which one of the following complexes will most likely absorb visible light? (At. nos. Sc = 21, Ti = 22, V = 23, Zn = 30)
A
[Sc(H2O)6]3+
B
[Ti(NH3)6]4+
C
[V(NH3)6]3+
D
[Zn(NH3)6]2+
Official Correct Answer:Option (C)
Step-by-Step Solution:
To determine which complex is most likely to absorb visible light, we need to understand that absorption of visible light in transition metal complexes occurs due to d-d transitions. These transitions happen when an electron moves from a lower energy d orbital to a higher energy d orbital within the same subshell. For this to occur, the central metal ion must have partially filled d orbitals. If the d orbitals are completely empty (d⁰) or completely filled (d¹⁰), no d-d transitions are possible, and the complex will not absorb visible light in the typical range for such transitions.
Let's examine the electron configurations of the metal ions in each complex:
Scandium (Sc, atomic number 21): The neutral atom has configuration [Ar] 4s² 3d¹. For Sc³⁺, it loses three electrons (two from 4s and one from 3d), resulting in [Ar] 3d⁰.
Titanium (Ti, atomic number 22): Neutral atom is [Ar] 4s² 3d². For Ti⁴⁺, it loses four electrons (two from 4s and two from 3d), giving [Ar] 3d⁰.
Vanadium (V, atomic number 23): Neutral atom is [Ar] 4s² 3d³. For V³⁺, it loses three electrons (two from 4s and one from 3d), so the configuration is [Ar] 3d².
Zinc (Zn, atomic number 30): Neutral atom is [Ar] 4s² 3d¹⁰. For Zn²⁺, it loses two electrons from the 4s orbital, resulting in [Ar] 3d¹⁰.
Now, analyze each complex:
Option A: [Sc(H₂O)₆]³⁺
The central ion is Sc³⁺, which has a 3d⁰ configuration. Since there are no d electrons, d-d transitions cannot occur. Water (H₂O) is a weak field ligand, but even with splitting, no electrons are present to transition. Thus, this complex does not absorb visible light via d-d transitions.
Option B: [Ti(NH₃)₆]⁴⁺
The central ion is Ti⁴⁺, with a 3d⁰ configuration. Again, no d electrons are present, so d-d transitions are impossible. Ammonia (NH₃) is a strong field ligand, but without electrons, splitting is irrelevant. This complex will not absorb visible light due to d-d transitions.
Option C: [V(NH₃)₆]³⁺
The central ion is V³⁺, with a 3d² configuration. Partially filled d orbitals allow d-d transitions. Ammonia (NH₃) is a strong field ligand, creating a large splitting energy (Δ₀) in the octahedral complex. For d², the electrons can occupy the t₂g orbitals, and transitions to the e_g level are possible. This complex can absorb visible light.
Option D: [Zn(NH₃)₆]²⁺
The central ion is Zn²⁺, with a 3d¹⁰ configuration. The d orbitals are fully filled, so no empty orbitals are available for d-d transitions. Ammonia (NH₃) causes splitting, but electrons cannot move within the d subshell as all orbitals are occupied. Thus, this complex does not absorb visible light via d-d transitions.
Comparing all options, only [V(NH₃)₆]³⁺ (option C) has a metal ion with partially filled d orbitals (d²), enabling d-d transitions and absorption of visible light.
Hence, the correct answer is Option C.
Q 55ChemistrySection A • MCQhaloalkanes and haloarenes
+4 / -1
Conversion of benzene diazonium chloride to chlorobenzene is an example of which of the following reactions?
A
Claisen
B
Friedel-craft
C
Sandmeyer
D
Wurtz
Official Correct Answer:Option (C)
Step-by-Step Solution:
The conversion of benzene diazonium chloride to chlorobenzene involves replacing the diazonium group (−N₂⁺Cl⁻) with a chlorine atom. The reaction is:
C6H5N2Cl−>C6H5Cl+N2
Now, let's examine each option:
Option A: Claisen reaction - This typically refers to condensation or rearrangement reactions involving carbonyl compounds, such as esters forming β-keto esters. It does not apply to diazonium salt conversions.
Option B: Friedel-Crafts reaction - This is an electrophilic aromatic substitution where halogens or alkyl groups are introduced using catalysts like AlCl₃. For example, benzene reacts with Cl₂/AlCl₃ to form chlorobenzene. However, here we start from benzene diazonium chloride, not benzene, so this is incorrect.
Option C: Sandmeyer reaction - This reaction specifically converts aryl diazonium salts to aryl halides using copper(I) halides. For chlorobenzene, benzene diazonium chloride reacts with CuCl:
C6H5N2Cl+CuCl−>C6H5Cl+N2+CuCl
This matches the given conversion exactly.
Option D: Wurtz reaction - This couples alkyl halides with sodium metal to form higher alkanes (e.g., 2CH₃Br + 2Na → CH₃CH₃ + 2NaBr). It does not involve diazonium salts.
Therefore, the conversion is a Sandmeyer reaction.
Hence, the correct answer is Option C.
Q 56ChemistrySection A • MCQhydrocarbons
+4 / -1
The major product obtained in the photo catalysed bromination of 2-methylbutane is:
A
1-bromo-2-methylbutane
B
1-bromo-3-methylbutane
C
2-bromo-3-methylbutane
D
2-bromo-2-methylbutane
Official Correct Answer:Option (D)
Step-by-Step Solution:
The photo-catalysed bromination of 2-methylbutane is a free radical substitution reaction. Under UV light, bromine molecules (Br2) undergo homolytic cleavage to form bromine radicals (Br∙). These radicals abstract hydrogen atoms from the alkane, leading to alkyl radicals. The stability of the alkyl radical determines the major product, as bromination is selective for the most stable radical.
The structure of 2-methylbutane is CH3−CH(CH3)−CH2−CH3. We identify the types of hydrogen atoms:
The hydrogen on the carbon at position 2 (the carbon with the methyl group) is tertiary (3°), as this carbon is bonded to three other carbons. There is one such hydrogen.
The hydrogens on the carbon at position 3 (CH2) are secondary (2°). There are two such hydrogens.
The hydrogens on the terminal methyl groups (positions 1, 4, and the methyl branch on carbon 2) are primary (1°). Specifically:
Position 1 (CH3- attached to carbon 2): 3 hydrogens.
The methyl branch on carbon 2: 3 hydrogens.
Position 4 (CH3): 3 hydrogens.
Total primary hydrogens: 9.
The stability order of alkyl radicals is tertiary > secondary > primary. Bromine radicals preferentially abstract the tertiary hydrogen due to its higher stability, even though there is only one tertiary hydrogen compared to multiple primary and secondary hydrogens.
The product is 2-bromo-2-methylbutane (CH3−CBr(CH3)−CH2−CH3).
Comparing with the options:
Option A: 1-bromo-2-methylbutane (BrCH2−CH(CH3)−CH2−CH3) is a primary bromide.
Option B: 1-bromo-3-methylbutane likely refers to CH3CH(CH3)CH2CH2Br, which is also a primary bromide.
Option C: 2-bromo-3-methylbutane (CH3CHBrCH(CH3)CH3) is a secondary bromide.
Option D: 2-bromo-2-methylbutane (CH3CBr(CH3)CH2CH3) is a tertiary bromide.
Due to the high selectivity of bromine for tertiary hydrogens (relative rate approximately 1600 times that of primary), the major product is the tertiary bromide, 2-bromo-2-methylbutane.
Hence, the correct answer is Option D.
Q 57ChemistrySection A • MCQalcohols phenols and ethers
+4 / -1
In the Victor-Meyer's test, the colour given by 1°, 2° and 3° alcohols are respectively:
A
Red, colourless, blue
B
Red, blue, colourless
C
Colourless, red, blue
D
Red, blue, violet
Official Correct Answer:Option (B)
Step-by-Step Solution:
In the Victor-Meyer's test, alcohols are classified as primary (1°), secondary (2°), or tertiary (3°) based on the colour they produce. The test involves several steps:
First, the alcohol is converted to an alkyl iodide using iodine and red phosphorus. Then, the alkyl iodide reacts with silver nitrite to form a nitroalkane. The nitroalkane is treated with nitrous acid (generated from sodium nitrite and hydrochloric acid), and finally, the mixture is made alkaline with sodium hydroxide.
The colour observed depends on the type of alcohol:
For a primary alcohol (1°), the nitroalkane formed is primary. This primary nitroalkane reacts with nitrous acid to form a nitrolic acid. When treated with sodium hydroxide, the nitrolic acid gives a red colour.
For a secondary alcohol (2°), the nitroalkane formed is secondary. This secondary nitroalkane reacts with nitrous acid to form a pseudonitrol (a nitroso compound), which appears blue.
For a tertiary alcohol (3°), no reaction occurs in the initial steps because tertiary alcohols undergo dehydration to form alkenes instead of alkyl iodides. Therefore, no nitro compound is formed, and the mixture remains colourless.
So, the colours given by 1°, 2°, and 3° alcohols are red, blue, and colourless, respectively.
Now, comparing with the options:
Option A: Red, colourless, blue → Incorrect, as it assigns colourless to 2° and blue to 3°.
Option B: Red, blue, colourless → Correct, as it matches red for 1°, blue for 2°, and colourless for 3°.
