Official NTA Question PaperFull Solved Paper2026Morning Shift
JEE Main 2026 23rd January Morning Shift Question Paper with Solutions
Official solved question paper for Joint Entrance Examination (Main). Review all 75 questions, official answer keys, and detailed step-by-step solutions below, or attempt online with timer and negative marking.
Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R) Consider a ferromagnetic material : Assertion (A) : The individual atoms in a ferromagnetic material possess a magnetic dipole moment and interact with one another in such a way that they spontaneously align themselves forming domains. Reason (R): At high enough temperature, the domain structure of ferromagnetic material disintegrates. Thus, magnetization will disappear at high enough temperature known as Curie temperature. In the light of the above statements, choose the correct answer from the options given below :
A
Both (A) and (R) are true but (R) is not the correct explanation of (A)
B
(A) is true but (R) is false
C
Both (A) and (R) are true and (R) is the correct explanation of (A)
D
(A) is false but (R) is true
Official Correct Answer:Option (A)
Step-by-Step Solution:
We need to evaluate the Assertion and Reason about ferromagnetic materials.
Assertion (A): "The individual atoms in a ferromagnetic material possess a magnetic dipole moment and interact with one another in such a way that they spontaneously align themselves forming domains."
Analysis: In ferromagnetic materials (like iron, cobalt, nickel), each atom has a permanent magnetic dipole moment due to unpaired electrons. These atomic magnetic moments interact through a quantum mechanical exchange interaction, which causes neighboring moments to align parallel to each other spontaneously, forming regions called magnetic domains. Assertion (A) is TRUE.
Reason (R): "At high enough temperature, the domain structure of ferromagnetic material disintegrates. Thus, magnetization will disappear at high enough temperature known as Curie temperature."
Analysis: Above the Curie temperature, thermal energy overcomes the exchange interaction energy, destroying the long-range ordering of magnetic moments. The material transitions from ferromagnetic to paramagnetic behavior. Reason (R) is TRUE.
Relationship: While both statements are true, Reason (R) describes what happens at high temperatures (loss of domain structure), which does not explain why domains form in the first place (Assertion A). The formation of domains is due to exchange interactions at lower temperatures, not related to their destruction at the Curie temperature. R does NOT explain A.
The correct answer is Option 1: Both (A) and (R) are true but (R) is not the correct explanation of (A).
Q 2PhysicsSection A • MCQsemiconductor devices and logic gates
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The following diagram shows a Zener diode as a voltage regulator. The Zener diode is rated at Vz=5V and the desired current in load is 5 mA. The unregulated voltage source can supply upto 25 V. Considering the Zener diode can withstand four times of the load current, the value of resistor Rs (shown in circuit) should be ____ Ω .
Two small balls with masses m and 2m are attached to both ends of a rigid rod of length d and negligible mass. If angular momentum of this system is L about an axis (A) passing through its centre of mass and perpendicular to the rod then angular velocity of the system about A is :
A
5md22L
B
23md2L
C
md22L
D
34md2L
Official Correct Answer:Option (B)
Step-by-Step Solution:
We need to find the angular velocity of a system of two balls (masses m and 2m) attached to a rod of length d, given angular momentum L about the axis through the center of mass.
Find the center of mass. Taking the position of mass m as origin:
xcm=m+2mm⋅0+2m⋅d=32d
So mass m is at distance 32d from the CM, and mass 2m is at distance d−32d=3d from the CM.
The moment of inertia of a square loop made of four uniform solid cylinders, each having radius R and length L (R<L) about an axis passing through the mid points of opposite sides, is (Take the mass of the entire loop as M) :
A
43MR2+127ML2
B
83MR2+61ML2
C
43MR2+61ML2
D
83MR2+127ML2
Official Correct Answer:Option (B)
Step-by-Step Solution:
Let the mass of each cylinder be m=4M.
The moment of inertia of a solid cylinder of mass m, radius R and length L about a diameter of its circular cross section (axis through centre perpendicular to its length) is given by the formula
I\diameter=41mR2+121mL2−(1)
The two vertical rods (left and right sides) have their midpoints on the rotation axis and for each the axis is a diameter of its cross section.
Moment of inertia of one vertical rod about the given axis is
Iv,1=41mR2+121mL2.
For two vertical rods,
Ivertical=2Iv,1=21mR2+61mL2−(2)
The moment of inertia of a solid cylinder of mass m and radius R about its central (longitudinal) axis is
Ilong=21mR2−(3)
The top and bottom rods are horizontal, parallel to the rotation axis, and at a perpendicular distance 2L from it.
Using the parallel axis theorem for one such rod:
Ih,1=Ilong+m(2L)2=21mR2+41mL2−(4)
For both horizontal rods,
Ihorizontal=2Ih,1=mR2+21mL2−(5)
The total moment of inertia of the square loop about the given axis is
I=Ivertical+Ihorizontal=(21mR2+61mL2)+(mR2+21mL2).
Substituting m=4M gives
I=(21⋅4MR2+61⋅4ML2)+(4MR2+21⋅4ML2)=8MR2+24ML2+4MR2+8ML2=83MR2+6ML2.
Therefore, the required moment of inertia is
83MR2+61ML2,
which corresponds to Option B.
Q 5PhysicsSection A • MCQatoms and nuclei
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In hydrogen atom spectrum, (R ➔ Rydberg's constant) A. the maximum wavelength of the radiation of Lyman series is 3R4 B. the Balmer series lies in the visible region of the spectrum C. the minimum wavelength of the radiation of Paschen series is R9 D. the minimum wavelength of Lyman series is 4R5 Choose the correct answer from the options given below :
A
A, B Only
B
A, B and D Only
C
A, B and C Only
D
B, D Only
Official Correct Answer:Option (C)
Step-by-Step Solution:
We need to verify which statements about the hydrogen atom spectrum are correct.
Key Formula: The wavelength of spectral lines is given by:
λ1=R(n121−n221)
where R is Rydberg's constant, n1 is the lower level, and n2 is the upper level.
Statement A: The maximum wavelength of Lyman series is 3R4.
The Lyman series has n1=1. Maximum wavelength corresponds to minimum energy transition (n2=2):
λmax1=R(121−221)=R×43
λmax=3R4Statement A is CORRECT.
Statement B: The Balmer series lies in the visible region of the spectrum.
The Balmer series has n1=2. Its wavelengths range from 364.6 nm (series limit) to 656.3 nm, which falls in the visible region (380-700 nm). Statement B is CORRECT.
Statement C: The minimum wavelength of Paschen series is R9.
The Paschen series has n1=3. Minimum wavelength corresponds to the series limit (n2→∞):
λmin1=R(321−0)=9R
λmin=R9Statement C is CORRECT.
Statement D: The minimum wavelength of Lyman series is 4R5.
The minimum wavelength of Lyman series corresponds to n2→∞:
λmin1=R(121−0)=R
λmin=R1
This is NOT 4R5. Statement D is INCORRECT.
The correct statements are A, B, and C.
The correct answer is Option 3: A, B and C Only.
Q 6PhysicsSection A • MCQdual nature of radiation
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The de Broglie wavelength of an oxygen molecule at 27∘C is x×10−12m. The value of x is (take Planck's constant =6.63×10−34J.s, Boltzmann constant =1.38×10−23J/K, mass of oxygen molecule =5.31×10−26kg)
A
20
B
24
C
30
D
26
Official Correct Answer:Option (D)
Step-by-Step Solution:
We need to find the de Broglie wavelength of an O2 molecule at 27°C. The de Broglie wavelength of a gas molecule at temperature T is: λ=3mkBTh where h is Planck's constant, m is the mass of one molecule, kB is Boltzmann's constant, and T is the absolute temperature.
h=6.63×10−34J⋅s m=32×1.66×10−27kg=53.12×10−27kg (O2 has molar mass 32 g/mol) kB=1.38×10−23J/K T=27°C=300K
A simple pendulum of string length 30 cm performs 20 oscillations in 10 s. The length of the string required for the pendulum to perfo rm 40 oscillations in the same time duration is _________cm. [Assume that the mass of the pendulum remains same.]
A
120
B
15
C
0.75
D
7.5
Official Correct Answer:Option (D)
Step-by-Step Solution:
T=2πL/g. T1=10/20=0.5s. T2=10/40=0.25s. T2/T1=1/2=L2/L1. L2=L1/4=30/4=7.5 cm.
The answer is Option 4: 7.5 cm.
Q 8PhysicsSection A • MCQcircular motion
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A small bob A of mass m is attached to a massless rigid rod of length 1 m pivoted at point P and kept at an angle of 60° with vertical as shown in figure. At distance of 1 m below point P, an identical bob B is kept at rest on a smooth horizontal surface that extends to a circular track of radius R as shown in figure. If bob B just manages to complete the circular path of radius R upto a point Q after being hit elastically by bob A, then radius R is ____ m.
A
52+3
B
52−3
C
53
D
51
Official Correct Answer:Option (D)
Step-by-Step Solution:
vertical descent height of bob A.
h=L−Lcos(60∘)=1−1(21)=0.5 m
Apply conservation of energy
21mvA2=mgh⟹vA=2⋅g⋅0.5=g
elastic collision between identical masses.
Velocities are exchanged, so vB=vA=g
minimum velocity required at the bottom to just complete the vertical circular track.
vB=5gR
g=5gR⟹g=5gR⟹R=51=0.2 m
Q 9PhysicsSection A • MCQcurrent electricity
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A wire of uniform resistance λΩ/m is bent into a circle of radius r and another piece of wire with length 2r is connected between points A and B (AOB) as shown in figure. The equivalent resistance between points A and B is ____Ω .
Two point charges 2q and q are placed at vertex A and centre of face CDEF of the cube as shown in figure. The electric flux passing through the cube is :
A
ϵ∘3q
B
2ϵ∘3q
C
ϵ∘q
D
4ϵ∘3q
Official Correct Answer:Option (D)
Step-by-Step Solution:
Use Gauss law.
Charge at center of face CDEF:
It lies exactly on surface of cube.
A charge on a face contributes half its flux through the cube.
So contribution:
Φ1=2ϵ0q
Charge 2q is at vertex A.
A vertex is shared by 8 identical cubes.
So this cube gets one-eighth contribution:
Φ2=8ϵ02q=4ϵ0q
Total flux:
Φ=Φ1+Φ2
=2ϵ0q+4ϵ0q
=4ϵ03q
Q 11PhysicsSection A • MCQunits and measurements
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In a screw gauge, the zero of the circular scale lies 3 divisions above the horizontal pitch line when their metallic studs are brought in contact. Using this instrument thickness of a sheet is measured. If pitch scale reading is 1 mm and the circular scale reading is 51 then the correct thickness of the sheet is_____ mm. [Assume least count is 0.01 mm]
A
1.48
B
1.54
C
1.50
D
1.51
Official Correct Answer:Option (B)
Step-by-Step Solution:
We are given a screw gauge with a zero error where the zero of the circular scale lies 3 divisions above the horizontal pitch line when the studs are in contact. The least count (LC) is 0.01 mm.
