
[p = Total pressure at equilibrium = 1.9 atm]
Now, at equilibrium pV = (1 + 2x)RT
⇒1+2x=RTpV=0.082×3001.9×25=1.93
[V = 25 L, R = 0.082 L atm mol−1 K−1 T = 300 K]
⇒x=21.93−1=0.465
⇒Kp=pAB2pA×pB2⇒(1+2x1−xp)(1+2xxp)×(1+2x2xp)2
=(1+2x)34x3×p3×(1−x)×p(1+2x)=(1+2x)2×(1−x)4x3×p2
=(1+2×0.465)2×(1−0.465)4×(0.465)3×(1.9)2=0.7285 atm
=72.85×10−2 atm ≃73×10−2=x×10−2
∴ x=73