Option C: Colourless, red, blue → Incorrect, as it assigns colourless to 1° and blue to 3°.
Option D: Red, blue, violet → Incorrect, as it assigns violet to 3° instead of colourless.
Hence, the correct answer is Option B.
Q 58ChemistrySection A • MCQaldehydes ketones and carboxylic acids
+4 / -1
Phthalic acid reacts with resorcinol in the presence of concentrated H2SO4 to give:
A
Phenolphthalein
B
Alizarin
C
Coumarin
D
Fluorescein
Official Correct Answer:Option (D)
Step-by-Step Solution:
Phthalic acid, when heated with concentrated sulfuric acid, first dehydrates to form phthalic anhydride. The reaction then proceeds with phthalic anhydride acting as an electrophile.
Resorcinol (1,3-dihydroxybenzene) has a highly activated benzene ring due to the presence of two electron-donating hydroxyl groups in the meta position. The ortho and para positions relative to each hydroxyl group are nucleophilic sites.
In the presence of concentrated H₂SO₄, phthalic anhydride undergoes electrophilic substitution with resorcinol. The carbonyl carbon of the anhydride attacks the para position of one hydroxyl group in resorcinol (specifically, the position between the two hydroxyl groups, which is highly activated). This forms an intermediate keto-acid:
This intermediate undergoes intramolecular cyclization: the carboxylic acid group attacks the ortho position relative to the other hydroxyl group in the resorcinol moiety. This forms a six-membered lactone ring, releasing a water molecule. The resulting compound is fluorescein, which has a xanthene ring system fused to a benzoic acid derivative.
Now, evaluating the options:
Option A (Phenolphthalein) is formed from phthalic anhydride and phenol (not resorcinol).
Option B (Alizarin) is formed from phthalic anhydride and catechol (1,2-dihydroxybenzene).
Option C (Coumarin) is formed from salicylaldehyde and acetic anhydride, not from phthalic acid and resorcinol.
Option D (Fluorescein) matches the product of phthalic anhydride and resorcinol.
Hence, the correct answer is Option D.
Q 59ChemistrySection A • MCQchemistry in everyday life
+4 / -1
Aminoglycosides are usually used as:
A
antibiotic
B
analgesic
C
hypnotic
D
antifertility
Official Correct Answer:Option (A)
Step-by-Step Solution:
Aminoglycosides are a class of medications that are primarily known for their antibacterial properties. They work by inhibiting protein synthesis in bacteria, which prevents the bacteria from growing and multiplying. This makes them effective against a variety of bacterial infections, especially those caused by Gram-negative bacteria.
Now, let's examine the given options:
Option A: Antibiotic - This refers to a substance that kills or inhibits the growth of bacteria.
Option B: Analgesic - This refers to a drug that relieves pain.
Option C: Hypnotic - This refers to a drug that induces sleep.
Option D: Antifertility - This refers to a drug that prevents conception or fertility.
Since aminoglycosides specifically target bacteria and are used to treat bacterial infections, they fall under the category of antibiotics. Common examples include gentamicin, tobramycin, and amikacin, which are prescribed for serious infections like sepsis, urinary tract infections, and certain types of pneumonia.
Therefore, aminoglycosides are classified as antibiotics.
Hence, the correct answer is Option A.
Q 60ChemistrySection A • MCQbiomolecules
+4 / -1
Which of the following will not show mutarotation?
A
Maltose
B
Lactose
C
Glucose
D
Sucrose
Official Correct Answer:Option (D)
Step-by-Step Solution:
Mutarotation is the change in optical rotation observed when a sugar is dissolved in water due to the equilibrium between its alpha and beta anomers. This occurs only if the anomeric carbon is free and not involved in a glycosidic bond.
Let's examine each option:
Option A: Maltose
Maltose is a disaccharide formed from two glucose units linked by an α-1,4-glycosidic bond. The anomeric carbon of the first glucose is bonded, but the second glucose has a free anomeric carbon. Therefore, maltose can undergo mutarotation.
Option B: Lactose
Lactose is a disaccharide of galactose and glucose linked by a β-1,4-glycosidic bond. The anomeric carbon of galactose is bonded, but the glucose unit has a free anomeric carbon. Hence, lactose shows mutarotation.
Option C: Glucose
Glucose is a monosaccharide with a free anomeric carbon in its cyclic form. When dissolved, it equilibrates between α-D-glucose and β-D-glucose, showing mutarotation.
Option D: Sucrose
Sucrose is a disaccharide of glucose and fructose linked by an α-1,β-2-glycosidic bond. Here, both anomeric carbons (C1 of glucose and C2 of fructose) are involved in the glycosidic bond. Neither anomeric carbon is free to open and form the open-chain aldehyde or ketone required for mutarotation. Therefore, sucrose does not show mutarotation.
Hence, the correct answer is Option D.
Q 61MathematicsSection A • MCQquadratic equations
+4 / -1
The sum of the roots of the equation, x2+∣2x−3∣−4=0, is:
A
2
B
−2
C
2
D
−2
Official Correct Answer:Option (C)
Step-by-Step Solution:
We are given the equation x2+∣2x−3∣−4=0. The absolute value ∣2x−3∣ changes behavior at the point where 2x−3=0, which is x=23. Therefore, we need to solve the equation in two cases: when x<23 and when x≥23.
Case 1:x<23
For x<23, 2x−3<0, so ∣2x−3∣=−(2x−3)=−2x+3. Substituting this into the equation:
x2+(−2x+3)−4=0
Simplify:
x2−2x+3−4=0
x2−2x−1=0
Solve this quadratic equation using the quadratic formula x=2a−b±b2−4ac, where a=1, b=−2, and c=−1.
Discriminant D=b2−4ac=(−2)2−4(1)(−1)=4+4=8.
So, x=22±8=22±22=1±2.
The roots are x=1+2 and x=1−2.
Since this case is for x<23=1.5, we check:
1+2≈1+1.414=2.414>1.5 → not valid.
1−2≈1−1.414=−0.414<1.5 → valid.
Thus, only x=1−2 is valid in this case.
Case 2:x≥23
For x≥23, 2x−3≥0, so ∣2x−3∣=2x−3. Substituting:
x2+(2x−3)−4=0
Simplify:
x2+2x−3−4=0
x2+2x−7=0
Solve using quadratic formula: a=1, b=2, c=−7.
Discriminant D=22−4(1)(−7)=4+28=32.
So, x=2−2±32=2−2±42=−1±22.
The roots are x=−1+22 and x=−1−22.
Check x≥1.5:
−1+22≈−1+2×1.414=−1+2.828=1.828>1.5 → valid.
−1−22≈−1−2.828=−3.828<1.5 → not valid.
Thus, only x=−1+22 is valid in this case.
The roots of the equation are x=1−2 and x=−1+22. The sum of the roots is:
Let z=−i be any complex number such that z+1z−1 is a purely imaginary number. Then z+z1 is:
A
0
B
any non-zero real number other than 1
C
any non-zero real number.
D
a purely imaginary number.
Official Correct Answer:Option (C)
Step-by-Step Solution:
Let z=a+bi with a,b∈R. Then z+1z−1=(a+1)+bi(a−1)+bi. Multiplying numerator and denominator by the conjugate of the denominator gives a real part equal to (a+1)2+b2(a−1)(a+1)+b2=(a+1)2+b2a2+b2−1.
For z+1z−1 to be purely imaginary, its real part must be zero: a2+b2−1=0, which means ∣z∣=1. Additionally, the imaginary part must be nonzero; the imaginary part works out to (a+1)2+b22b, so we need b=0. Also z=−1 is required for the expression to be defined.
Now consider z+z1. Since ∣z∣=1, we have z1=zˉ, so z+z1=z+zˉ=2a. This is always a real number. Since ∣z∣=1 and b=0, we have a2<1, meaning a∈(−1,1), so z+z1=2a can take any real value in (−2,2). In particular, z+z1 is any non-zero real number for any choice of z with a=0.
Q 63MathematicsSection A • MCQpermutations and combinations
+4 / -1
8-digit numbers are formed using the digits 1, 1, 2, 2, 2, 3, 4, 4. The number of such numbers in which the odd digits do no occupy odd places, is:
A
160
B
120
C
60
D
48
Official Correct Answer:Option (B)
Step-by-Step Solution:
To solve this problem, we need to form 8-digit numbers using the digits 1, 1, 2, 2, 2, 3, 4, 4, such that no odd digit occupies an odd place. The odd places in an 8-digit number are positions 1, 3, 5, and 7, while the even places are positions 2, 4, 6, and 8. The odd digits are 1 and 3 (since 1 and 3 are odd), and there are three odd digits in total: two 1's and one 3. The even digits are 2 and 4, with five even digits in total: three 2's and two 4's.
The condition requires that odd digits do not occupy odd places. Therefore, all odd digits must be placed in even places. Since there are four even places but only three odd digits, one of the even places must be occupied by an even digit. Additionally, all four odd places must be occupied by even digits because no odd digit can be there.
We can break down the arrangement into steps:
First, we need to choose which even position (out of positions 2, 4, 6, and 8) will be occupied by an even digit. The remaining three even positions will be occupied by the three odd digits. The number of ways to choose which even position gets the even digit is given by the combination formula. Since there are four even positions and we choose one, the number of ways is (14)=4.