When the zero of the circular scale lies 3 divisions above the reference line, the circular scale has not reached its zero mark. This means extra rotation is needed to bring it to zero, which represents a negative zero error:
Zero error=−3×LC=−3×0.01=−0.03 mm
The observed reading is given by:
Observed reading=PSR+(CSR×LC)=1+(51×0.01)=1.51 mm
The zero correction is the negative of the zero error, so the corrected reading is:
Correct thickness=Observed reading−Zero error=1.51−(−0.03)=1.54 mm
The correct answer is 1.54 mm.
Q 12PhysicsSection A • MCQunits and measurements
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Four persons measure the length of a rod as 20.00 cm, 19.75 cm, 17.01 cm and 18.25cm. The relative error in the measurement of average length of the rod is :
A
0.24
B
0.18
C
0.08
D
0.06
Official Correct Answer:Option (D)
Step-by-Step Solution:
We need to find the relative error in the measurement of the average length of a rod measured by four persons as 20.00 cm, 19.75 cm, 17.01 cm, and 18.25 cm.
Calculate the mean absolute deviation (mean error):
Δxˉ=41.2475+0.9975+1.7425+0.5025=44.49=1.1225cm
Calculate the relative error:
Relative error=xˉΔxˉ=18.75251.1225=0.0599≈0.06
The correct answer is Option (4): 0.06.
Q 13PhysicsSection A • MCQray optics
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Consider light travelling from a medium A to medium B separated by a plane interface. If the light undergoes total internal reflection during its travel from medium A to B and the speed of light in media A and B are 2.4×108m/s and 2.7×108m/s respecti vely, then the value of critical angle is :
A
cot−1(133)
B
sin−1(89)
C
tan−1(178)
D
cos−1(98)
Official Correct Answer:Option (C)
Step-by-Step Solution:
Refractive index of a medium is defined by the formula n=vc, where c is the speed of light in vacuum and v is the speed of light in the medium. —(1)
For medium A: n1=2.4×108c For medium B: n2=2.7×108c
Since 2.4×108<2.7×108, it follows that n1>n2, so total internal reflection is possible when light travels from A to B.
The critical angle θc is given by Snell’s law at the limit of refraction: sinθc=n1n2 —(2)
Substituting the values of n1 and n2 from (1), we get sinθc=2.4×108c2.7×108c=2.7×1082.4×108=98 —(3)
Therefore, θc=sin−1(98) —(4)
To express θc in the form involving an inverse tangent, use the identity tanθ=1−sin2θsinθ. Substituting sinθc=98 gives tanθc=1−(98)298=91798=178 —(5)
Hence, θc=tan−1(178).
Comparing with the given options, this corresponds to Option C.
Q 14PhysicsSection A • MCQmotion in a plane
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An object is projected with kinetic energy K from a point A at an angle 60° with the horizontal The ratio of the difference in kinetic energies at points B and C to that at point A (see figure), in the absence of air friction is :
A
3:4
B
1:4
C
2:3
D
1:2
Official Correct Answer:Option (A)
Step-by-Step Solution:
An object is projected from point A with kinetic energy KKK at an angle of 60∘60^\circ60∘. Since there is no air resistance, mechanical energy is conserved throughout the motion.
At point A, the total energy is purely kinetic.
KA=K=21×m×v2 = 2mv2
As the object moves upward to point B, it gains height. Due to this increase in height, some of the kinetic energy is converted into potential energy, so the kinetic energy at B decreases.
KA=KB+m×g×h
At the highest point B, the vertical component of velocity becomes zero, and only the horizontal component remains. Therefore, kinetic energy at B depends only on the horizontal velocity.
Now, as the object moves from B to C, it comes back to the same vertical level as A. Hence, the potential energy at C is the same as at A, and thus the kinetic energy at C becomes equal to the initial kinetic energy.
KA=KC=K
Now consider the difference in kinetic energies between C and B , and kinetic energy at A
KC−KB=K−4K=43K
KA=K
Finally, take the ratio of these differences.
KineticenergyatAdiffbetweenBandC = K43K
= 43
Thus, the required ratio is 3:4
Q 15PhysicsSection A • MCQelectromagnetic waves
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Matd1 List - I with List - II. atd1 List - I with List - II. List - I List - II Relation Law A. ∮E.dl=−dtd∮B.da I. Ampere's circuital law B. ∮B.dl=μ∘(I+ϵ∘dtdϕE) II. Faraday's laws of electromagnetic induction C. ∮E.da=ϵ∘1∫vρdv III. Ampere - Maxwell law D. ∮B.dl=μ∘I IV. Gauss's law of electrostatics Choose the correct answer from the options given below :
A
A-I, B-IV, C-III, D-II
B
A-IV, B-I, C-II D-III
C
A-II B-III C-IV, D-I
D
A-II B-III C-I, D-IV
Official Correct Answer:Option (C)
Step-by-Step Solution:
We need to match Maxwell's equations (List I) with their corresponding laws (List II).
∮E⋅dl=−dtd∮B⋅da This is the integral form of Faraday's law of electromagnetic induction — a changing magnetic flux induces an electric field. → II (Faraday's law)
∮B⋅dl=μ0(I+ϵ0dtdϕE) This is Ampere's law with Maxwell's displacement current correction — magnetic fields are produced by both conduction current and changing electric flux. → III (Ampere-Maxwell law)
∮E⋅da=ϵ01∫Vρdv This is Gauss's law for electricity — the electric flux through a closed surface equals the enclosed charge divided by ϵ0. → IV (Gauss's law of electrostatics)
∮B⋅dl=μ0I This is the original Ampere's circuital law (without the displacement current term). → I (Ampere's circuital law)
The correct answer is Option (3): A-II, B-III, C-IV, D-I.
Q 16PhysicsSection A • MCQelectromagnetic induction
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A 20 m long uniform copper wire held horizontally is allowed to fall under the gravity (g=10m/s2) through a uniform horizontal magnetic fie ld of 0.5 Gauss perpendicular to the length of the wire. The induced EMF across the wire when it travells a vertical distance of200 m is ____ mV.
A
20010
B
210
C
2010
D
0.210
Official Correct Answer:Option (C)
Step-by-Step Solution:
A conductor of length L moving with velocity v perpendicular to a magnetic field of strength B has an induced EMF given by the formula: E=BLv−(2)
First, find the speed v of the wire after falling through a vertical distance h=200 m under gravity g=10 m/s2. Using the kinematic relation with initial speed zero: v2=u2+2gh=0+2×10×200=4000−(1) Hence v=4000=2010 m/s
Convert the magnetic field from gauss to tesla: 1 Gauss = 10−4 T. Thus B=0.5 Gauss=0.5×10−4 T=5×10−5 T
Substitute B=5×10−5 T, L=20 m and v=2010 m/s into equation (2): E=(5×10−5)×20×2010=0.0210 V
Convert volts to millivolts: 0.0210 V=2010 mV
Therefore, the induced EMF is 2010 mV, which is Option C.
Q 17PhysicsSection A • MCQwork power and energy
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Two blocks with masses 100 g and 200 g are attached to the ends of springs A and B as shown in figure. the energy stored in A is E. The energy stored in B, when spring constants KA,KB of A and B, respectively satisfy the relation 4KA=3KB is:
A
3E
B
34E
C
4E
D
2E
Official Correct Answer:Option (A)
Step-by-Step Solution:
Let extension in spring A = xA and extension in spring B = xB
Energy stored in spring A = EA = E and energy stored in spring B = EB
From Force balance in spring A,
KAxA=mg=0.1×10=1N
∴xA=KA1
EA=21KAxA2=21KA×KA21=KA0.5
Similarly, from spring B,
KBxB=0.2×10=2
∴xB=KB2
EB=21KBxB2=21KB×KB24=KB2
Since, KB=34KA
∴EB=34KA2=KA1.5=3×KA0.5=3E
Q 18PhysicsSection A • MCQray optics
+4 / -1
A thin prism with angle 5° of refractive index 1.72 is combined with another prism of refractive index 1.9 to produce dispersion w ithout deviation. The angle of second prism is ____ .
A
6∘
B
4∘
C
4.5∘
D
5∘
Official Correct Answer:Option (B)
Step-by-Step Solution:
We need to find the angle of the second prism when two thin prisms are combined to produce dispersion without deviation.
We first state the deviation formula for a thin prism.
For a thin prism with small angle A and refractive index n, the deviation is given by:
δ=(n−1)A
This formula is derived from Snell's law under the small-angle approximation (sinθ≈θ).
Next, we set up the condition for zero net deviation.
When two prisms are combined in opposite orientations, their deviations act in opposite directions. For the net deviation to be zero:
δ1+δ2=0
This implies:
(n1−1)A1=(n2−1)A2
(The deviations must be equal in magnitude but opposite in direction.)
Substituting the given values n1=1.72, A1=5°, and n2=1.9 into this equation gives:
(1.72−1)×5=(1.9−1)×A2
0.72×5=0.9×A2
3.6=0.9×A2
Solving for A2 yields:
A2=0.93.6=4°
The correct answer is Option B: 4°.
Q 19PhysicsSection A • MCQheat and thermodynamics
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In a perfectly inelastic collision, two spheres made of the same material with masses 15 kg and 25 kg, moving in opposite directions with speeds of 10 m/s and 30 m/s, respectively, strike each other and stick together. The rise in temperature (in ∘C), if all the heat produced during the collision is retained by these spheres, is : (specific heat of sphere material 31 cal/kg.∘C and 1 cal =4.2 J)
A
1.75
B
1.15
C
1.95
D
1.44
Official Correct Answer:Option (D)
Step-by-Step Solution:
Let the masses be m1=15kg and m2=25kg, and their velocities before collision be v1=+10m/s and v2=−30m/s (opposite directions).
In a perfectly inelastic collision, momentum is conserved. The formula is:
Next, compute the final kinetic energy of the combined mass:
Kf=21(m1+m2)vf2−(5)
Substitute values:
Kf=21×40×(−15)2=20×225=4500J−(6)
Thus, the heat generated is:
Q=Ki−Kf=12000−4500=7500J−(7)
Given specific heat in calories: c=31cal/kg∘C and 1cal=4.2J. Converting to SI units:
c=31×4.2=130.2J/kg∘C−(8)
The total mass is:
M=m1+m2=15+25=40kg−(9)
The temperature rise is:
ΔT=McQ=40×130.27500≈1.44∘C−(10)
Final Answer: The rise in temperature is 1.44∘C (Option D).
Q 20PhysicsSection A • MCQproperties of matter
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The strain-stress plot for materials A, B, C and D is shown in the figure. Which material has the largest Young's modulus?
A
B
B
A
C
D
D
C
Official Correct Answer:Option (D)
Step-by-Step Solution:
Young's modulus, Y=StrainStress
In the given plot, strain is on the y-axis and stress is on the x-axis.
Slope=StressStrain=Y1
Therefore, the material with the least slope will have the largest Young's modulus.
Observing the plot, material C has the minimum slope. Therefore, it possesses the largest Young's modulus.
Q 21PhysicsSection B • Numericalelectromagnetic induction
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A simple pendulum made of mass 10 g and a metallic wire of length 10 cm is suspended vertically in a uniform magnetic field of 2 T. The magnetic field direction is perpendicular to the plane of oscillations of the pendulum. If the pendulwn is released from an angle of 60° with vertical, then maximum induced EMF between the point of s uspension and point of oscillation is ______mV (Take g=10m/s2)
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
The pendulum consists of a metallic wire of length L=10 cm=0.1 m and a bob of mass m=10 g=0.01 kg, oscillating in a uniform magnetic field B=2 T perpendicular to the plane of oscillation. The maximum induced EMF occurs when the angular velocity is maximum, which is at the lowest point of the swing.
