Official NTA Question PaperFull Solved Paper2026Paper 2
JEE Advanced 2026 Paper 2 Question Paper with Solutions
Official solved question paper for Joint Entrance Examination (Advanced). Review all 54 questions, official answer keys, and detailed step-by-step solutions below, or attempt online with timer and negative marking.
A metal wire of cross-sectional area 0.5mm2 and length 100m is connected across a battery of e.m.f. 2V and internal resistance 1Ω. The density, atomic mass and electrical conductivity of the metal are 6.35×103kgm−3, 63.5gm/mole and 2×108mhom−1, respectively. Assuming one conduction electron per atom of the metal, the drift velocity (in mms−1) of the electrons in the wire is:
[Take Avogadro's number as 6×1023 and charge of the electron as 1.6×10−19C.]
A
0.052
B
0.104
C
0.208
D
0.156
Official Correct Answer:Option (C)
Step-by-Step Solution:
For a conductor of uniform cross-sectional area A and length L, the number of conduction electrons per unit
volume (number density) is n.
If the electrons drift with an average velocity , electric current I is defined as the rate of flow of charge:
The drift velocity is,
It is given that each atom contributes exactly one conduction electron. Therefore, the number density of
electrons n is equal to the number density of atoms in the metal.
Let the mass density of the metal be and its molar mass be .
The volume of one mole of the metal is:
One mole of any substance contains Avogadro's number of atoms.
Since there is 1 conduction electron per atom, one mole contains conduction electrons. The number of
electrons per unit volume is:
The density is
The molar mass is
Avogadro's number is
Substituting values into the expression for n:
The resistance R of a wire depends on its length L, cross-sectional area A, and electrical conductivity . By
definition, resistivity is the reciprocal of conductivity .
The length of wire is
Electrical conductivity is
The cross-sectional area is
Substituting these values:
The wire is connected to a battery of electromotive force (e.m.f.) and internal resistance .
By Ohm's law applied to the total closed loop, the total circuit current I is :
Substituting the values of and :
Now substituting the values of current , number density , electron charge , and cross-sectional area into the drift velocity equation:
The current is
The number density is
The electronic charge is
And area of cross-section is
Therefore, the drift velocity of electron in given conductor is . Hence, the correct option is (C).
Q 2PhysicsSection A • MCQatoms and nuclei
+3 / -1
A nuclear reactor starts producing a radioactive nuclide X from t=0, at a constant rate of α per second. Each decay of X produces energy E0, which is utilized to heat a liquid of mass m and specific heat s. Assuming no heat loss from the liquid and taking λ as the decay constant of X, the rate of increase in the temperature of the liquid is:
A
msαE0(1−e−λt)
B
msαE0(eλt−1)
C
msλE0(1−e−λt)
D
msE0(α−λe−λt)
Official Correct Answer:Option (A)
Step-by-Step Solution:
Let N(t) be the number of active nuclei of the radioactive substance X present in the reactor at any time t.
The net rate of change of the number of nuclei (dtdN) is of concurrent processes, the production of nuclei at a constant rate, which is +α and the decay of nuclei which is proportional to the number of nuclei present, given by −λN.
dtdN=α−λN
α−λNdN=dt
At t=0, the reactor just starts producing the nuclide, so the initial number of nuclei is N=0.
At time t, let the number of nuclei be N:
0∫Nα−λNdN=0∫tdt
For integral 0∫Nα−λNdN, on substitution u=α−λN→du=−λdN→dN=−λdu
0∫Nα−λNdN=∫u1(−λdu)=−λ1ln∣u∣=−λ1ln∣α−λN∣
=[−λ1ln(α−λN)]0N=t
ln(α−λN)−ln(α)=−λt
Using the logarithmic identity lnA−lnB=lnBA:
ln(αα−λN)=−λt
αα−λN=e−λt
α−λN=αe−λt
λN=α−αe−λt
λN=α(1−e−λt)
The activity A(t) of a radioactive sample is the total number of decays occurring per second.
A(t)=λN
A(t)=α(1−e−λt)
Each decay releases a fixed amount of thermal energy E0. Therefore, the total thermal energy released per unit time (the power input to the liquid, dtdQ) is
dtdQ=A(t)⋅E0=αE0(1−e−λt)
When heat energy Q is supplied to a liquid of mass m and specific heat capacity s, the relationship between the heat supplied and the resulting temperature rise ΔT is given by
Q=msΔT
For an infinitesimal change over time dt,
dQ=msdT
dtdQ=msdtdT
dtdT=ms1(dtdQ)
dtdT=ms1[αE0(1−e−λt)]
dtdT=msαE0(1−e−λt)
Therefore, the rate of increase of temperature of liquid is msαE0(1−e−λt). Thus, the correct option is (A).