Next, we arrange the three odd digits in the remaining three even positions. The odd digits are two identical 1's and one 3. The number of distinct arrangements for these three digits in three positions is calculated by considering the repetitions. We choose a position for the digit 3 (since the two 1's are identical), which can be done in (13)=3 ways. The other two positions automatically get the 1's. Thus, there are 3 ways to arrange the odd digits.
Now, we have five positions that must be filled with even digits: the four odd places (positions 1, 3, 5, 7) and the one chosen even position (from step 1). The even digits available are three identical 2's and two identical 4's. We need to arrange these five digits in the five positions. The number of distinct arrangements is given by the multinomial coefficient, which accounts for identical items. Specifically, we choose positions for the three 2's (or equivalently for the two 4's). The number of ways is (35)=10 (since choosing three positions for the 2's leaves the remaining two for the 4's).
To find the total number of such 8-digit numbers, we multiply the number of choices from each step: the number of ways to choose the even position for the even digit, the number of ways to arrange the odd digits in the remaining even positions, and the number of ways to arrange the even digits in the five designated positions. Therefore, the total is 4×3×10=120.
This satisfies the condition that no odd digit occupies an odd place, as all odd digits are in even positions, and all odd positions have even digits.
Hence, the correct answer is Option B.
Q 64MathematicsSection A • MCQsequences and series
+4 / -1
Let G be the geometric mean of two positive numbers a and b, and M be the arithmetic mean of a1 and b1. If M1 : G is 4 : 5, then a : b can be:
A
1 : 4
B
1 : 2
C
2 : 3
D
3 : 4
Official Correct Answer:Option (A)
Step-by-Step Solution:
We are given two positive numbers a and b. The geometric mean G of a and b is defined as G=ab. The arithmetic mean M of a1 and b1 is given by M=2a1+b1. Simplifying M, we get:
M=2a1+b1=2abb+a=2aba+b.
The problem states that M1:G=4:5, which means the ratio of M1 to G is 4 to 5. This can be written as:
GM1=54⇒M⋅G1=54⇒M⋅G=45.
Substituting the expressions for M and G, we have:
(2aba+b)⋅ab=45.
Simplify the left side:
2aba+b⋅ab=2ab⋅aba+b⋅ab=2aba+b.
Note that ab=ab, so:
2aba+b=2aba+b.
Set k=ba. This implies k2=ba, so a=k2b. Substitute this into the equation:
If 1+x4+x5=∑i=05ai(1+x)i, for all x in R, then a2 is:
A
−4
B
6
C
−8
D
10
Official Correct Answer:Option (A)
Step-by-Step Solution:
Let y=1+x, which implies x=y−1.
The equation becomes 1+(y−1)4+(y−1)5=∑i=05aiyi
Since the RHS is a polynomial in y, a2 is specifically the coefficient of the y2 term on the LHS.
The y2 term in (y−1)4 is (24)y2(−1)2=6y2. The y2 term in (y−1)5 is (25)y2(−1)3=−10y2.
a2=6−10=−4
Q 67MathematicsSection A • MCQbinomial theorem
+4 / -1
If (2+3x)55 is expanded in the ascending powers of x and the coefficients of powers of x in two consecutive terms of the expansion are equal, then these terms are:
A
7th and 8th
B
8th and 9th
C
28th and 29th
D
27th and 28th
Official Correct Answer:Option (B)
Step-by-Step Solution:
In the binomial expansion of (a+b)n, the general term Tr+1 is given by:
Tr+1=(rn)an−rbr
The (r+1)th term is Tr+1=(r55)(2)55−r(3x)r=[(r55)255−r(31)r]xr
The coefficient of the power xr is Cr=(r55)255−r3−r
We are looking for two consecutive terms with equal coefficients. Let these be the coefficients of xr and xr+1. We set Cr=Cr+1:
(r55)255−r3−r=(r+155)255−(r+1)3−(r+1)
(r55)⋅2=(r+155)⋅31
6⋅(r55)=(r+155)
Using the property (rn)(r+1n)=r+1n−r:
6=r+155−r
6(r+1)=55−r
6r+6=55−r
7r=49⟹r=7
Since r=7, the powers of x with equal coefficients are x7 and x8:
The term containing x7 is the (7+1)th=8th term.
The term containing x8 is the (8+1)th=9th term.
Q 68MathematicsSection A • MCQstraight lines
+4 / -1
If a line intercepted between the coordinate axes is trisected at a point A(4, 3), which is nearer to x-axis, then its equation is:
A
4x−3y=7
B
3x+2y=18
C
3x+8y=36
D
x+3y=13
Official Correct Answer:Option (B)
Step-by-Step Solution:
We are given that a line segment intercepted between the coordinate axes is trisected at the point A(4, 3), and A is nearer to the x-axis. We need to find the equation of this line.
Let the line intersect the x-axis at point P(a, 0) and the y-axis at point Q(0, b). The segment PQ is trisected, meaning it is divided into three equal parts by two points. Since A(4, 3) is nearer to the x-axis, it must be the trisection point closer to P (the x-intercept). Therefore, A divides PQ in the ratio 1:2, where PA:AQ = 1:2 (the part from P to A is one-third of PQ).
Using the section formula, if a point divides the line segment joining (x₁, y₁) and (x₂, y₂) in the ratio m:n, its coordinates are:
(m+nmx2+nx1,m+nmy2+ny1)
Here, P(a, 0) and Q(0, b), and A(4, 3) divides PQ in the ratio m:n = 1:2. Substituting:
For the x-coordinate:
4=1+21⋅0+2⋅a=32a
Solving for a:
4=32a
Multiply both sides by 3:
12=2a
Divide both sides by 2:
a=6
For the y-coordinate:
3=1+21⋅b+2⋅0=3b
Solving for b:
3=3b
Multiply both sides by 3:
b=9
So, the x-intercept is 6 and the y-intercept is 9. The equation of a line in intercept form is:
ax+by=1
Substituting a = 6 and b = 9:
6x+9y=1
To eliminate denominators, multiply both sides by the least common multiple of 6 and 9, which is 18:
18⋅6x+18⋅9y=18⋅1
Simplify each term:
3x+2y=18
Thus, the equation is 3x + 2y = 18.
Now, comparing with the options:
A. 4x - 3y = 7
B. 3x + 2y = 18
C. 3x + 8y = 36
D. x + 3y = 13
Option B matches our equation. To verify, check if A(4, 3) lies on this line and if it trisects PQ with intercepts (6, 0) and (0, 9).
Substitute x = 4, y = 3 into 3x + 2y:
3(4)+2(3)=12+6=18
This equals the right-hand side, so A lies on the line.
For trisection: the point dividing PQ from P(6, 0) to Q(0, 9) in the ratio 1:2 is:
(1+21⋅0+2⋅6,1+21⋅9+2⋅0)=(312,39)=(4,3)
This confirms A(4, 3) is the trisection point nearer to the x-axis (since the other trisection point at ratio 2:1 is (2, 6), which has a larger y-coordinate and is farther from the x-axis).
Hence, the correct answer is Option B.
Q 69MathematicsSection A • MCQstraight lines
+4 / -1
If the three distinct lines x+2ay+a=0, x+3by+b=0 and x+4ay+a=0 are concurrent, then the point (a,b) lies on a:
A
circle
B
hyperbola
C
straight line
D
parabola
Official Correct Answer:Option (C)
Step-by-Step Solution:
The three given lines are:
1. x+2ay+a=0
2. x+3by+b=0
3. x+4ay+a=0
Since the lines are concurrent, they all pass through a common point. For three lines to be concurrent, the determinant of their coefficients must be zero. The general form of a line is px+qy+r=0. For the given lines:
Lines 1 and 3 are identical (both are x=0), violating distinctness. Thus, a=0 is invalid.
Therefore, a=b. The point (a,b) satisfies b=a, meaning it lies on the straight line y=x.
Hence, the correct answer is Option C.
Q 70MathematicsSection A • MCQcircles
+4 / -1
For the two circles x2+y2=16 and x2+y2−2y=0, there is/are:
A
one pair of common tangents
B
two pair of common tangents
C
three pair of common tangents
D
no common tangent
Official Correct Answer:Option (D)
Step-by-Step Solution:
We are given two circles:
First circle: x2+y2=16
Second circle: x2+y2−2y=0
To find the number of common tangents, we first rewrite both equations in standard form to identify their centers and radii.
For the first circle: x2+y2=16. This is already in standard form, so it can be written as (x−0)2+(y−0)2=42. Therefore, the center is C1=(0,0) and the radius is r1=4.
For the second circle: x2+y2−2y=0. We complete the square for the y-terms. Rewrite as x2+(y2−2y)=0. To complete the square, add and subtract 1: x2+(y2−2y+1)=1, which simplifies to x2+(y−1)2=1. Therefore, the center is C2=(0,1) and the radius is r2=1.
Now, we have:
Circle 1: Center (0,0), Radius 4
Circle 2: Center (0,1), Radius 1
Next, we calculate the distance d between the centers C1(0,0) and C2(0,1):
d=(0−0)2+(0−1)2=0+1=1=1
We compare this distance with the sum and difference of the radii:
Sum of radii: r1+r2=4+1=5
Difference of radii: ∣r1−r2∣=∣4−1∣=3
The relative positions of the circles determine the number of common tangents:
If d>r1+r2, the circles are separate and have 4 common tangents (2 direct, 2 transverse).