The induced EMF in a rotating conductor of length L about one end in a uniform magnetic field B perpendicular to the plane of rotation is given by:
E=21BωL2
where ω is the angular velocity.
To find the maximum angular velocity ωmax, use conservation of energy. The initial angle is θ0=60∘. The height h above the lowest point is:
h=L(1−cosθ0)
Substitute cos60∘=0.5:
h=0.1×(1−0.5)=0.1×0.5=0.05 m
The potential energy at the initial position converts to kinetic energy at the lowest point:
mgh=21mvmax2
where g=10 m/s2. Solve for vmax:
vmax=2gh=2×10×0.05=1=1 m/s
The maximum angular velocity ωmax is related to vmax by:
ωmax=Lvmax=0.11=10 rad/s
Now substitute into the EMF formula:
Emax=21BωmaxL2=21×2×10×(0.1)2
Calculate step by step:
(0.1)2=0.01
Emax=21×2×10×0.01=1×10×0.01=0.1 V
Convert to millivolts: 0.1 V=100 mV.
Thus, the maximum induced EMF is 100 mV.
Q 22PhysicsSection B • Numericalelectromagnetic waves
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The equation of the electric field of an electromagnetic wave propagating through free space is given by: E=377sin(6.27×103t−2.09×10−5x)N/C The average power of the electromagnetic wave is (α1)W/m2. The value of α is______ (Takeϵ∘μ∘=377inSIunits)
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
We are given the electric field E=377sin(6.27×103t−2.09×10−5x) N/C and must determine α such that the time‐averaged power density equals α1 W/m2.
For a plane electromagnetic wave, the instantaneous power per unit area is described by the Poynting vector, and its time‐averaged value (or intensity) is
⟨S⟩=2Z0E02
In this expression, E0 denotes the amplitude of the electric field, while Z0=μ0/ϵ0 represents the intrinsic impedance of free space. The factor of 21 arises because ⟨sin2(ωt)⟩=21 over a full cycle.
From the given wave, one reads off the amplitude E0=377 N/C, and since Z0=μ0/ϵ0 takes the value 377Ω in SI units, substitution yields
⟨S⟩=2Z0E02=2×377(377)2=2×377377=21 W/m2
Because this result must equal α1, we set α1=21, which leads directly to α=2.
The answer is 2.
Q 23PhysicsSection B • Numericalwave optics
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In two separate Young's double-slit experimental set-ups and two monochromatic light sources of different wavelengths are used to get fringes of equal width. the ratios of the slits separations and that of the wavelengths of light used are 2: 1 and 1 : 2 respectively. The corresponding ratio of the distances between the slits and the respective screens (D1/D2) is ______.
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
We need to find the ratio D1/D2 given that two Young’s double-slit setups produce fringes of equal width.
The fringe width in Young’s double-slit experiment is given by
β=dλD
Here λ is the wavelength, D is the distance from slits to screen, and d is the slit separation.
Since the fringe widths are equal, β1=β2, which implies
d1λ1D1=d2λ2D2
Substituting the given ratios d1:d2=2:1 and λ1:λ2=1:2, we rearrange for D1/D2:
D2D1=λ1λ2×d2d1
Evaluating this gives
D2D1=12×12=4
The answer is 4.
Q 24PhysicsSection B • Numericalcapacitor
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The space between the plates of a parallel plate capacitor of capacitance C (without any dielectric) is now filled with three dielectric slabs of dielectric constants K1=2,K2=3 and K3=5 (as shown in figtue). lf new capacitance is 3nC then the value of n is_____.
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
Let original capacitance (no dielectric):
C=dε0A
step 1: understand geometry
• Top half (thickness d/2): dielectric K1=2, area A
• Bottom half (thickness d/2): split into two equal areas:
left: K2=3, area A/2
right: K3=5, area A/2
step 2: bottom part (parallel combination)
Each has thickness d/2:
C2=d/23ε0(A/2)=d3ε0A
C3=d/25ε0(A/2)=d5ε0A
Parallel:
Cbottom=C2+C3=d8ε0A
step 3: top part
Ctop=d/22ε0A=d4ε0A
step 4: series combination
Top and bottom are in series:
C′1=Ctop1+Cbottom1=4ε0Ad+8ε0Ad
=8ε0A3d
C′=3d8ε0A
Q 25PhysicsSection B • Numericalalternating current
+4 / -1
Using a variable frequency a.c. voltage source the maximum current measured in the given LCR circuit is 50 mA for V= 5 sin(100t) The values of L and R are shown in the figure. The capacitance of the capacitor (C) used is ____ µF.
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
(Z) of a series LCR circuit
Z=R2+(XL−XC)2
(XL=ωL) and (XC=ωC1):
Z=R2+(ωL−ωC1)2
I0=ZV0
I0=R2+(ωL−ωC1)2V0
For the current I0 to be maximum, the denominator (the impedance Z) must be at its least possible value.
Since R2 is constant and positive, Z is minimum when the squared term is zero:
(ωL−ωC1)2=0
ωL=ωC1
100×2=100×C1
C=200×1001
C=5×10−5 F
C=50μF
Q 26ChemistrySection A • MCQpractical organic chemistry
+4 / -1
Match List - I with List - II.
choose the correct answer from the options given below :
A
A-IV, B-III, C-II, D-I
B
A-IV, B-I, C-II, D-III
C
A-III, B-IV, C-II, D-I
D
A-III, B-IV, C-I, D_II
Official Correct Answer:Option (B)
Step-by-Step Solution:
A. Unsaturation (Baeyer's Test) → IV. Discharge of pink colour
Baeyer's reagent is a cold, alkaline solution of potassium permanganate (KMnO4), which is deep pink/purple. When it reacts with an alkene or alkyne, the MnO4− ion is reduced to MnO2 (a brown precipitate), causing the pink colour to disappear (decolourise).
B. Alcoholic group (Ceric ammonium nitrate test) → I. Red colour appears
Ceric ammonium nitrate (CAN) is an orange-yellow reagent. When added to an alcohol, it forms a alkoxy cerium(IV) complex, which results in a characteristic wine-red colouration.
C. Aldehyde group (Tollen's reagent) → II. Silver mirror appears
Tollen's reagent contains the silver-ammonia complex [Ag(NH3)2]+. Aldehydes reduce these silver ions to metallic silver, which deposits on the inner walls of the test tube, creating a shining silver mirror.
D. Phenolic group (FeCl3 test) → III. Violet colour appears
Phenols react with neutral ferric chloride to form a coordination complex with the iron. For simple phenol, this complex is typically violet or purple, though other phenols can produce green or blue colours.
Q 27ChemistrySection A • MCQcoordination compounds
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The statements that are incorrect about the nickel(II) complex of dimethylglyoxime are: A. It is red in colour. B. It has a high solubility in water at pH =9. C. The Ni ion has two unpaired d-electrons. D. The N - Ni - N bond angle is almost close to 90° E. The complex contains four five-membered metallacycles (metal containing rings). Choose the correct answer from the options given below :
A
A, D and B Only
B
C and D Only
C
C and E Only
D
B, C and E Only
Official Correct Answer:Option (D)
Step-by-Step Solution:
We need to identify the incorrect statements about the nickel(II) complex of dimethylglyoxime (DMG), which is [Ni(DMG)2].
Statement A: It is red in colour.
The nickel-DMG complex is indeed bright red (also called strawberry red). Statement A is CORRECT.
Statement B: It has high solubility in water at pH = 9.
The nickel-DMG complex is insoluble in water. It precipitates out at pH 5-9, which is actually how nickel is detected gravimetrically. Statement B is INCORRECT.
Statement C: The Ni ion has two unpaired d-electrons.
In the square planar nickel-DMG complex, Ni2+ has a d8 configuration. In a square planar field, all 8 electrons are paired (dxy2,dyz2,dxz2,dz22, empty dx2−y2). So there are zero unpaired electrons. Statement C is INCORRECT.
Statement D: The N-Ni-N bond angle is almost close to 90 degrees.
In the square planar geometry of the complex, the N-Ni-N bond angle between adjacent nitrogen atoms is approximately 90 degrees. Statement D is CORRECT.
Statement E: The complex contains four five-membered metallacycles.
Each DMG molecule forms one five-membered chelate ring with Ni (Ni-N-C-C-N). With two DMG ligands, there are only two five-membered metallacycles, not four. Statement E is INCORRECT.
The incorrect statements are B, C, and E. The answer is Option D) B, C and E Only.
Q 28ChemistrySection A • MCQp block elements
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The correct statements from the following are: A. Ionic radii of trivalent cations of group 13 elements decreases down the group. B. Electronegativity of group 13 elements decreases down the group. C. Among the group 13 elements, Boron has highest first ionisation enthalpy. D. The trichloride and triiodide of group 13 elements are covalent in nature. Choose the correct answer from the options given below :
A
A and D Only
B
A and C Only
C
B and D Only
D
C and D Only
Official Correct Answer:Option (D)
Step-by-Step Solution:
. Ionic Radii: The distance between the nucleus of a trivalent cation (M3+) and its outermost electron shell. General Trend: It increases down the group (B3+<Al3+<Ga3+<In3+<Tl3+) because new principal energy levels (shells) are added. Statement A is False.
B. Electronegativity: The tendency of an atom to attract a shared pair of electrons. General Trend: It decreases from Boron to Aluminium, but then increases slightly from Aluminium to Thallium. Exception: This irregular trend occurs because of the poor shielding effect of d and f electrons in heavier elements, which increases the effective nuclear charge. Statement B is False.
C. Ionisation Enthalpy: The energy required to remove the most loosely bound electron from an isolated gaseous atom. General Trend: It generally decreases down the group. Exception:Boron has the highest value because it has the smallest atomic size and a very high nuclear charge density, making its electrons hardest to remove. Statement C is True.
D. Covalent Nature: The sharing of electron pairs between atoms rather than total transfer. General Trend: Group 13 halides (trichlorides and triiodides) are predominantly covalent. Exception: According to Fajan's Rule, the small size and high +3 charge of these cations result in high polarizing power, which distorts the electron cloud of the large halide ions to create covalent character. Statement D is True.
Q 29ChemistrySection A • MCQhydrocarbons
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Consider the following compounds
Arrange these compounds in the increasing order of reactivity with nitrating mixture.
A
b < a < c
B
c < b < a
C
b < c < a
D
c < a < b
Official Correct Answer:Option (A)
Step-by-Step Solution:
Nitration of benzene ∝ nucleophlicity of benzene ring. ∝ electron donating group on benzene ring.
Q 30ChemistrySection A • MCQcoordination compounds
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Given below are two statements : Statement I: [CoBr4]2− ion will absorb light of lower energy than [CoCl4]2− ion. Statement II: In [Col4]2− ion, the energy separation between the two set of d-orbitals is more than [CoCl4]2− ion. ln the light of the above statements, choose the correct answer from the options given below:
A
Statement I is false but Statement II is true
B
Both Statement I and Statement II are false
C
Statement I is true but Statement II is false
D
Both Statement I and Statement II are true
Official Correct Answer:Option (C)
Step-by-Step Solution:
In a tetrahedral complex, the splitting of the d-orbitals is denoted by Δt. The energy of light absorbed, Eabs, is directly proportional to this splitting: Eabs∝Δt−(1)
Also, the wavelength of light absorbed, λabs, is inversely proportional to the energy absorbed:
Ligand field strength for halides follows the order: F−>Cl−>Br−>I−
This means chloride is a stronger field ligand than bromide, and bromide is stronger than iodide.
