Principles of Green Chemistry Relevant to the Options:
Reduce Derivatives (Principle 8):
Avoid unnecessary derivatization such as protection/deprotection steps because they require additional reagents and generate waste.
Use of Renewable Feedstocks (Principle 7):
Prefer renewable raw materials over depleting resources like crude oil.
Design for Degradation (Principle 10):
Chemical products should be designed to break down into non-harmful substances after use.
Safer Solvents and Auxiliaries (Principle 5):
Use safer solvents or eliminate the need for solvents when possible.
Option Analysis:
Option A:
Statement: It is good to use the technique of protection and deprotection of functional group in organic synthesis.
Analysis:
Protection and deprotection steps involve adding and removing protective groups to functional groups in a molecule.
These steps increase the number of reactions, use extra reagents, and generate additional waste.
According to Principle 8, such steps should be minimized or avoided to reduce waste and improve efficiency.
Conclusion: This statement is NOT true according to green chemistry principles.
Option B:
Statement: Use of chemicals derived from plant resources is better than crude oil.
Analysis:
Plant resources are renewable, whereas crude oil is a non-renewable fossil fuel.
Principle 7 advocates for the use of renewable feedstocks.
Conclusion: This statement is true according to green chemistry principles.
Option C:
Statement: Use of biodegradable pesticides is advantageous.
Analysis:
Biodegradable pesticides break down into harmless substances, reducing environmental impact.
This aligns with Principle 10, which promotes designing products that degrade after use.
Conclusion: This statement is true according to green chemistry principles.
Option D:
Statement: Use of critical as solvent is better than organic solvents.
Analysis:
Supercritical is a green solvent: non-toxic, non-flammable, and recyclable.
It reduces the need for hazardous organic solvents.
This supports Principle 5, which encourages the use of safer solvents.
Conclusion: This statement is true according to green chemistry principles.
Final Answer:
Option A
Explanation:
Option A contradicts the principles of green chemistry by promoting the use of protection and deprotection steps, which are discouraged under Principle 8 due to increased waste and resource consumption.
Options B, C, and D are consistent with green chemistry principles, advocating for renewable resources, biodegradable products, and safer solvents, respectively.
Answer: Option A