If d=r1+r2, the circles touch externally and have 3 common tangents.
If ∣r1−r2∣<d<r1+r2, the circles intersect at two points and have 2 common tangents.
If d=∣r1−r2∣, the circles touch internally and have 1 common tangent.
If d<∣r1−r2∣, one circle lies entirely inside the other without touching, and there are no common tangents.
Here, d=1 and ∣r1−r2∣=3. Since 1<3, we have d<∣r1−r2∣. This means circle 2 lies entirely inside circle 1 without touching it.
To confirm, we check for points of intersection by solving the equations simultaneously:
Equation of circle 1: x2+y2=16
Equation of circle 2: x2+y2−2y=0
Subtract circle 2 from circle 1:
(x2+y2)−(x2+y2−2y)=16−0
x2+y2−x2−y2+2y=16
2y=16
y=8
Substitute y=8 into circle 1:
x2+(8)2=16
x2+64=16
x2=16−64=−48
This gives x2=−48, which has no real solutions. Therefore, the circles do not intersect and do not touch.
Since circle 2 is entirely inside circle 1 without touching, there are no common tangents. Any tangent to circle 2 (the inner circle) will intersect circle 1 (the outer circle) at two points, as verified by testing tangents at various points on circle 2. For example:
At point (0,0) on circle 2, the tangent is y=0 (x-axis). Substituting into circle 1: x2+02=16 gives x=±4, so it intersects circle 1 at two points.
At point (0,2) on circle 2, the tangent is y=2. Substituting into circle 1: x2+22=16 gives x2=12, so x=±23, again two intersection points.
At point (1,1) on circle 2, the tangent is x=1. Substituting into circle 1: 12+y2=16 gives y2=15, so y=±15, two intersection points.
Thus, no line is tangent to both circles.
Hence, the correct answer is Option D.
Q 71MathematicsSection A • MCQparabola
+4 / -1
Two tangents are drawn from a point (−2,−1) to the curve, y2=4x. If α is the angle between them, then ∣tanα∣ is equal to:
A
31
B
31
C
3
D
3
Official Correct Answer:Option (D)
Step-by-Step Solution:
We are given a point (−2,−1) and the parabola y2=4x. We need to find ∣tanα∣, where α is the angle between the two tangents drawn from this point to the parabola.
First, recall that for a parabola y2=4ax, the equation of a tangent with slope m is y=mx+ma. Comparing y2=4x with y2=4ax, we get 4a=4, so a=1. Therefore, the equation of a tangent to the parabola y2=4x with slope m is:
y=mx+m1
Since the tangent passes through the point (−2,−1), we substitute x=−2 and y=−1 into the tangent equation:
−1=m⋅(−2)+m1
Simplify the equation:
−1=−2m+m1
To eliminate the denominator, multiply both sides by m:
−1⋅m=(−2m+m1)⋅m
This gives:
−m=−2m2+1
Bring all terms to one side to form a quadratic equation:
2m2−m−1=0
Solve for m using the quadratic formula. Here, a=2, b=−1, and c=−1. The discriminant D is:
D=b2−4ac=(−1)2−4⋅2⋅(−1)=1+8=9
So, the solutions are:
m=2a−b±D=2⋅2−(−1)±9=41±3
Thus, the two slopes are:
m1=41+3=44=1
m2=41−3=4−2=−21
The angle α between two lines with slopes m1 and m2 is given by:
tanα=1+m1m2m1−m2
Substitute m1=1 and m2=−21:
m1−m2=1−(−21)=1+21=23
1+m1m2=1+(1)⋅(−21)=1−21=21
Therefore,
tanα=2123=23×12=∣3∣=3
Hence, ∣tanα∣=3.
Comparing with the options, we see that 3 corresponds to option D.
Hence, the correct answer is Option D.
Q 72MathematicsSection A • MCQellipse
+4 / -1
The minimum area of a triangle formed by any tangent to the ellipse 16x2+81y2=1 and the co-ordinate axes is:
A
12
B
18
C
26
D
36
Official Correct Answer:Option (D)
Step-by-Step Solution:
We are given the ellipse equation: 16x2+81y2=1. Here, a2=16 so a=4, and b2=81 so b=9. We need to find the minimum area of the triangle formed by any tangent to this ellipse and the coordinate axes.
First, recall the equation of a tangent to the ellipse a2x2+b2y2=1 in terms of slope m. It is given by: y=mx±a2m2+b2 Substituting a2=16 and b2=81, we get: y=mx±16m2+81
This tangent intersects the coordinate axes. To find the x-intercept, set y=0: 0=mx±16m2+81 Solving for x: mx=∓16m2+81x=m∓16m2+81 The absolute value of the x-intercept is: ∣x∣=∣m∣16m2+81
To find the y-intercept, set x=0: y=m(0)±16m2+81=±16m2+81 The absolute value of the y-intercept is: ∣y∣=16m2+81
The area A of the triangle formed by the tangent and the axes is half the product of the intercepts: A=21×∣x∣×∣y∣=21×∣m∣16m2+81×16m2+81 Simplifying: A=21×∣m∣16m2+81 Since the area is positive and the expression depends on m2, we can assume m>0 without loss of generality. Thus: A=21×m16m2+81=21(16m+m81)
To minimize A, we take the derivative with respect to m and set it to zero. Let: A(m)=21(16m+m81) The derivative is: A′(m)=21(16−m281) Set A′(m)=0: 21(16−m281)=016−m281=016=m281m2=1681m = \frac{9}{4} \quad \text{(sincem > 0)}
To confirm this is a minimum, check the second derivative: A′′(m)=21(m3162)=m381 For m=49>0, A′′(m)>0, so it is a minimum.
Now substitute m=49 into the area formula: A=21(16×49+4981) Simplify inside the parentheses: 16×49=364981=81×94=36 So: A=21(36+36)=21×72=36
Therefore, the minimum area is 36. Comparing with the options: A. 12, B. 18, C. 26, D. 36. Hence, the correct answer is Option D.
Q 73MathematicsSection A • MCQmathematical reasoning
+4 / -1
Let p, q, r denote arbitrary statements. Then the logically equivalent of the statement p⇒(q∨r) is:
A
(p∨q)⇒r
B
(p⇒q)∨(p⇒r)
C
(p⇒∼q)∧(p⇒r)
D
(p⇒q)∧(p⇒∼r)
Official Correct Answer:Option (B)
Step-by-Step Solution:
We are given the statement p⇒(q∨r) and need to find which option is logically equivalent to it. Remember that a⇒b is equivalent to ∼a∨b. So, let's rewrite the given statement:
p⇒(q∨r)=∼p∨(q∨r)
Since disjunction (OR) is associative, we can write this as:
∼p∨q∨r
Now, we'll check each option by converting them into equivalent forms using the same implication rule.
Option A:(p∨q)⇒r
Rewrite the implication:
(p∨q)⇒r=∼(p∨q)∨r
Apply De Morgan's law to ∼(p∨q):
(∼p∧∼q)∨r
This is not the same as ∼p∨q∨r because it has a conjunction (∧) and different terms. For example, if p is false, q is false, and r is false, the original statement is true (since ∼p is true), but this expression becomes (true∧true)∨false=true∨false=true. However, if p is true, q is false, and r is false, the original is false (true implies false), but this expression is (false∧true)∨false=false∨false=false, which matches. But let's test another case: p false, q true, r false. Original: false implies (true or false) = false implies true = true. Option A: (false∨true)⇒false=true⇒false=false. Not the same. So, not equivalent.
Option B:(p⇒q)∨(p⇒r)
Rewrite each implication:
p⇒q=∼p∨q
p⇒r=∼p∨r
So the expression becomes:
(∼p∨q)∨(∼p∨r)
Since disjunction is associative and commutative, rearrange:
∼p∨∼p∨q∨r
Simplify (∼p∨∼p=∼p):
∼p∨q∨r
This matches the original expression exactly. So, option B is equivalent.
Option C:(p⇒∼q)∧(p⇒r)
Rewrite each implication:
p⇒∼q=∼p∨∼q
p⇒r=∼p∨r
So the expression is:
(∼p∨∼q)∧(∼p∨r)
Factor out ∼p using distribution:
∼p∨(∼q∧r)
This is not the same as ∼p∨q∨r. For example, if p is true, q is true, and r is false, the original statement is true (true implies (true or false) = true implies true = true), but this expression is false∨(false∧false)=false∨false=false. Not equivalent.
Option D:(p⇒q)∧(p⇒∼r)
Rewrite each implication:
p⇒q=∼p∨q
p⇒∼r=∼p∨∼r
So the expression is:
(∼p∨q)∧(∼p∨∼r)
Factor out ∼p:
∼p∨(q∧∼r)
This is not the same as ∼p∨q∨r. For example, if p is true, q is false, and r is true, the original statement is true (true implies (false or true) = true implies true = true), but this expression is false∨(false∧false)=false∨false=false. Not equivalent.
Therefore, only option B is logically equivalent to the given statement. Hence, the correct answer is Option B.