Analysis of Statement I:
Statement I claims that [CoBr4]2− absorbs lower energy light than [CoCl4]2−.
Since Δt(Cl−)>Δt(Br−) by the ligand field series, then by (1): Eabs(Cl−)>Eabs(Br−)
Hence [CoBr4]2− indeed absorbs lower energy light compared to [CoCl4]2−.
Therefore, Statement I is true.
Analysis of Statement II:
Statement II claims that in [CoI4]2− the splitting Δt is greater than in [CoCl4]2−.
From the ligand field series, Δt(Cl−)>Δt(I−).
This contradicts Statement II. Therefore, Statement II is false.
Combining these results: Statement I is true and Statement II is false.
Hence the correct answer is Option C.
Q 31ChemistrySection A • MCQsolutions
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Which one of the following graphs accurately represents the plot of partial pressure of CS2 vs its mole fraction in a mixture of acetone and CS2 at constant temperature?
A
B
C
D
Official Correct Answer:Option (C)
Step-by-Step Solution:
For any binary liquid mixture maintained at a fixed temperature, Raoult’s law for an ideal solution states that the partial pressure of a component equals the product of its mole fraction and its pure-component vapour pressure:
pi=xipi∗(i=1,2)
Thus, for an ideal solution of CS2 (component-2) with any other liquid, the graph of pCS2 versus xCS2 would be a straight line passing through the origin with slope pCS2∗.
The mixture in the question, however, is acetone + CS2. Acetone molecules are strongly dipolar, while CS2 molecules are non-polar. The unlike (acetone-CS2) interactions are therefore much weaker than the like (acetone-acetone dipole-dipole and CS2-CS2 dispersion) interactions. Because of these weaker intermolecular forces, molecules escape more readily into the vapour phase, raising the vapour pressure above the Raoult-law value.
This behaviour is called a positive deviation from Raoult’s law. Mathematically,
pCS2>xCS2pCS2∗
for every intermediate value of xCS2 (except at the ends, where the mixture is pure CS2 and equality holds).
Consequently, the plot of pCS2 versus xCS2 must lie above the straight-line ideal plot and be curved upwards (convex to the mole-fraction axis).
Among the four sketches given in the question, the only one that shows an upward-curving line starting at the origin, lying above the ideal straight line, and reaching pCS2∗ at xCS2=1 is Option C.
Hence, the correct choice is: Option C which is: (graph showing positive deviation from Raoult’s law).
Q 32ChemistrySection A • MCQbasics of organic chemistry
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Given below are two statements : Statement I: Sublimation is used for the separation and purification of compounds with low melting Point. Statement II: The boiling point of a liquid increases as the external pressure is reduced. In the light of the above statements, choose the correct answer from the options given below :
A
Both Statement I and Statement II are true
B
Both Statement I and Statement II are false
C
Statement I is false but Statement II is true
D
Statement I is true but Statement II is false
Official Correct Answer:Option (B)
Step-by-Step Solution:
Sublimation is defined as the process in which a solid converts directly into vapour without passing through the liquid state. This process is feasible only when the substance has a significant vapour pressure at a temperature below its melting point. Therefore, sublimation depends on the vapour pressure characteristics of a compound, not on having a low melting point. Hence Statement I is false.
The boiling point of a liquid is the temperature at which its vapour pressure Pvap equals the external pressure Pext:
Pvap=Pext
When the external pressure is reduced, the temperature required for the vapour pressure to reach that lower external pressure also decreases. Thus the boiling point decreases as the external pressure is reduced. Statement II claims the boiling point increases on reducing external pressure, which contradicts this principle. Hence Statement II is false.
Since both Statement I and Statement II are false, the correct choice is Option B.
Q 33ChemistrySection A • MCQhaloalkanes and haloarenes
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The correct sequence of reagents for the above conversion of X to Y is:
Converts alkene to primary alcohol (Ph-CH₂-CH₂-OH)
Step 3: Jones reagent (CrO₃ / H⁺) Reaction name: Oxidation of primary alcohol
Converts -CH₂OH → -COOH
Forms Ph-CH₂-COOH
Q 34ChemistrySection A • MCQcompounds containing nitrogen
+4 / -1
Consider the following sequence of reactions.
4-Nitrotoluene Assuming that the reaction proceeds to completion, then 137 mg of 4-nitrotoluene will produce ____ mg of B. (Given molar mass in g mol−1 H : 1, C: 12, N: 14, 0: 16, Br : 80)
A
146
B
228
C
301
D
208
Official Correct Answer:Option (B)
Step-by-Step Solution:
Moles of given compound = mass / molar mass
= 137137×10−3=1×10−3
= 0.001 mol
All reactions (reduction → acetylation → bromination) are 1:1, so moles of product = 0.001 mol
Mass of product = moles × molar mass
= 0.001×228
= 0.228 g = 228 mg
Q 35ChemistrySection A • MCQperiodic classification of elements
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The correct trend in the first ionization enthalpies of the elements in the 3rd period of periodic table is:
A
Al < Si < S < P < Cl
B
Si < S < Al < P < Cl
C
S < Si < Al < P < Cl
D
Al < S < P < Si < Cl
Official Correct Answer:Option (A)
Step-by-Step Solution:
The elements present in the 3rd period are Na,Mg,Al,Si,P,S,Cl,Ar.
First ionization enthalpy (IE1) generally increases from left to right across a period because - atomic size decreases, and - effective nuclear charge Zeff increases.
There are two characteristic exceptions in this period:
Case 1:Mg>Al because Mg has the stable configuration 3s2, whereas in Al the electron is removed from the higher-energy 3p1 subshell, so less energy is needed.
Case 2:P>S because P possesses the half-filled configuration 3p3, which is more stable than the 3p4 configuration of S. Hence an electron is removed more easily from S.
Experimental IE1 values (in kJ mol−1) confirm this trend: IE1(Na)=496<IE1(Mg)=738>IE1(Al)=578<IE1(Si)=787<IE1(S)=999<IE1(P)=1012<IE1(Cl)=1251<IE1(Ar)=1521.
Keeping only the elements quoted in the options and arranging them in ascending order:
Al<Si<S<P<Cl
This sequence corresponds to Option A.
Hence, the correct trend in first ionization enthalpies for the given elements of the 3rd period is Al<Si<S<P<Cl; the correct answer is Option A.
Q 36ChemistrySection A • MCQatomic structure
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Which of the following statements regarding the energy of the stationary state is true in the following one - electron systems?
A
−2.18×10−18J for third orbit of Li2+ ion
B
−1.09×10−18J for second orbit of H atom.
C
+2.18×10−18J for second orbit of He+ ion
D
+8.72×10−18J for first orbit of He+ ion
Official Correct Answer:Option (A)
Step-by-Step Solution:
Determine which statement about the energy of stationary states is true.
The energy of the nth orbit in a hydrogen-like atom with atomic number Z is given by En=−13.6×n2Z2 eV. Using 1 eV=1.6×10−19 J, this can be written as En=−2.18×10−18×n2Z2 J.
For the third orbit of Li2+ (where Z=3 and n=3), the energy is E3=−2.18×10−18×3232=−2.18×10−18 J, which matches the value stated in Option A.
Option B refers to the second orbit of hydrogen (Z=1, n=2), giving E=−2.18×10−18/4=−0.545×10−18 J, not −1.09×10−18 J. Option C is incorrect because the energy of a bound state is always negative, never positive. Option D is false since the first orbit of He+ has energy −2.18×10−18×4=−8.72×10−18 J, not a positive value.
The correct answer is Option A: −2.18×10−18 J for the third orbit of Li2+.
Q 37ChemistrySection A • MCQchemical equilibrium
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Consider the general reaction given below at 400 K xA(g)⇌yB(g). The values of Kp and Kc are studied under the same condition of temperature but variation in x and y (i)Kp=85.87 and Kc=2.586 appropriate units (ii)Kp=0.862 and Kc=28.62 appropriate units The values of x and yin (i) and (ii) respectively are:
A
(i)1,2 (ii)2,1
B
(i)1,3 (ii)2,1
C
(i)4,1 (ii)4,1
D
(i)3,1 (ii)3,1
Official Correct Answer:Option (A)
Step-by-Step Solution:
We are given the reaction xA(g)⇌yB(g) at T=400 K, with two cases.
Kp=Kc(RT)Δn, where Δn=y−x (moles of gaseous products minus reactants) and R=0.0821 L·atm/(mol·K).
At T=400 K: RT=0.0821×400=32.84.
KcKp=2.58685.87≈33.2≈32.841
So (RT)Δn≈(32.84)1, meaning Δn=y−x=1.
With x=1,y=2: Δn=2−1=1 ✓
KcKp=28.620.862≈0.0301≈33.21≈(32.84)−1
So (RT)Δn≈(32.84)−1, meaning Δn=y−x=−1.
With x=2,y=1: Δn=1−2=−1 ✓
(i) x=1,y=2 and (ii) x=2,y=1.
The answer is Option A: (i) 1, 2 and (ii) 2, 1.
Q 38ChemistrySection A • MCQaldehydes ketones and carboxylic acids
+4 / -1
Compound 'P' undergoes the following sequence of reactions:
B: Aldehyde (cyclohexyl-CH₂-CHO)
NH₃ does not convert aldehyde to amide under these conditions
No proper substrate for Hofmann reaction Fails
C: Ketone (cyclohexyl-CO-CH₃)
NH₃ forms imine, not amide
Hofmann reaction needs amide → not possible Fails
D: Amide (cyclohexyl-CONH₂)
Already amide, so NH₃/Δ does nothing
Br₂/KOH → cyclohexyl-NH₂
CHCl₃/KOH → cyclohexyl-NC
But initial step is unnecessary and does not match sequence properly Not correct as per given pathway
Final answer:A
Q 39ChemistrySection A • MCQthermodynamics
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A cup of water at 5°C (system) is placed in a microwave oven and the oven is turned on for one minute during which the water begins to boil. Which of the following option is true ?
A
q = + ve, w = 0, △U = - ve
B
q = + ve, w = - ve, △U = - ve
C
q = + ve, w = - ve, △U = + ve
D
q = - ve, w = - ve, △U = - ve
Official Correct Answer:Option (C)
Step-by-Step Solution:
Heat (q): The system absorbs radiation energy from the microwave, increasing its thermal energy. Since energy enters the system, heat is positive (q=+ ve).
Work (w): As the water heats up and begins to boil, it turns into vapor and expands against atmospheric pressure. Since work is done by the system on the surroundings, work is negative (w=- ve).
Internal Energy Change (ΔU): The temperature of the water rises significantly from 5∘C to its boiling point (100∘C). Since internal energy is a direct function of temperature (U∝T), it increases (ΔU=+ ve).
Conclusion:
The process involves absorption of energy resulting in expansion work and a net rise in temperature, making q=+ ve, w=- ve, and ΔU=+ ve.
Answer: Option C — q=+ ve,w=- ve,ΔU=+ ve
Q 40ChemistrySection A • MCQchemical bonding and molecular structure
+4 / -1
ldentify the molecule (X) with maximum number of lone pairs of electrons (obtained using Lewis dot structure) among HNO3,H2SO4,NF3 and O3. Choose the correct bond angle made by the central atom of the molecule (X).
A
116∘
B
102∘
C
120∘
D
107∘
Official Correct Answer:Option (B)
Step-by-Step Solution:
Count lone pairs on all atoms in each molecule using Lewis dot structures:
HNO3: Nitrogen forms one N=O double bond, one N-O single bond, and one N-OH bond. N has 0 lone pairs. The =O has 2 lone pairs, the -O- (bridging to H) has 2 lone pairs, and the -OH oxygen has 2 lone pairs. Total = 0+2+2+2=6.
H2SO4: Sulfur forms two S=O double bonds and two S-OH bonds. S has 0 lone pairs. Each of the 2 terminal =O atoms has 2 lone pairs, and each of the 2 -OH oxygens has 2 lone pairs. Total = 0+2(2)+2(2)=8.
NF3: Nitrogen has 1 lone pair and forms three N-F bonds. Each F has 3 lone pairs. Total = 1+3(3)=10.
O3: Central O has 1 lone pair. The double-bonded terminal O has 2 lone pairs. The single-bonded terminal O (with formal charge -1) has 3 lone pairs. Total = 1+2+3=6.
NF3 has the maximum number of lone pairs (10), so molecule X = NF3 with central atom nitrogen.
In NF3, nitrogen is sp3 hybridized with trigonal pyramidal geometry. The highly electronegative F atoms draw bonding electron density away from N, reducing bond pair-bond pair repulsion. Combined with the lone pair compression, the F-N-F bond angle is reduced to approximately 102°.
The answer is Option B: 102°.
Q 41ChemistrySection A • MCQbiomolecules
+4 / -1
From the given following (A to D) cyclic structures, those which will not react with Tollen's reagent are:
A
A and D
B
B and D
C
B and C
D
A and B
Official Correct Answer:Option (C)
Step-by-Step Solution:
Key Concept: Tollen's reagent is a mild oxidizing agent that reacts with reducing sugars. A cyclic carbohydrate acts as a reducing sugar if it contains a hemiacetal or hemiketal group at its anomeric carbon (a carbon atom bonded directly to an −OH group and an internal ring oxygen atom). In solution, hemiacetals can readily open up to expose a free, reactive aldehyde group. Conversely, if the anomeric carbon is bonded to an ether group (−OCH3 or another sugar unit) instead of a free −OH group, it forms an acetal or ketal, which is stable in neutral/alkaline conditions, cannot open into a free carbonyl group, and will not react with Tollen's reagent.
Structure A: Let's examine the rightmost anomeric carbon in this six-membered pyranose ring. The anomeric carbon is directly bonded to a free hydroxyl group (−OH) and a hydrogen atom (−H). Because it forms a hemiacetal linkage, it can undergo ring-opening to generate a free formyl group. Therefore, it acts as a reducing sugar and will react with Tollen's reagent. This statement is FALSE.
Structure B: Let's look closely at the anomeric position on the right side of this pyranose ring. The anomeric carbon is bonded to a methoxy group (−OCH3) rather than an −OH group. This configuration represents a non-reactive methyl glycoside with an acetal linkage. Since it cannot open to form a free aldehyde group under basic Tollen's conditions, it will not react with Tollen's reagent. This statement is TRUE.
Structure C: Let's inspect the anomeric carbon on the right side of this five-membered furanose ring. This carbon atom is directly attached to a methoxy group (−OCH3) and a hydrogen atom (−H). Similar to Structure B, this represents a stable acetal (glycoside) structure that cannot undergo ring-opening to yield a free reducing sugar intermediate. Consequently, it will not react with Tollen's reagent. This statement is TRUE.
Structure D: Let's check the anomeric position on the rightmost carbon of this pyranose ring. This carbon is directly bonded to an alpha/beta hydroxyl group (−OH) and a hydrogen atom (−H). This forms a classic hemiacetal functionality, permitting ring-opening to expose a free aldehyde group. Thus, it acts as a reducing sugar and will react with Tollen's reagent. This statement is FALSE.
Therefore, the cyclic structures that will not react with Tollen's reagent are B and C.
Answer: Option C — B and C
Q 42ChemistrySection A • MCQhydrocarbons
+4 / -1
But-2-yne and hydrogen (one mole each) are separately treated with (i) Pd/C and (ii) Na/ liq. NH3 to give the products X and Y respectively.
Identify the incorrect statements. A. X and Y are stereoisomers. B. Dipole moment of X is zero. C. Boiling point of X is higher than Y. D. X and Y react with O3/Zn+H2O to give different products. Choose the correct answer from the options given below :
A
B and D Only
B
A and B Only
C
B and C Only
D
A and C Only
Official Correct Answer:Option (A)
Step-by-Step Solution:
A. X and Y are stereoisomers: True. They are geometrical isomers (cis and trans).
B. Dipole moment of X is zero: False. In cis-but-2-ene (X), the bond dipoles of the C−CH3 groups reinforce each other, giving a net dipole moment (μ=0). In trans-but-2-ene (Y), the dipoles cancel out, making its dipole moment zero.
C. Boiling point of X is higher than Y: True. Boiling point is directly proportional to the dipole moment. Since the cis isomer (X) is more polar, it has stronger intermolecular forces and a higher boiling point.
D. X and Y react with O3/Zn+H2O to give different products: False.
Reaction Name: Reductive Ozonolysis.
Both cis and trans isomers of But-2-ene break at the double bond to yield two molecules of Ethanal (CH3CHO). The connectivity is the same, so the products are identical.
Q 43ChemistrySection A • MCQaldehydes ketones and carboxylic acids
+4 / -1
'x' is the product which is obtained &om propanenitrile and stannous chloride in the presence of hydrochloric acid followed by hydrolysis. 'y' is the product which is obtained from the but-2-ene by the ozonolysis followed by hydrolysis. From the followu1g, which product is not obtained when one mole of 'x' and one mole of 'y' react with, each other in the presence of alkali followed by heating?
A
Pent-2-enal
B
3-Methylbut-2-enal
C
2-Methylbut-2-enal
D
2-Methylpent-2-enal
Official Correct Answer:Option (B)
Step-by-Step Solution:
We first identify the products x and y.
Finding x: Propanenitrile (CH3CH2CN) is treated with stannous chloride (SnCl2) and hydrochloric acid, followed by hydrolysis. This is the Stephen reduction, which converts a nitrile to an aldehyde. Therefore x=propanal(CH3CH2CHO).
Finding y: But-2-ene (CH3CH=CHCH3) undergoes ozonolysis followed by hydrolysis. The double bond is cleaved to produce two molecules of ethanal (acetaldehyde, CH3CHO). Since we take one mole of the ozonolysis product, y=ethanal(CH3CHO).
When one mole of propanal and one mole of ethanal react in the presence of alkali followed by heating, aldol condensation followed by dehydration takes place. Four α,β-unsaturated aldehyde products are possible:
Product 1 — Self-aldol of ethanal: The enolate of one ethanal molecule attacks the carbonyl of another ethanal. After dehydration this gives CH3CH=CHCHO, which is but-2-enal (crotonaldehyde).
Product 2 — Cross-aldol (ethanal enolate + propanal): The enolate of ethanal (−CH2CHO) attacks the carbonyl carbon of propanal. The resulting aldol product dehydrates to give CH3CH2CH=CHCHO = pent-2-enal.
Product 3 — Cross-aldol (propanal enolate + ethanal): The enolate of propanal (CH3C−HCHO) attacks the carbonyl carbon of ethanal. The aldol product dehydrates to give CH3CH=C(CH3)CHO = 2-methylbut-2-enal.
Product 4 — Self-aldol of propanal: The enolate of one propanal attacks the carbonyl of another propanal. Dehydration gives CH3CH2CH=C(CH3)CHO = 2-methylpent-2-enal.
Now consider the options. 3-Methylbut-2-enal has the structure (CH3)2C=CHCHO. Forming this would require a branched reactant such as acetone or isobutyraldehyde as one of the starting materials, but neither is present in our reaction mixture. Therefore, 3-methylbut-2-enal cannot be obtained from this reaction.
Hence, the correct answer is Option 2.
Q 44ChemistrySection A • MCQelectrochemistry
+4 / -1
In the given electrochemical cell, Ag(s)∣AgCl(s)∣FeCl2(aq), FeCl3(aq)∣Pt(s) at298 K, theceU potential Ecell will increase when: A. Concentration of Fe2+ is increased. B. Concentration of Fe3+ is decreased. C. Concentration of Fe2+ is decreased. D. Concentration of Fe3+ is increased. E. Concentration of Cl− is increased. Choose the correct answer from the options given below :
A
B Only
B
A and B Only
C
C, D and E Only
D
A and E Only
Official Correct Answer:Option (C)
Step-by-Step Solution:
Let us write the two half‐reactions with their standard reduction potentials:
AgCl(s) + e- → Ag(s) + Cl- ; E° = +0.222 V
Fe3+ + e- → Fe2+ ; E° = +0.771 V
Since the Fe3+/Fe2+ couple has the higher E°, it acts as the cathode and AgCl/Ag as the anode. The overall cell reaction is:
Ag(s)+Cl−(aq)+Fe3+(aq)→AgCl(s)+Fe2+(aq) (1)
The standard cell potential is:
Ecell∘=Ecathode∘−Eanode∘=0.771−0.222=0.549 V
The Nernst equation for a one‐electron transfer is:
Ecell=Ecell∘−nFRTlnQ (2)
Here n=1, and the reaction quotient is:
Q=[Fe3+][Cl−][Fe2+] (3)
Substituting (3) into (2) gives:
Ecell=0.549−FRTln([Fe3+][Cl−][Fe2+])
We now examine how changes in concentrations affect Ecell:
Case 1: Increase in [Fe2+]. This raises the numerator of Q, so Q increases and lnQ increases. Hence Ecell decreases.
Case 2: Decrease in [Fe3+]. This lowers the denominator of Q, so Q increases and lnQ increases. Hence Ecell decreases.
Case 3: Decrease in [Fe2+]. This lowers the numerator of Q, so Q decreases and lnQ decreases. Hence Ecell increases.
Case 4: Increase in [Fe3+]. This raises the denominator of Q, so Q decreases and lnQ decreases. Hence Ecell increases.
Case 5: Increase in [Cl−]. This raises the denominator of Q, so Q decreases and lnQ decreases. Hence Ecell increases.
Therefore, the cell potential increases in Cases 3, 4 and 5, corresponding to decreasing [Fe2+], increasing [Fe3+] and increasing [Cl−]. These are options C, D and E. Hence the correct choice is Option C.
Q 45ChemistrySection A • MCQatomic structure
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Given, (A) n=5,m1=−1 (B) n=3,1=2,m1=−1,m2=+21 The maximum number of electron(s) in an atom that can have the quantum numbers as given in (A) and (B) respectively are:
A
26 and 1
B
8 and 1
C
2 and 4
D
4 and 1
Official Correct Answer:Option (B)
Step-by-Step Solution:
(A) n=5, ml=-1: possible in l=1,2,3,4 with ml=-1. Each has 2 electrons: total = 8.