Q 74MathematicsSection A • MCQstatistics
+4 / -1
Let Xˉ and M.D. be the mean and the mean deviation about Xˉ of n observations xi, i = 1, 2, n. If each of the observations is increased by 5, then the new mean and the mean deviation about the new mean, respectively, are:
A
Xˉ, M.D.
B
Xˉ+5, M.D.
C
Xˉ, M.D. +5
D
Xˉ+5, M.D. +5
Official Correct Answer:Option (B)
Step-by-Step Solution:
We are given n observations xi for i=1,2,…,n. The mean of these observations is denoted by Xˉ, and the mean deviation about Xˉ is denoted by M.D. The mean deviation is defined as:
M.D.=n1∑i=1n∣xi−Xˉ∣
Each observation is increased by 5, so the new observations are yi=xi+5 for all i. We need to find the new mean and the new mean deviation about this new mean.
First, let's find the new mean, which we'll call Yˉ. The new mean is the average of the new observations:
Yˉ=n1∑i=1nyi=n1∑i=1n(xi+5)
We can split this summation into two parts:
Yˉ=n1(∑i=1nxi+∑i=1n5)
The first sum is the sum of the original observations, which is nXˉ because Xˉ=n1∑i=1nxi, so ∑i=1nxi=nXˉ. The second sum is the sum of n fives, which is 5n. Substituting these:
Yˉ=n1(nXˉ+5n)=n1×n(Xˉ+5)=Xˉ+5
So the new mean is Xˉ+5.
Next, we find the new mean deviation about the new mean Yˉ. The new mean deviation is:
New M.D.=n1∑i=1n∣yi−Yˉ∣
Substitute yi=xi+5 and Yˉ=Xˉ+5:
yi−Yˉ=(xi+5)−(Xˉ+5)=xi+5−Xˉ−5=xi−Xˉ
Therefore, the absolute difference is:
∣yi−Yˉ∣=∣xi−Xˉ∣
Now plug this into the formula for the new mean deviation:
New M.D.=n1∑i=1n∣yi−Yˉ∣=n1∑i=1n∣xi−Xˉ∣
But n1∑i=1n∣xi−Xˉ∣ is exactly the original mean deviation M.D. So:
New M.D.=M.D.
Thus, the new mean is Xˉ+5 and the new mean deviation is M.D. (unchanged).
Comparing with the options:
A. Xˉ, M.D.
B. Xˉ+5, M.D.
C. Xˉ, M.D. +5
D. Xˉ+5, M.D. +5
Option B matches our result.
Hence, the correct answer is Option B.
Q 75MathematicsSection A • MCQsets and relations
+4 / -1
A relation on the set A = {x : |x| < 3, x ∈ Z}, where Z is the set of integers is defined by R = {(x, y) : y = |x|, x =−1}. Then the number of elements in the power set of R is:
A
32
B
16
C
8
D
64
Official Correct Answer:Option (B)
Step-by-Step Solution:
First, we need to understand the set A. The set A is defined as A = {x : |x| < 3, x ∈ Z}, where Z is the set of integers. This means A consists of all integers x such that the absolute value of x is less than 3. The condition |x| < 3 translates to -3 < x < 3. Since x must be an integer, we list all integers satisfying this inequality: x = -2, because | -2 | = 2 < 3; x = -1, because | -1 | = 1 < 3; x = 0, because |0| = 0 < 3; x = 1, because |1| = 1 < 3; and x = 2, because |2| = 2 < 3. Note that x = -3 is not included because | -3 | = 3 is not less than 3, and similarly x = 3 is not included. Therefore, A = {-2, -1, 0, 1, 2}.
Next, we define the relation R on the set A. The relation is given as R = {(x, y) : y = |x|, x ≠ -1}. This means R consists of ordered pairs (x, y) where y is the absolute value of x, and x is not equal to -1. Since R is a relation on A, both x and y must be elements of A.
We now list all possible pairs (x, y) that satisfy the condition. The elements of A are x = -2, -1, 0, 1, 2. However, the condition x ≠ -1 excludes x = -1. So we consider the remaining x values: -2, 0, 1, 2.
For each x, we compute y = |x|:
When x = -2, y = | -2 | = 2, so the pair is (-2, 2).
When x = 0, y = |0| = 0, so the pair is (0, 0).
When x = 1, y = |1| = 1, so the pair is (1, 1).
When x = 2, y = |2| = 2, so the pair is (2, 2).
We must ensure that each y is in A. Checking: y = 2 is in A, y = 0 is in A, y = 1 is in A, and y = 2 is in A. Also, there is no pair for x = -1 because it is excluded. Therefore, the relation R consists of the ordered pairs: (-2, 2), (0, 0), (1, 1), and (2, 2). Thus, R has 4 elements.
Now, we need to find the power set of R, denoted P(R). The power set of a set is the set of all its subsets. If a set has n elements, the number of elements in its power set is 2n. Here, R has 4 elements, so the number of elements in P(R) is 24.
Calculating: 24=2×2×2×2=16. Therefore, the power set of R has 16 elements.
Looking at the options: A. 32, B. 16, C. 8, D. 64. The value 16 corresponds to option B. Hence, the correct answer is Option B.
Q 76MathematicsSection A • MCQmatrices and determinants
+4 / -1
If A=[132−1x2] and B=yx1 be such that AB = [68], then:
A
y=2x
B
y=−2x
C
y=x
D
y=−x
Official Correct Answer:Option (A)
Step-by-Step Solution:
We are given two matrices: matrix A and matrix B. Matrix A is a 2x3 matrix defined as A=[132−1x2] and matrix B is a 3x1 column vector defined as B=yx1. The product AB is given to be [68]. We need to find the relationship between y and x from the options.
To compute the product AB, we multiply matrix A by matrix B. Since A is 2x3 and B is 3x1, the result will be a 2x1 matrix. Each element of the product is obtained by taking the dot product of each row of A with the column vector B.
For the first element (top entry) of AB, we take the first row of A, which is [1, 2, x], and dot it with B, which is [y, x, 1]. This gives: (1×y)+(2×x)+(x×1)=y+2x+x=y+3x.
For the second element (bottom entry) of AB, we take the second row of A, which is [3, -1, 2], and dot it with B: (3×y)+(−1×x)+(2×1)=3y−x+2.
Therefore, the product AB is: [y+3x3y−x+2].
We are told that AB equals [68]. So we set up the following equations:
Equation 1: y+3x=6
Equation 2: 3y−x+2=8
Simplify Equation 2 by subtracting 2 from both sides: 3y−x=6.
Now we have the system:
y+3x=6(Equation 1)
3y−x=6(Equation 2)
We can solve this system using elimination. Multiply Equation 1 by 3 to align coefficients:
3(y+3x)=3×6
3y+9x=18(Equation 3)
Subtract Equation 2 from Equation 3:
(3y+9x)−(3y−x)=18−6
3y+9x−3y+x=12
10x=12
Divide both sides by 10: x=1012=56.
Substitute x=56 into Equation 1 to find y:
y+3×56=6
y+518=6
Convert 6 to a fraction with denominator 5: 6=530
y=530−518=512
So we have x=56 and y=512.
Now, check the relationship: xy=6/512/5=512×65=612=2, which means y=2x.
Verify by substituting into the original equations:
Q 78MathematicsSection A • MCQmatrices and determinants
+4 / -1
If f(θ)=1−sinθ−1cosθ1sinθ1−cosθ1 and A and B are respectively the maximum and the minimum values of f(θ), then (A, B) is equal to:
A
(3, −1)
B
(4,2−2)
C
(2+2,2−2)
D
(2+2,−1)
Official Correct Answer:Option (C)
Step-by-Step Solution:
f(θ)=1−sinθ−1cosθ1sinθ1−cosθ1
f(θ)=1(1+sinθcosθ)−cosθ(−sinθ−cosθ)+1(−sin2θ+1)
f(θ)=1+sinθcosθ+sinθcosθ+cos2θ−sin2θ+1
f(θ)=2+2sinθcosθ+(cos2θ−sin2θ)
f(θ)=2+sin2θ+cos2θ
The range of the trigonometric part is [−2,2]
The required pair (A,B) is (2+2,2−2)
Q 79MathematicsSection A • MCQinverse trigonometric functions
+4 / -1
Statement I: The equation (sin−1x)3+(cos−1x)3−aπ3=0 has a solution for all a≥321.
Statement II: For any x ∈ R, sin−1x+cos−1x=2π and 0≤(sin−1x−4π)2≤169π2.
A
Both statements I and II are true.
B
Both statements I and II are false.
C
Statement I is true and statement II is false.
D
Statement I is false and statement II is true.
Official Correct Answer:Option (D)
Step-by-Step Solution:
Let f(x)=(sin−1x)3+(cos−1x)3. Using the identity sin−1x+cos−1x=2π for x∈[−1,1], let sin−1x=t, where t∈[−2π,2π].
f(x)=t3+(2π−t)3
A3+B3=(A+B)(A2−AB+B2):
f(x)=(t+2π−t)[t2−t(2π−t)+(2π−t)2]
f(x)=2π[t2−2πt+t2+4π2−πt+t2]
f(x)=2π[3t2−23πt+4π2]
f(x)=23π[t2−2πt+12π2]
f(x)=23π[(t−4π)2+48π2]
For x∈[−1,1], the range of t=sin−1x is [−2π,2π].