(B) n=3, l=2, ml=-1, ms=+1/2: exactly 1 electron.
The answer is Option 2: 8 and 1.
Q 46ChemistrySection B • Numericalcoordination compounds
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The crystal field splitting energy of [Co(oxalate)3]3− complex is 'n' times that of the [Cr(oxalate)3]3− complex. Here 'n' is_______. (Assume d △∘>>P)
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
Both [Co(oxalate)3]3− and [Cr(oxalate)3]3− are octahedral coordination compounds because each bidentate C2O42− (oxalate) ligand donates two pairs of electrons, giving a total of six donor atoms around the metal ion.
Given the condition △o≫P (crystal-field splitting energy much larger than pairing energy), the electrons prefer to pair up in the lower-energy t2g set before occupying the higher-energy eg set: this is called a low-spin arrangement.
Case 1:Co3+ in [Co(oxalate)3]3−
Atomic number of Co = 27, so Co3+ has 27−3=24 electrons ⇒ 3d6 configuration.
For a low-spin d6 ion in an octahedral field:
Orbital occupancy: t2g6eg0
Crystal-field stabilisation energy (CFSE) formula for an octahedral field:
each t2g electron contributes −0.4△o,
each eg electron contributes +0.6△o.
Therefore, CFSE for Co3+ complex: CFSECo=6(−0.4△o)+0(+0.6△o)=−2.4△o
Case 2:Cr3+ in [Cr(oxalate)3]3−
Atomic number of Cr = 24, so Cr3+ has 24−3=21 electrons ⇒ 3d3 configuration.
For a low-spin d3 ion (high-spin and low-spin are identical for d3):
Orbital occupancy: t2g3eg0
Therefore, CFSE for Cr3+ complex: CFSECr=3(−0.4△o)+0(+0.6△o)=−1.2△o
Now, the question states that the crystal-field splitting energy of the cobalt complex is n times that of the chromium complex, i.e. ∣CFSECo∣=n×∣CFSECr∣
Taking magnitudes (because the energies are negative): 2.4△o=n×1.2△o
Dividing both sides by 1.2△o: n=1.22.4=2
Hence, the required value of n is 2.
Q 47ChemistrySection B • Numericalchemical equilibrium
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For the following gas phase equilibrium reaction at constant temperature, NH3(g)⇌1/2N2(g)+3/2H2(g) if the to tal pressure is 3 atm and the pressure equilibrium constant (Kp) is 9 atm, then the degree of dissociation is given as (x×10−2)−1/2.The value of x is ______. (nearest integer)
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
To find the value of x for the equilibrium NH3(g)⇌21N2(g)+23H2(g), let the initial moles of NH3 be 1 and the degree of dissociation be α. At equilibrium, the moles are NH3=1−α, N2=2α, and H2=23α, so the total moles equal 1−α+2α+23α=1+α.
The total pressure PT is given as 3 atm, which leads to the partial pressures pNH3=1+α1−α⋅3, pN2=1+αα/2⋅3, and pH2=1+α3α/2⋅3.
The expression for Kp is Kp=pNH3pN21/2⋅pH23/2=9 atm, so substitution gives Kp=1+α(1−α)3(2(1+α)α3)1/2⋅(2(1+α)3α3)3/2.
In the numerator, (2(1+α)α3)1/2⋅(2(1+α)3α3)3/2=21/2(1+α)1/2α1/2⋅31/4⋅23/2(1+α)3/233/2α3/2⋅33/4=22⋅(1+α)231/4+3/2+3/4⋅α2=4(1+α)235/2⋅α2.
Solving 4(1−α2)α2=1 gives α2=4−4α2 and hence 5α2=4, so α2=54 and α=52.
Since α=(x×10−2)−1/2, it follows that α2=x×10−21=x100. Equating 54=x100 yields x=4500=125.
Therefore, the answer is 125.
Q 48ChemistrySection B • Numericalsome basic concepts of chemistry
+4 / -1
x mg of pure HCl was used to make an aqueous solution. 25.0 mL of 0.1 M Ba(OH)2 solution is used when the HCl solution was titrated against it. The numerical value of x is ______×10−1. (nearest integer) Given : Molar mass of HCl and Ba(OH)2 are 36.5 and 171.0 g mol−1 respectively.
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
We need to find the mass x (in mg) of pure HCl that reacts completely with 25.0 mL of 0.1 M Ba(OH)2.
The balanced equation is
2HCl+Ba(OH)2→BaCl2+2H2O
and the mole ratio is 2 mol HCl per 1 mol Ba(OH)2.
The moles of Ba(OH)2 are calculated as Molarity × Volume = 0.1×0.025=0.0025 mol, which equals 2.5 mmol.
The moles of HCl required are 2×2.5=5 mmol, or 0.005 mol.
The mass of HCl is then moles × molar mass = 0.005×36.5=0.1825 g, which equals 182.5 mg.
Expressing in the required form gives x=182.5, so x×10−1=1825.
The answer is 1825.
Q 49ChemistrySection B • Numericalhaloalkanes and haloarenes
+4 / -1
Consider all the structural isomers with molecular formula C5H11Br are separately treated with KOH(aq) to give respective substitution products, without any rearrangement. The number of products which can exhibit optical isomerism from these is ______.
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
We need to find all structural isomers of C5H11Br, treat each with aqueous KOH (SN2/SN1 substitution, no rearrangement), and count how many products exhibit optical isomerism.
The structural isomers of C5H11Br (monobromopentanes) are:
Now, substitution with KOH(aq) replaces Br with OH. The product is the corresponding alcohol. For optical isomerism, the product must have a chiral center (asymmetric carbon).
The products that can exhibit optical isomerism are: 2-pentanol (from isomer 2), 3-methyl-2-butanol (from isomer 5), and 2-methyl-1-butanol (from isomer 8).
The answer is 3.
Q 50ChemistrySection B • Numericalchemical kinetics
+4 / -1
For the thermal decomposition of reactant AB(g), the following plot is constructed.
The half life of the reaction is 'x' min. x= ____ min. (Nearest integer)
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
Zero order reaction:
Integrated rate law → [A] = [A]₀ − kt
This is of the form y = mx + c → a straight line between concentration and time
Q 51MathematicsSection A • MCQdefinite integration
+4 / -1
The value of the integral ∫24π245π1+3tan2xdx is:
A
18π
B
6π
C
3π
D
12π
Official Correct Answer:Option (D)
Step-by-Step Solution:
Here, since a+b=24π+245π=4π, applying King’s rule with the substitution x→4π−x transforms the integral into I=∫π/245π/241+tan1/3(2(4π−x))dx=∫π/245π/241+tan1/3(2π−2x)dx.
Using the identity tan(2π−θ)=cotθ=tanθ1 then gives I=∫π/245π/241+(tan2x1)1/3dx=∫π/245π/241+tan1/3(2x)1dx.
Consequently, 2I=245π−24π=244π=6π, which implies I=12π.
Q 52MathematicsSection A • MCQbinomial theorem
+4 / -1
The sum of all possible values of n∈N, so that the coefficients of x,x2 and x3 in the expansion of (1+x2)2(1+x)n, are in arithmetic progression is:
A
7
B
9
C
3
D
12
Official Correct Answer:Option (B)
Step-by-Step Solution:
Since (1+x2)2=1+2x2+x4, we can multiply this by (1+x)n to find the needed coefficients.
(1+x)n=∑r=0n(rn)xr, so each term in the product arises from multiplying one term in (1+x2)2 by one term in this expansion.
Only the product of 1 from the first factor with (1n)x from the second contributes to the coefficient of x, giving (1n)=n.
For the coefficient of x2, the contributions come from 1⋅(2n)x2 and 2x2⋅(0n), which sum to (2n)+2=2n(n−1)+2.
To find the coefficient of x3, we combine 1⋅(3n)x3 with 2x2⋅(1n)x, yielding (3n)+2n=6n(n−1)(n−2)+2n.
Because three numbers a,b,c are in AP precisely when 2b=a+c, we set
2(2n(n−1)+2)=n+6n(n−1)(n−2)+2n
n3−9n2+26n−24=0
(n−2)(n2−7n+12)=0
(n−2)(n−3)(n−4)=0, giving n=2,3,4
sum is 2+3+4=9.
Q 53MathematicsSection A • MCQtrigonometric equations
+4 / -1
Number of solutions of 3cos2θ+8cosθ+33=0,θϵ[−3π,2π] is:
A
0
B
5
C
4
D
3
Official Correct Answer:Option (B)
Step-by-Step Solution:
3cos2θ+8cosθ+33=0
We know that cos2θ=2cos2θ−1
3(2cos2θ−1)+8cosθ+33=0
23cos2θ−3+8cosθ+33=0
23cos2θ+8cosθ+23=0
23cos2θ+6cosθ+2cosθ+23=0
23cosθ(cosθ+3)+2(cosθ+3)=0
(23cosθ+2)(cosθ+3)=0
Thus, there are two solutions possible -> cosθ=−31 and cosθ=−3
Since, the value of cosθϵ[−1,1], therefore, cosθ=−3 is never possible.
Now, cosθ is negative in the second and the third quadrant, and in each cycle of π, cosθ takes all values in [−1,1]. Thus, in every cycle of π, there will be one solution for cosθ=−31.
Thus, from [−3π,2π], there will be 5 solutions for this equation.
Q 54MathematicsSection A • MCQcomplex numbers
+4 / -1
Let S={z:3≤∣2z−3(1+i)∣≤7} be a set of complex nwnbers. Then minZϵS(z+21(5+3i)) is equal to :
A
23
B
21
C
25
D
2
Official Correct Answer:Option (A)
Step-by-Step Solution:
∣2z−3(1+i)∣≤7
2(z−23(1+i))≤7⟹z−23(1+i)≤27
∣2z−3(1+i)∣≥3 gives z−23(1+i)≥23.
So S is the annular region (ring) centered at C1=23(1+i)=23+23i with inner radius r=23 and outer radius R=27.
Next, we identify the target point. We want to minimize z+25+3i=z−(−25+3i), which is the distance from z to the point C2=−25−23i.
The minimum distance from any point in the annular region to C2 occurs along the line connecting C1 and C2, at the point on the outer boundary of the annulus closest to C2. Since C2 is outside the annulus (distance between centers = 5 > outer radius = 7/2 = 3.5), the minimum distance is:
dmin=∣C1−C2∣−R=5−27=210−7=23
C2 lies outside the annulus because ∣C1−C2∣=5>27=3.5, so the closest point on the annulus to C2 is on the outer circle (radius 7/2) along the line from C1 to C2.
The correct answer is Option A: 23.
Q 55MathematicsSection A • MCQvector algebra
+4 / -1
Let a=−i+j+2k,b=i−j−3k,c=a×b and d=c×a. Then (a−b).d is equal to:
A
-2
B
4
C
-4
D
2
Official Correct Answer:Option (A)
Step-by-Step Solution:
sing the determinant form, we have
c=i^−11j^1−1k^2−3=i^(1⋅(−3)−2⋅(−1))−j^((−1)(−3)−2⋅1)+k^((−1)(−1)−1⋅1)=i^(−3+2)−j^(3−2)+k^(1−1)=−i^−j^+0k^
so c=(−1,−1,0).