The range of (t−4π) is [−43π,4π].
Squaring this interval: 0≤(sin−1x−4π)2≤(−43π)2=169π2
Thus, Statement II is true.
Using the range of (t−4π)2 in the expression for f(x):
Minimum value: f(x)min=23π[0+48π2]=32π3
Maximum value: f(x)max=23π[169π2+48π2]=23π[4828π2]=87π3
The given equation (sin−1x)3+(cos−1x)3=aπ3 has a solution if aπ3∈[32π3,87π3].
This implies 321≤a≤87
In the context of the given statements, the condition a≥321 identifies the lower bound necessary for a solution to exist. Hence, Statement I is false.
Q 80MathematicsSection A • MCQapplication of derivatives
+4 / -1
If f(x)=x2−x+5, x>21, and g(x) is its inverse function, then g'(7) equals:
A
−31
B
131
C
31
D
−131
Official Correct Answer:Option (C)
Step-by-Step Solution:
We are given the function f(x)=x2−x+5 for x>21, and we know that g(x) is its inverse function. We need to find g′(7).
To find the derivative of the inverse function at a point, we use the formula:
g′(y)=f′(g(y))1
So, for y=7, we have:
g′(7)=f′(g(7))1
This means we need to find two things: first, the value of g(7), which is the x such that f(x)=7, and second, the derivative f′(x) evaluated at that x.
Start by solving f(x)=7:
x2−x+5=7
Subtract 7 from both sides:
x2−x+5−7=0
x2−x−2=0
Now, solve this quadratic equation. We factor it:
x2−x−2=(x−2)(x+1)=0
So, the solutions are x=2 and x=−1.
But the domain is restricted to x>21. Since −1<21, we discard x=−1. Thus, x=2 is the solution.
Therefore, g(7)=2.
Next, find the derivative of f(x). The function is f(x)=x2−x+5, so:
f′(x)=dxd(x2−x+5)=2x−1
Now, evaluate f′(x) at x=g(7)=2:
f′(2)=2(2)−1=4−1=3
Finally, substitute back into the inverse derivative formula:
g′(7)=f′(g(7))1=f′(2)1=31
So, g′(7)=31.
Looking at the options:
A. −31
B. 131
C. 31
D. −131
Hence, the correct answer is Option C.
Q 81MathematicsSection A • MCQlimits continuity and differentiability
+4 / -1
Let f, g : R → R be two functions defined by f(x)={xsin(x1),0,x=0x=0 and g(x)=xf(x). Statement I: f is a continuous function at x = 0. Statement II: g is a differentiable function at x = 0.
A
Both statement I and II are false.
B
Both statement I and II are true.
C
Statement I is true, statement II is false.
D
Statement I is false, statement II is true.
Official Correct Answer:Option (B)
Step-by-Step Solution:
We are given two functions, f and g, both mapping real numbers to real numbers. The function f(x) is defined as:
f(x)={xsin(x1)0if x=0if x=0
and g(x) is defined as g(x)=x⋅f(x). We need to verify two statements: Statement I claims that f is continuous at x=0, and Statement II claims that g is differentiable at x=0.
First, let's check Statement I: continuity of f at x=0. For f to be continuous at x=0, the limit of f(x) as x approaches 0 must equal f(0). We know f(0)=0. So, we need to compute:
limx→0f(x)=limx→0xsin(x1)
Since ∣sin(θ)∣≤1 for any real θ, we have:
xsin(x1)≤∣x∣⋅1=∣x∣
This implies:
−∣x∣≤xsin(x1)≤∣x∣
As x approaches 0, both −∣x∣ and ∣x∣ approach 0. By the Squeeze Theorem,
limx→0xsin(x1)=0
Thus, limx→0f(x)=0=f(0), so f is continuous at x=0. Statement I is true.
Next, check Statement II: differentiability of g at x=0. First, express g(x) explicitly. Since g(x)=x⋅f(x), and using the definition of f(x):
For x=0, f(x)=xsin(x1), so:
g(x)=x⋅(xsin(x1))=x2sin(x1)
At x=0, g(0)=0⋅f(0)=0⋅0=0. Thus,
g(x)={x2sin(x1)0if x=0if x=0
To check differentiability at x=0, we compute the derivative using the limit definition:
As h approaches 0, both −∣h∣ and ∣h∣ approach 0. By the Squeeze Theorem,
limh→0hsin(h1)=0
Therefore, g′(0) exists and equals 0, so g is differentiable at x=0. Statement II is true.
Both statements are true. Now, reviewing the options:
A. Both statement I and II are false.
B. Both statement I and II are true.
C. Statement I is true, statement II is false.
D. Statement I is false, statement II is true.
Hence, the correct answer is Option B.
Q 82MathematicsSection A • MCQapplication of derivatives
+4 / -1
Let f and g be two differentiable functions on R such that f′(x)>0 and g′(x)<0 for all x∈R. Then for all x:
A
f(g(x))>f(g(x−1))
B
f(g(x))>f(g(x+1))
C
g(f(x))>g(f(x−1))
D
g(f(x))<g(f(x+1))
Official Correct Answer:Option (B)
Step-by-Step Solution:
We are given that f and g are differentiable functions on R with f′(x)>0 and g′(x)<0 for all x∈R. This means f is strictly increasing and g is strictly decreasing. A strictly increasing function preserves inequalities: if a>b, then f(a)>f(b). A strictly decreasing function reverses inequalities: if a>b, then g(a)<g(b).
Now, let's evaluate each option step by step.
Starting with Option A: f(g(x))>f(g(x−1)).
Compare x and x−1. Since x>x−1 (as x−(x−1)=1>0), and g is strictly decreasing, we have g(x)<g(x−1). Now, because f is strictly increasing, g(x)<g(x−1) implies f(g(x))<f(g(x−1)). This contradicts the option's claim f(g(x))>f(g(x−1)). Thus, Option A is false.
Next, Option B: f(g(x))>f(g(x+1)).
Compare x and x+1. Since x<x+1 (as x+1−x=1>0), and g is strictly decreasing, we have g(x)>g(x+1). Now, because f is strictly increasing, g(x)>g(x+1) implies f(g(x))>f(g(x+1)). This matches the option's statement. Thus, Option B appears true, but we'll verify the others.
Option C: g(f(x))>g(f(x−1)).
Compare x and x−1. Since x>x−1, and f is strictly increasing, we have f(x)>f(x−1). Now, because g is strictly decreasing, f(x)>f(x−1) implies g(f(x))<g(f(x−1)). This contradicts the option's claim g(f(x))>g(f(x−1)). Thus, Option C is false.
Option D: g(f(x))<g(f(x+1)).
Compare x and x+1. Since x<x+1, and f is strictly increasing, we have f(x)<f(x+1). Now, because g is strictly decreasing, f(x)<f(x+1) implies g(f(x))>g(f(x+1)). This contradicts the option's claim g(f(x))<g(f(x+1)). Thus, Option D is false.
Therefore, only Option B is correct. Hence, the correct answer is Option B.
Q 83MathematicsSection A • MCQindefinite integration
+4 / -1
The integral ∫(sin3x+cos3x)2sin2xcos2xdx is equal to:
A
(1+cot3x)1+c
B
−3(1+tan3x)1+c
C
(1+cos3x)sin3x+c
D
−3(1+sin3x)cos3x+c
Official Correct Answer:Option (B)
Step-by-Step Solution:
We start with the integral: ∫(sin3x+cos3x)2sin2xcos2xdx
First, recall the algebraic identity for the sum of cubes: sin3x+cos3x=(sinx+cosx)(sin2x−sinxcosx+cos2x) Since sin2x+cos2x=1, this simplifies to: sin3x+cos3x=(sinx+cosx)(1−sinxcosx)
Therefore, the denominator becomes: (sin3x+cos3x)2=[(sinx+cosx)(1−sinxcosx)]2=(sinx+cosx)2(1−sinxcosx)2
The integral now is: ∫(sinx+cosx)2(1−sinxcosx)2sin2xcos2xdx
Notice that the numerator sin2xcos2x=(sinxcosx)2, so we write: ∫(sinx+cosx)2(1−sinxcosx)2(sinxcosx)2dx
To simplify, we express everything in terms of tanx. Divide both numerator and denominator by cos4x:
Since t=tanx, we have: −3(tan3x+1)1+c=−3(1+tan3x)1+c
Comparing with the options:
Option A: (1+cot3x)1+c
Option B: −3(1+tan3x)1+c
Option C: (1+cos3x)sin3x+c
Option D: −3(1+sin3x)cos3x+c
Our result matches option B.
Hence, the correct answer is Option B.
Q 84MathematicsSection A • MCQdefinite integration
+4 / -1
If [ ] denotes the greatest integer function, then the integral ∫0π[cosx]dx is equal to:
A
2π
B
0
C
−1
D
−2π
Official Correct Answer:Option (D)
Step-by-Step Solution:
The integral to evaluate is ∫0π[cosx]dx, where [⋅] denotes the greatest integer function. This function returns the greatest integer less than or equal to its argument. The cosine function, cosx, decreases from 1 to -1 as x goes from 0 to π. The greatest integer function [cosx] will change values at points where cosx is an integer, specifically at x=0, x=π/2, and x=π, because cosx takes integer values 1, 0, and -1 at these points, respectively.
To compute the integral, split it at the discontinuity points, specifically at x=π/2:
' in math mode at position 1:̲
\int_0^{\pi} […" style="color:#cc0000">$
\int_0^{\pi} [\cos x] dx = \int_0^{\pi/2} [\cos x] dx + \int_{\pi/2}^{\pi} [\cos x] dx$
Now, evaluate each integral separately.
First, consider ∫0π/2[cosx]dx.
- At x=0, cos0=1, so [cos0]=[1]=1.
- For x∈(0,π/2], cosx is in the interval (0,1]. Since cosx>0 and cosx<1 for x>0, the greatest integer less than or equal to cosx is 0. At x=π/2, cos(π/2)=0, so [0]=0.
Thus, in the interval [0,π/2], [cosx]=1 only at the single point x=0, and [cosx]=0 for all x∈(0,π/2]. In the Riemann integral, the value at a single point does not affect the result because it has measure zero. Therefore, the function [cosx] is effectively 0 almost everywhere in [0,π/2], and the integral is:
' in math mode at position 1:̲
\int_0^{\pi/2}…" style="color:#cc0000">$
\int_0^{\pi/2} [\cos x] dx = \int_0^{\pi/2} 0 dx = 0$
To be rigorous, consider the limit as ϵ→0+:
' in math mode at position 1:̲
\int_0^{\pi/2}…" style="color:#cc0000">$
\int_0^{\pi/2} [\cos x] dx = \lim_{\epsilon \to 0^+} \int_{\epsilon}^{\pi/2} [\cos x] dx$
For ϵ>0 and small, x∈[ϵ,π/2], cosx∈(0,1), so [cosx]=0. Thus:
' in math mode at position 1:̲
\int_{\epsilon…" style="color:#cc0000">$
\int_{\epsilon}^{\pi/2} 0 dx = 0$
As ϵ→0+, the integral remains 0.
Next, consider ∫π/2π[cosx]dx.
- At x=π/2, cos(π/2)=0, so [0]=0.
- For x∈(π/2,π], cosx is in the interval (−1,0). For example, at x=π, cosπ=−1, so [−1]=−1. For any y∈(−1,0), the greatest integer less than or equal to y is −1 (e.g., [−0.5]=−1).
Thus, in the interval [π/2,π], [cosx]=0 only at the single point x=π/2, and [cosx]=−1 for all x∈(π/2,π]. Again, the value at a single point does not affect the integral, so [cosx] is effectively −1 almost everywhere in [π/2,π]. Therefore:
' in math mode at position 1:̲
\int_{\pi/2}^{…" style="color:#cc0000">$
\int_{\pi/2}^{\pi} [\cos x] dx = \int_{\pi/2}^{\pi} (-1) dx = -1 \cdot \left( \pi - \frac{\pi}{2} \right) = -1 \cdot \frac{\pi}{2} = -\frac{\pi}{2}$
To be rigorous, consider the limit as δ→0+:
' in math mode at position 1:̲
\int_{\pi/2}^{…" style="color:#cc0000">$
\int_{\pi/2}^{\pi} [\cos x] dx = \lim_{\delta \to 0^+} \left( \int_{\pi/2 + \delta}^{\pi} [\cos x] dx + \int_{\pi/2}^{\pi/2 + \delta} [\cos x] dx \right)$
For x∈[π/2+δ,π], cosx∈[−1,−sinδ)⊂(−1,0), so [cosx]=−1. Thus:
' in math mode at position 1:̲
\int_{\pi/2 + …" style="color:#cc0000">$
\int_{\pi/2 + \delta}^{\pi} (-1) dx = -1 \cdot \left( \pi - \left( \frac{\pi}{2} + \delta \right) \right) = -\left( \frac{\pi}{2} - \delta \right)$
For x∈[π/2,π/2+δ], [cosx] is bounded between −1 and 0, so the integral is bounded in absolute value by δ⋅1=δ. As δ→0+, this part approaches 0. Thus:
' in math mode at position 1:̲
\lim_{\delta \…" style="color:#cc0000">$
\lim_{\delta \to 0^+} \left( -\left( \frac{\pi}{2} - \delta \right) + \text{bounded term} \right) = -\frac{\pi}{2}$
Now, sum the two integrals:
' in math mode at position 1:̲
\int_0^{\pi} […" style="color:#cc0000">$
\int_0^{\pi} [\cos x] dx = \int_0^{\pi/2} [\cos x] dx + \int_{\pi/2}^{\pi} [\cos x] dx = 0 + \left( -\frac{\pi}{2} \right) = -\frac{\pi}{2}$
Therefore, the integral evaluates to −π/2.
Hence, the correct answer is Option D.
So, the answer is −2π.
Q 85MathematicsSection A • MCQdefinite integration
+4 / -1
If for a continuous function f(x), ∫−πt(f(x)+x)dx=π2−t2, for all t≥−π, then f(−3π) is equal to:
A
π
B
2π
C
3π
D
6π
Official Correct Answer:Option (A)
Step-by-Step Solution:
We are given that for a continuous function f(x), the equation ∫−πt(f(x)+x)dx=π2−t2 holds for all t≥−π. We need to find the value of f(−3π).
Since the equation is true for all t≥−π, we can differentiate both sides with respect to t to find an expression for f(t). According to the Fundamental Theorem of Calculus, if F(t)=∫atg(x)dx, then F′(t)=g(t). Here, the left side is ∫−πt(f(x)+x)dx, so we let g(x)=f(x)+x.
Differentiating both sides of the given equation with respect to t:
Left side derivative: dtd[∫−πt(f(x)+x)dx]=f(t)+t.
Right side derivative: dtd[π2−t2]=−2t.
So, we have:
f(t)+t=−2t
Now, solve for f(t):
Subtract t from both sides:
f(t)=−2t−t
f(t)=−3t
Therefore, the function is f(t)=−3t.
Now, substitute t=−3π to find f(−3π):
f(−3π)=−3×(−3π)
Simplify:
f(−3π)=−3×−3π=3×3π=π
To verify, substitute f(x)=−3x into the original integral:
∫−πt(f(x)+x)dx=∫−πt(−3x+x)dx=∫−πt(−2x)dx
Integrate −2x:
∫−2xdx=−2×2x2=−x2
Evaluate from −π to t:
[−x2]−πt=−t2−(−(−π)2)=−t2−(−π2)=−t2+π2=π2−t2
This matches the right side of the given equation, confirming that f(x)=−3x is correct.
Hence, f(−3π)=π, which corresponds to option A.
So, the answer is Option A.
Q 86MathematicsSection A • MCQdifferential equations
+4 / -1
The general solution of the differential equation, sin2x(dxdy−tanx)−y=0, is:
This is a linear differential equation of the form dxdy+P(x)y=Q(x), where P(x)=−sin2x1 and Q(x)=tanx.
The integrating factor (I.F.) is e∫P(x)dx=e∫−sin2x1dx.
Compute ∫−sin2x1dx. Since sin2x1=csc2x, we have ∫−csc2xdx.
Let θ=2x, so dθ=2dx and dx=2dθ:
∫−cscθ⋅2dθ=−21∫cscθdθ
The integral of cscθ is ln∣cscθ−cotθ∣+C, so:
−21∫cscθdθ=−21ln∣cscθ−cotθ∣+C
Substitute back θ=2x:
−21ln∣csc2x−cot2x∣+C
Simplify csc2x−cot2x:
csc2x−cot2x=sin2x1−sin2xcos2x=sin2x1−cos2x
Use identities 1−cos2x=2sin2x and sin2x=2sinxcosx:
2sinxcosx2sin2x=cosxsinx=tanx
Thus:
∫−sin2x1dx=−21ln∣tanx∣+C
The integrating factor is:
I.F.=e−21ln∣tanx∣=eln∣tanx∣−1/2=∣tanx∣−1/2
Since tanx is in the equation, we consider tanx>0, so drop the absolute value:
I.F.=(tanx)−1/2=tanx1=cotx
The solution of the linear differential equation is:
y⋅(I.F.)=∫Q(x)⋅(I.F.)dx+C
ycotx=∫tanx⋅cotxdx+C
Simplify the integrand:
tanx⋅cotx=tanx⋅cotx=1=1
Thus:
ycotx=∫1dx+C=x+C
Comparing with the options:
A. ytanx=x+c
B. ycotx=tanx+c
C. ytanx=cotx+c
D. ycotx=x+c
Hence, the correct answer is Option D.
Q 87MathematicsSection A • MCQvector algebra
+4 / -1
If x^, y^ and z^ are three unit vectors in threedimensional space, then the minimum value of ∣x^+y^∣2+∣y^+z^∣2+∣z^+x^∣2
A
23
B
3
C
33
D
6
Official Correct Answer:Option (B)
Step-by-Step Solution:
We are given three unit vectors x^, y^, and z^ in three-dimensional space and need to find the minimum value of the expression ∣x^+y^∣2+∣y^+z^∣2+∣z^+x^∣2.
First, recall that for any vector a, ∣a∣2=a⋅a. Using this, expand each term in the expression.