Next, we compute d=c×a. Again using the determinant,
d=i^−1−1j^−11k^02=i^((−1)(2)−0⋅1)−j^((−1)(2)−0⋅(−1))+k^((−1)(1)−(−1)(−1))=i^(−2)−j^(−2)+k^(−1−1)=−2i^+2j^−2k^
which gives d=(−2,2,−2).
Then
a−b=(−1−1,1−(−1),2−(−3))=(−2,2,5),
and the dot product is
(a−b)⋅d=(−2)(−2)+(2)(2)+(5)(−2)=4+4−10=−2.
Q 56MathematicsSection A • MCQquadratic equations
+4 / -1
A building construction work can be completed by two masons A and B together in 22.5 days. Mason A alone can complete the construction work in 24 days less than mason B alone. Then mason A alone will complete the construction work in :
A
36 days
B
24 days
C
42 days
D
30 days
Official Correct Answer:Option (A)
Step-by-Step Solution:
Let the time taken by A to complete the construction be a days. Then B’s time = a+24 days.
If the total work is say 1 unit, then work done by A in one day is a1 units , and work by B is a+241 units.
Given, a1+a+241=22.51 [work done by A in one day+ work by B in one day= total work done in one day]
or, a(a+24)(a+24)+a=22.51
or, a(a+24)2a+24=22.51
or, 22.5(2a+24)=a(a+24)
or, 45a+540=a2+24a
or, a2−21a−540=0
or, a=221±212+4⋅540
or, a=221±441+2160=221±2601=221±51
Since, the number of days cannot be negative, so a=272=36days
Q 57MathematicsSection A • MCQhyperbola
+4 / -1
Let the domain of the function f(x)=log3log5log7(9x−x2−13) be the interval (m, n). Let the hyperbola a2x2−b2y2=1 have eccentricity 3n and the length of the latus rectum 38m. Then b2−a2 is equal to:
A
11
B
7
C
5
D
9
Official Correct Answer:Option (B)
Step-by-Step Solution:
9x−x2−13>0 log7(9x−x2−13)>1⟹9x−x2−13>7
The second inequality is stronger, so we keep it: 9x−x2−13>7⟹9x−x2−20>0 −x2+9x−20>0⟹x2−9x+20<0 x2−9x+20=(x−4)(x−5)
the domain is the open interval(4,5)
Thus m=4 and n=5.
For the hyperbola a2x2−b2y2=1:
• Eccentricity e=3n=35
• Length of the latus rectum L=38m=38×4=332
The standard results for such a hyperbola are
e2=1+a2b2 L=a2b2
(35)2=1+a2b2⟹925=1+a2b2
a2b2=925−1=916⟹b2=916a2
Using the latus-rectum length:
a2b2=332⟹b2=316a
916a2=316a⟹91a2=31a⟹a2=3a⟹a(a−3)=0
Since a>0, we take a=3, giving a2=9.
Substitute back to find b2:
b2=916a2=916×9=16
b2−a2=16−9=7
Q 58MathematicsSection A • MCQbinomial theorem
+4 / -1
The value of 51100C50+52100C51+...+101100C100 is:
A
1012100
B
1002100
C
1012101
D
1002101
Official Correct Answer:Option (A)
Step-by-Step Solution:
We use the identity r+1(rn)=n+11(r+1n+1) which can be verified as follows:
Applying this identity with n=100 shows that each term r+1(r100) becomes 1011(r+1101). Hence, the given sum can be rewritten as
S=∑r=50100r+1(r100)=1011∑r=50100(r+1101)
Setting k=r+1 transforms the limits: when r=50, k=51; when r=100, k=101. Therefore,
S=1011∑k=51101(k101)
Since the binomial coefficients satisfy ∑k=0101(k101)=2101 and, by symmetry (k101)=(101−k101), the sum over k from 51 to 101 equals the sum from 0 to 50. Each half is therefore 2100. It follows that
S=1011×2100=1012100
The correct answer is Option A: 1012100.
Q 59MathematicsSection A • MCQ3d geometry
+4 / -1
The vertices B and C of a triangle ABC lie on the line 1x=−21−y=3z−2 The coordinates of A and B are (1, 6, 3) and (4, 9, α) respectively and C is at a distance of 10 units from B. The area (in sq. units) of △ABC is :
A
513
B
1013
C
1513
D
2013
Official Correct Answer:Option (A)
Step-by-Step Solution:
Parametrize the line: x=t; y=1-2t; z=2+3t ⇒C(t,1−2t,2+3t)
be continuous at x=−23. If fof(x)=57 then x is equal to:
A
2
B
1.4
C
0
D
1
Official Correct Answer:Option (D)
Step-by-Step Solution:
The given function is f(x)=⎩⎨⎧4x2+4x−3ax2+2ax+3,b,x=−23,21x=−23,21
For continuity, the limit of the first branch as x→−23 must be finite, so both numerator and denominator must vanish there:
Denominator: 4x2+4x−3=0 at x=−23 (verify: 4(2.25)−6−3=0).
For x=−23,21 the common factor 2x+3 cancels, giving f(x)=2x−12x+1(with a hole at x=−23).
The limit as x→−23 of the simplified form is b=f(−23)=2(−23)−12(−23)+1=−3−1−3+1=−4−2=21.
Let y=f(x)=2x−12x+1 (defined for x=21,−23). f(f(x))=f(y)=2y−12y+1. 2y−12y+1=57 y=3.
2x−12x+1=3 x=1.
Check the domain: x=1 is not 21 or −23, so it is valid.
Therefore, the required value of x is 1.
Option D.
Q 61MathematicsSection A • MCQstraight lines and pair of straight lines
+4 / -1
A rectangle is formed by the lines x= 0, y = 0, x=3 and y = 4. Let the line L be perpendicular to 3x +y + 6 = 0 and divide the area of the rectangle into two equal parts. Then the distance of the point (21,−5) from the line L is equal to :
A
210
B
10
C
310
D
25
Official Correct Answer:Option (A)
Step-by-Step Solution:
Rectangle vertices are bounded by x=0,y=0,x=3,y=4
Center of the rectangle: C=(23,2)
Line L is perpendicular to 3x+y+6=0: Slope of L(mL)=−3−1=31
Equation of line L passing through C(23,2):
y−2=31(x−23)⟹3y−6=x−23⟹2x−6y+9=0
Perpendicular distance d of point P(21,−5) from line L:
d=22+(−6)2∣2(21)−6(−5)+9∣
d=40∣1+30+9∣=4040=40=210
Q 62MathematicsSection A • MCQtrigonometric ratios and identities
+4 / -1
Let α and β respectively be the maximum and the minimum values of the function f(θ)=4(sin4(27π−θ)+sin4(11π+θ))−2(sin6(23π−θ)+sin6(9π−θ)),θ∈R. Then α+2β is equal to:
Let the direction cosines of two lines satisfy the equations : 4l + m - n =0 and 2mn +10nl +3lm= 0. Then the cosine of the acute angle between these lines is :
A
33820
B
3810
C
33810
D
73810
Official Correct Answer:Option (C)
Step-by-Step Solution:
We are given two equations for direction cosines (l,m,n): 4l+m−n=0⋯(1) and 2mn+10nl+3lm=0⋯(2).
First, from (1) we have n=4l+m, and substituting this into (2) gives 2m(4l+m)+10(4l+m)l+3lm=0, which simplifies to 40l2+21lm+2m2=0.
Next, dividing by m2 let t=l/m
40t2+21t+2=0.
t=80−21±441−320=80−21±121=80−21±11, so t1=−81 and t2=−52.
For the first line, where l/m=−81, we may choose l=−1 and m=8, which leads to n=4(−1)+8=4, giving the direction ratios (−1,8,4).
Similarly, for the second line with l/m=−52, setting l=−2 and m=5 yields n=4(−2)+5=−3, so the direction ratios are (−2,5,−3).
Finally, the cosine of the acute angle between these two vectors is cosθ=1+64+164+25+9∣(−1)(−2)+(8)(5)+(4)(−3)∣=8138∣2+40−12∣=93830=33810.
Q 64MathematicsSection A • MCQquadratic equations
+4 / -1
If α and β (α<β) are the roots of the equation (−2+3)(∣x−3∣)+(x−6x)+(9−23)=0,x≥0 then αβ+αβ is equal to:
A
9
B
10
C
8
D
11
Official Correct Answer:Option (B)
Step-by-Step Solution:
To solve this equation, let's look for a way to simplify it using substitution.
Notice that the terms (x−6x) and the 9 from the last constant term can be grouped to form a perfect square:
x−6x+9=(x−3)2=∣x−3∣2
Substitute this back into the original equation to reorganize it:
(−2+3)∣x−3∣+∣x−3∣2−23=0
Let t=∣x−3∣. Since t represents an absolute value, we know that t≥0.
The equation now becomes a standard quadratic in terms of t:
t2+(−2+3)t−23=0
We can factor this quadratic by splitting the middle term:
t2−2t+3t−23=0
t(t−2)+3(t−2)=0
(t−2)(t+3)=0
This gives two possible values for t:
t=2 or t=−3
Since we established that t≥0, we reject −3. Therefore, t=2.
Substitute back t=∣x−3∣:
∣x−3∣=2
This results in two distinct cases:
x−3=2⟹x=5⟹x=25
x−3=−2⟹x=1⟹x=1
The roots of the equation are 1 and 25. We are given that α and β are the roots with α<β, which means:
α=1
β=25
Finally, substitute these values into the expression we need to evaluate:
αβ+αβ
=125+(1)(25)
=5+5=10
Q 65MathematicsSection A • MCQstatistics
+4 / -1
Let the mean and variance of 8 numbers - 10, - 7, - 1, x, y, 9, 2, 16 be 27 and 4293 respectively. Then the mean of 4 numbers x, y, x + y + 1, |x-y| is:
A
11
B
12
C
10
D
9
Official Correct Answer:Option (A)
Step-by-Step Solution:
Sum of the eight numbers = −10+(−7)+(−1)+x+y+9+2+16=9+x+y.
Mean is given by the formula Mean=nSum of terms. Here n=8 and the mean is 27, so
Using the identity (x+y)2=x2+y2+2xy and substituting (2) and (3):
192=193+2xy⟹361=193+2xy⟹2xy=168⟹xy=84−(4)
Now compute (x−y)2 via
(x−y)2=(x+y)2−4xy=361−4×84=361−336=25.
∣x−y∣=5.
The four numbers whose mean is required are x,y,x+y+1,∣x−y∣. Their sum is
x+y+(x+y+1)+∣x−y∣=19+20+5=44.
Hence the mean of these four numbers is
444=11.
Q 66MathematicsSection A • MCQmatrices and determinants
+4 / -1
Among the statements : I: If 1mathbfcosαmathbfcosβcosα1cosγcosβcosγ1=0mathbfcosαmathbfcosβcosα0cosγcosβcosγ0, then cos2α+cos2β+cos2γ=23, and
II: x2+x2x2+3x−1x2+2x+3x+13x2x−1x−23x−32x−1=px+q, then p2=196q2
A
only I is true
B
both are false
C
only II is true
D
both are true
Official Correct Answer:Option (B)
Step-by-Step Solution:
Statement I
Put a=cosα,b=cosβ,c=cosγ.
The first determinant becomes
Δ1=1aba1cbc1
For any symmetric matrix of this type the standard expansion gives Δ1=1+2abc−a2−b2−c2.−(1)
Thus p=24,q=−12 and p2=242=576,196q2=196⋅144=28224=576.
Hence Statement II is also false.
Both statements are false → Option B.
Q 67MathematicsSection A • MCQellipse
+4 / -1
Let the line y - x = 1 intersect the ellipse 2x2+1y2=1 at the points A and B. Then the angle made by the line segment AB at the center of the ellipse is:
A
2π+2tan−1(41)
B
π−tan−1(41)
C
2π−tan−1(41)
D
2π+tan−1(41)
Official Correct Answer:Option (D)
Step-by-Step Solution:
Substituting y=x+1 into the ellipse equation gives
2x2+(x+1)2=1
which simplifies to
2x2+x2+2x+1=1⟹23x2+2x=0⟹x(3x+4)=0,
so that x=0 or x=−34.
When x=0, we have y=1, hence A=(0,1). When x=−34, we get y=−34+1=−31, so B=(−34,−31).
Next, we denote OA=(0,1) and OB=(−34,−31) and use the dot-product formula
cosθ=∣OA∣∣OB∣OA⋅OB.
Since OA⋅OB=0⋅(−34)+1⋅(−31)=−31,
∣OA∣=1,∣OB∣=916+91=317,
cosθ=1⋅(17/3)−31=−171.
Because cosθ=−171, it follows that
θ=π−cos−1(171).
On the other hand, if we set tanϕ=4 with ϕ=tan−1(4), then in a right triangle with opposite side 4 and adjacent side 1 the hypotenuse is 17, so cosϕ=171 and hence cos−1(171)=tan−1(4).
Moreover, by the complementary-angle identity, tan−1(4)=2π−tan−1(41). Therefore
θ=π−(2π−tan−1(41))=2π+tan−1(41).
Q 68MathematicsSection A • MCQindefinite integration
+4 / -1
Let f(x)=∫(1+x)(1−x)23(2−x2).exdx. If f(0)=0, then f(21) is equal to:
A
3e+1
B
2e−1
C
2e+1
D
3e−1
Official Correct Answer:Option (D)
Step-by-Step Solution:
2−x2=1+(1−x)(1+x), the integrand splits as ex(1+x(1−x)3/21+1−x1+x).
Let g(x)=1−x1+x. Then g′(x)=(1−x)3/21+x1.
ex(g(x)+g′(x)).
Using the identity ∫ex(g+g′)dx=exg+C gives f(x)=ex1−x1+x+C.
Substituting f(0)=0 yields 1+C=0, so C=−1.
Therefore f(21)=e3−1=3e−1, and the correct answer is Option 4.
Q 69MathematicsSection A • MCQsets and relations
+4 / -1
Let A= {- 2, - 1, 0, 1, 2, 3, 4}. Let R be a relation on A defined by xRy if and only if ∣2x+y∣≤3. Let l be the number of elements in R. Let m and n be the minimun number of elements required to be added in R to make it reflexive and symmetric relations respectively. Then l+ m + n is equal to:
A
35
B
32
C
34
D
33
Official Correct Answer:Option (D)
Step-by-Step Solution:
A=−2,−1,0,1,2,3,4,xRy⇔∣2x+y∣≤3
Count pairs for each (x):
(x=−2:y=1,2,3,4⇒4)
(x=−1:y=−1,0,1,2,3,4⇒6)
(x=0:y=−2,−1,0,1,2,3⇒6)
(x=1:y=−2,−1,0,1⇒4)
(x=2:y=−2,−1⇒2)
l=4+6+6+4+2=22
For reflexive relation, missing: (-2,-2),(2,2),(3,3),(4,4) Hence m=4
For symmetry, missing reverse pairs: (-1,-2),(0,-2),(0,2),(1,-1),(1,2),(2,-2),(2,0) Hence n=7 l+m+n=22+4+7=33
Q 70MathematicsSection A • MCQdifferential equations
+4 / -1
Let y = y(x) be the solution of the differential equation x4dy+(4x3y+2sinx)dx=0,x>0,y(2π)=0. Then π4y(3π) is equal to :
A
81
B
64
C
72
D
92
Official Correct Answer:Option (A)
Step-by-Step Solution:
x4dy+(4x3y+2sinx)dx=0.
x4dxdy+4x3y+2sinx=0.
Divide both sides by x4
dxdy+x4y=−x42sinx−(1)
The integrating factor is given by
μ(x)=e∫P(x)dx,
where P(x)=x4
μ(x)=e∫x4dx=e4lnx=x4−(2)
Multiply equation (1) by μ(x)=x4.
The left side becomes the derivative of the product x4y, and the right side simplifies as follows:
x4dxdy+4x3y=dxd(x4y),x4⋅(−x42sinx)=−2sinx. \
Therefore we get
dxd(x4y)=−2sinx−(3)
Integrate both sides of (3) with respect to x:
∫dxd(x4y)dx=∫−2sinxdx
gives
x4y=2cosx+C−(4)
Use the initial condition y(2π)=0 in (4):
(2π)4⋅0=2cos(2π)+C⟹0=2⋅0+C⟹C=0.
Thus the particular solution is
y=x42cosx.
Finally, we compute
π4y(3π)=π4⋅(3π)42cos(3π)=π4⋅34π42⋅21=1⋅134=81.
π4y(3π)=81.
Option A is the correct answer.
Q 71MathematicsSection B • Numericalpermutations and combinations
+4 / -1
The number of 4-letter words, with or without meaning, which can be formed using the letters PQRPQRSTUVP, is ___ .
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
The word given is PQRPQRSTUVP. Here, we have P 3 times, Q 2 times, R 3 times, and S,T,U,V one time each Total distinct letters: 7
We form 4-letter words using these.
Case 1: All letters are distinct
Here, 4 distinct letters can be chosen from 7 letters in 7C4=7⋅6⋅5⋅4=840 ways
Case 2: One pair + two distinct
To choose a pair, we need to pick one from the letters that occur 2 times or more in the word. Of the letters P,Q and R occure more than once, so the letter that will form the pair can be picked in 3 ways. For the remaining 2 distinct letters, they can be picked from the remaining 6 letters in (26)=15 ways. These can be arranged amongst themselves in 2!4!=12 ways
Total number of ways words can be formed is= 3⋅15⋅12=540 ways
Case 3: Two pairs
Here, we need to choose 2 letters (each must occur ≥2 times): from (P,Q,R), which can be done in 3 ways. The letters can be arranged amongst themselves in 2!2!4!=6 ways
Total number of ways words can be formed is 3⋅6=18 ways
Case 4: Three same + one different
Only P occurs three times, so here it can be picked in 1 way, and the 1 different letter from the remaining 6 can be picked in 6 ways. The letters can be arranged amongst themselves in 3!4!=4
Total number of ways words can be formed is 1⋅6⋅4=24 ways
Hence, the total number of ways words can be formed considering all the cases is 840+540+18+24=1422 ways
Q 72MathematicsSection B • Numericaldifferential equations
+4 / -1
Let f be a twice differentiable non-negative function such that (f(x))2=25+∫0x((f(t))2+(f′(t))2)dt. Then the mean of f(loge(1)),f(loge(2)),.....,f(loge(625)) is equal to:
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
differentiating both sides with respect to x.
2f(x)f′(x) = (f(x))2+(f′(x))2
(f′(x)−f(x))2=0
f'(x) - f(x) = 0\
dxdf=f(x)
f(x)1df=dx
so integrating both sides leads to
∫f(x)1df=∫1dx⟹lnf(x)=x+C,
whence
f(x)=Cex
for some constant C.
(f(0))2=25+∫00((f(t))2+(f′(t))2)dt=25.
Since f is non-negative it follows that f(0)=5, so C=5 and
f(x)=5ex.
Noting that for any positive integer k we have
f(lnk)=5elnk=5k,
the sum of these 625 values is
∑k=16255k=5∑k=1625k=5⋅2625⋅626.
Therefore the mean is
6251×5×2625×626=25×626=5×313=1565.
Q 73MathematicsSection B • Numericalmatrices and determinants
+4 / -1
Let |A|=6, Where A is a 3×3 matrix. If ∣adj(3adj(A2⋅adj(2A)))∣=2m⋅3n,m,nϵN, then m+n is equal to:
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
Since ∣A∣=6 for a 3×3 matrix A, we need to find ∣adj(3adj(A2⋅adj(2A)))∣=2m⋅3n.
3×3 matrix M, one has ∣adj(M)∣=∣M∣2 and ∣kM∣=k3∣M∣.
Substituting k=2 gives ∣2A∣=23⋅∣A∣=8⋅6=48.
This yields ∣adj(2A)∣=∣2A∣2=482=2304.
Since ∣A2∣=∣A∣2=36, it follows that ∣A2⋅adj(2A)∣=∣A2∣⋅∣adj(2A)∣=36⋅2304=82944.
Factoring 82944=36⋅2304=62⋅482=(6⋅48)2=2882 and noting 288=25⋅32 gives 2882=210⋅34.
∣adj(A2⋅adj(2A))∣=∣A2⋅adj(2A)∣2=(210⋅34)2=220⋅38.
Multiplying by 3 yields ∣3adj(A2⋅adj(2A))∣=33⋅∣adj(A2⋅adj(2A))∣=27⋅220⋅38=220⋅311.
Finally, ∣adj(3adj(A2⋅adj(2A)))∣=∣3adj(A2⋅adj(2A))∣2=(220⋅311)2=240⋅322, so m=40 and n=22, giving m+n=62.
Q 74MathematicsSection B • Numericalprobability
+4 / -1
From the first 100 natural numbers, two numbers first a and then b are selected randomly without replacement. If the probability that a−b≥10 is nm, gcd (m, n) = 1, then m + n is equal to______.
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
We select two numbers, a and then b from the first 100 natural numbers without replacement.
Thus the total number of ordered selections is 100×99=9900
We need P(a−b≥10)
∴(a≥b+10)
So for every chosen a, the value of b must be at least 10 or less than a.
The smallest possible a satisfying the condition is 11.
For each a, the possible values of b are:
1,2,3,…,a−10
Number of choices for b: a−10
Favourable outcomes:
Σa=11a=100(a−10)
Let k=a-10
∴Σk=1k=90(k)
sum=2(90(90+1))=4095
P=99004095
When we simplify for coprime, we get 99004095=22091
∴ m=91 and n=220
m+n=91+220=311
Hence, our answer is 311.
Q 75MathematicsSection B • Numericalarea under the curves
+4 / -1
Let the area of the region bounded by the curve y= max {sinx,cosx}, lines x = O, x=23π, and the x-axis be A. Then, A+A2 is equal to_____.
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
We need to find the area A bounded by y=max{sinx,cosx}, x=0, x=23π, and the x-axis.
- [0,4π]: cosx≥sinx, so y=cosx
- [4π,45π]: sinx≥cosx, so y=sinx
- [45π,23π]: cosx≥sinx, so y=cosx
The area between the curve and x-axis counts absolute values. The function max{sinx,cosx}:
- Is positive on [0,π]
- Becomes negative: sinx<0 for x∈(π,2π), and cosx<0 for x∈(2π,23π)