Start with ∣x^+y^∣2:
∣x^+y^∣2=(x^+y^)⋅(x^+y^)=x^⋅x^+2x^⋅y^+y^⋅y^
Since x^ and y^ are unit vectors, x^⋅x^=1 and y^⋅y^=1, so:
The minimum value of s is −23, achieved when ∣x^+y^+z^∣2=0, meaning x^+y^+z^=0. This occurs when the vectors are coplanar and equally spaced at 120 degrees to each other.
For example, take:
x^=(1,0,0),y^=(−21,23,0),z^=(−21,−23,0)
Verify these are unit vectors:
Magnitude of y^: (−21)2+(23)2=41+43=1=1, similarly for z^.
Since s≥−23, the expression 6+2s≥6+2(−23)=3, and we achieved 3, it is the minimum.
Hence, the correct answer is Option B.
Q 88MathematicsSection A • MCQ3d geometry
+4 / -1
A symmetrical form of the line of intersection of the planes x=ay+b and z=cy+d is:
A
ax−b=1y−1=cz−d
B
ax−b−a=1y−1=cz−d−c
C
bx−a=1y−0=dz−c
D
bx−b−a=0y−1=dz−d−c
Official Correct Answer:Option (B)
Step-by-Step Solution:
We are given two planes: x=ay+b and z=cy+d. To find the symmetrical form of their line of intersection, we first rewrite the plane equations in standard form. The first plane is x−ay=b, and the second plane is −cy+z=d.
The normal vector to the first plane is ⟨1,−a,0⟩ and to the second plane is ⟨0,−c,1⟩. The direction vector of the line of intersection is perpendicular to both normals, so we compute their cross product:
' in math mode at position 1:̲
\vec{d} = \beg…" style="color:#cc0000">$
\vec{d} = \begin{vmatrix}
\hat{i} & \hat{j} & \hat{k} \\
1 & -a & 0 \\
0 & -c & 1 \\
\end{vmatrix} = \hat{i}[(-a)(1) - (0)(-c)] - \hat{j}[(1)(1) - (0)(0)] + \hat{k}[(1)(-c) - (-a)(0)]$
Simplifying each component:
' in math mode at position 1:̲
\hat{i}[-a - 0…" style="color:#cc0000">$
\hat{i}[-a - 0] - \hat{j}[1 - 0] + \hat{k}[-c - 0] = -a\hat{i} - \hat{j} - c\hat{k}$
So, the direction vector is ⟨−a,−1,−c⟩, which can be simplified to ⟨a,1,c⟩ by multiplying by −1. Thus, the direction ratios are a, 1, and c.
Next, we find a point on the line by choosing a value for y. Let y=1:
From the first plane: x=a(1)+b=a+b
From the second plane: z=c(1)+d=c+d
So, the point is (a+b,1,c+d).
The symmetrical form of a line is lx−x0=my−y0=nz−z0, where (x0,y0,z0) is a point on the line and ⟨l,m,n⟩ is the direction vector. Substituting the point (a+b,1,c+d) and direction ratios ⟨a,1,c⟩:
' in math mode at position 1:̲
\frac{x - (a +…" style="color:#cc0000">$
\frac{x - (a + b)}{a} = \frac{y - 1}{1} = \frac{z - (c + d)}{c}$
Rewriting the numerators:
' in math mode at position 1:̲
\frac{x - a - …" style="color:#cc0000">$
\frac{x - a - b}{a} = \frac{y - 1}{1} = \frac{z - c - d}{c}$
Now, comparing with the options:
Option A: ax−b=1y−1=cz−d corresponds to the point (b,1,d), which does not satisfy the first plane unless a=0 (since b=a(1)+b implies a=0), so it is incorrect.
Option B: ax−b−a=1y−1=cz−d−c matches exactly with our derived form.
Option C: bx−a=1y−0=dz−c has denominators b and d instead of a and c, and the point (a,0,c) may not lie on the planes (e.g., a=a(0)+b implies a=b, which is not necessarily true).
Option D: bx−b−a=0y−1=dz−d−c has a denominator of 0 for y, which is invalid since the direction vector has a non-zero y-component (m=1).
Therefore, only option B is correct.
Hence, the correct answer is Option B.
Q 89MathematicsSection A • MCQ3d geometry
+4 / -1
If the distance between planes, 4x−2y−4z+1=0 and 4x−2y−4z+d=0 is 7, then d is:
A
41 or −42
B
42 or −43
C
−41 or 43
D
−42 or 44
Official Correct Answer:Option (C)
Step-by-Step Solution:
The given planes are 4x−2y−4z+1=0 and 4x−2y−4z+d=0. These planes are parallel because they have the same normal vector ⟨4,−2,−4⟩. The distance between two parallel planes ax+by+cz+d1=0 and ax+by+cz+d2=0 is given by the formula:
Distance=a2+b2+c2∣d1−d2∣
For the first plane, 4x−2y−4z+1=0, we have d1=1. For the second plane, 4x−2y−4z+d=0, we have d2=d. The coefficients are a=4, b=−2, and c=−4.
First, compute the denominator a2+b2+c2:
a2=42=16
b2=(−2)2=4
c2=(−4)2=16
Adding these: 16+4+16=36
So, 36=6
The distance is given as 7, so:
7=6∣1−d∣
Multiply both sides by 6 to isolate the absolute value:
7×6=∣1−d∣
42=∣1−d∣
The absolute value equation ∣1−d∣=42 means that 1−d could be 42 or 1−d could be -42. We solve both cases.
Case 1:1−d=42
Subtract 1 from both sides:
−d=42−1
−d=41
Multiply both sides by -1:
d=−41
Case 2:1−d=−42
Subtract 1 from both sides:
−d=−42−1
−d=−43
Multiply both sides by -1:
d=43
Therefore, the possible values of d are −41 and 43.
Comparing with the options:
A. 41 or −42
B. 42 or −43
C. −41 or 43
D. −42 or 44
The values −41 and 43 match option C.
Hence, the correct answer is Option C.
Q 90MathematicsSection A • MCQprobability
+4 / -1
A number x is chosen at random from the set {1, 2, 3, 4, ..., 100}. Define the event: A = the chosen number x satisfies (x−30)(x−10)(x−50)≥0. Then P(A) is:
A
0.71
B
0.70
C
0.51
D
0.20
Official Correct Answer:Option (A)
Step-by-Step Solution:
We are given a set of numbers from 1 to 100, and we choose a number x at random. The event A is defined by the inequality (x−30)(x−10)(x−50)≥0. We need to find the probability P(A), which is the number of integers x in {1,2,…,100} that satisfy this inequality divided by 100.
First, note that the expression is undefined when the denominator is zero, i.e., at x=30. Therefore, x=30 cannot satisfy the inequality and must be excluded from the favorable outcomes.
The critical points where the numerator or denominator is zero are x=10, x=50, and x=30. These points divide the real number line into intervals. We will test the sign of the expression in each interval to determine where the inequality holds. The intervals are:
x<10
10<x<30
30<x<50
x>50
We analyze each interval by picking a test point and evaluating the sign of each factor:
For x<10 (e.g., x=5):
(x−10)=5−10=−5<0
(x−50)=5−50=−45<0
(x−30)=5−30=−25<0
Numerator: (−)×(−)=+
Denominator: −
Fraction: −+=− (negative)
Since the expression is negative, it does not satisfy ≥0.
For 10<x<30 (e.g., x=20):
(x−10)=20−10=10>0
(x−50)=20−50=−30<0
(x−30)=20−30=−10<0
Numerator: (+)×(−)=−
Denominator: −
Fraction: −−=+ (positive)
Since the expression is positive, it satisfies ≥0.
For 30<x<50 (e.g., x=40):
(x−10)=40−10=30>0
(x−50)=40−50=−10<0
(x−30)=40−30=10>0
Numerator: (+)×(−)=−
Denominator: +
Fraction: +−=− (negative)
Since the expression is negative, it does not satisfy ≥0.
For x>50 (e.g., x=60):
(x−10)=60−10=50>0
(x−50)=60−50=10>0
(x−30)=60−30=30>0
Numerator: (+)×(+)=+
Denominator: +
Fraction: ++=+ (positive)
Since the expression is positive, it satisfies ≥0.
Next, we check the critical points:
At x=10: (10−30)(10−10)(10−50)=−200×(−40)=−200=0≥0, so it satisfies.
At x=50: (50−30)(50−10)(50−50)=2040×0=200=0≥0, so it satisfies.
At x=30: The expression is undefined, so it does not satisfy.
Combining the results, the inequality holds for:
x=10
10<x<30
x=50
x>50
In interval notation, this is x∈[10,30)∪[50,∞). Since our set is {1,2,…,100}, we consider integers from 1 to 100.
The favorable integers are:
From 10 to 29 inclusive (since 30 is excluded): x=10,11,…,29.
From 50 to 100 inclusive: x=50,51,…,100.
Now, we count these integers:
Number of integers from 10 to 29: First term is 10, last term is 29, so the count is 29−10+1=20.
Number of integers from 50 to 100: First term is 50, last term is 100, so the count is 100−50+1=51.
Total favorable outcomes = 20+51=71.
Total possible outcomes = 100 (since the set has 100 integers).