Q 3PhysicsSection A • MCQray optics
+3 / -1
A beam of polychromatic light passes through a thin prism of prism angle 6∘. The refractive index of the material of the prism varies with wavelength (λ) as n(λ)=αλ+λ2β, where α=3μm−1 and β=0.096μm2. If λmin is the wavelength at which the angle of minimum deviation Dm is smallest, then the correct value of Dm at λmin is
A
6.4∘
B
4.8∘
C
3.2∘
D
2.4∘
Official Correct Answer:Option (B)
Step-by-Step Solution:
For a thin prism with a small angle A=6∘, the deviation Dm is given by:
' in math mode at position 1:̲D_m = (n - 1)A" style="color:#cc0000">Dm=(n−1)A</span>
To find the wavelength λmin at which Dm is smallest, we minimize the refractive index n(λ), where:
n(λ)=αλ+λ2β
Differentiating n(λ) with respect to λ and setting the derivative to zero:
dλdn=α−λ32β=0
λmin3=α2β
Substituting α=3μm−1 and β=0.096μm2:
λmin3=32×0.096=0.064μm3
λmin=30.064=0.4μm
Calculating the refractive index at λmin:
nmin=3(0.4)+(0.4)20.096=1.2+0.6=1.8
Substituting nmin back into the deviation equation:
Dm=(1.8−1)×6∘=0.8×6∘=4.8∘
The correct value of Dm at λmin is 4.8∘.
Q 4PhysicsSection A • MCQgravitation
+3 / -1
A particle of mass m, and angular momentum ℓ is moving in a circular orbit of radius r0 under the influence of an attractive force F(r)=−r2kr^. Keeping its angular momentum unchanged, the particle is displaced radially by a small distance δr≪r0, due to which its radial distance varies periodically. The corresponding time period is:
A
mk22πℓ3
B
2πkm
C
3mk22πℓ3
D
5mk22πℓ3
Official Correct Answer:Option (A)
Step-by-Step Solution:
The particle of mass m moving in a plane under a central force field F(r)=F(r)r^.
In polar coordinates (r,θ), the position vector is r=rr^.
Differentiating the position vector with respect to time gives the velocity vector:
By Newton's second law, F=ma. Since the force is purely radial, the transverse component of acceleration must be zero, which means the angular momentum l is a conserved quantity.
l=mr2ω⇒dtdθ=mr2l
Using Newton's second law for the radial component:
m(dt2d2r−r(dtdθ)2)=F(r)
m(dt2d2r−r(mr2l)2)=F(r)
mdt2d2r−mr3l2=F(r)
mdt2d2r=mr3l2+F(r)
The given attractive force is F(r)=−kr2, the equation becomes:
mdt2d2r=mr3l2−kr2
For a perfect circular orbit of constant radius r0, the radial distance does not change over time,
dtdr=0 and dt2d2r=0.
From the radial equation of motion:
mr03l2−r02k=0
mr03l2=r02k⇒r0=mkl2
When the particle is given a small radial displacement δr from its equilibrium position r0. Let its instantaneous radius be:
r=r0+δr
Taking the second time derivative, since r0 is a constant:
dt2d2r=dt2d2(r0+δr)=dt2d2δr
mdt2d2δr=m(r0+δr)3l2−(r0+δr)2k
mdt2d2δr=mr03(1+r0δr)3l2−r02(1+r0δr)2k
mdt2d2δr=mr03l2(1+r0δr)−3−r02k(1+r0δr)−2
mdt2d2δr=mr03l2(1+r0δr)−3−r02k(1+r0δr)−2
Since δr≪r0, we can use the binomial expansion (1+x)n≈1+nx for ∣x∣≪1:
mdt2d2δr≈mr03l2(1−3r0δr)−r02k(1−2r0δr)
mdt2d2δr≈(mr03l2−r02k)−(mr033l2−r022k)δr
From the equilibrium condition mr03l2−r02k=0.
mdt2d2δr≈=−(mr043l2−r032k)δr
Substituting l2=mkr0 from the equilibrium condition
mr043(mkr0)−r032k=r033k−r032k=r03k
The standard simple harmonic motion (SHM) form dt2d2δr=−ω2δr :
mdt2d2δr=−r03kδr⇒dt2d2δr=−(mr03k)δr
Thus, the angular frequency of the radial oscillations is:
ω=mr03k
The relationship for the time period T of an oscillation is:
Consider two isosceles prisms 1 and 2 with prism angles A1 and A2 and refractive indices n1 and n2, respectively, as shown in the figure. The faces a1b1 and a2b2 are parallel to each other and perpendicular to the mirror M. If a ray of light is incident on the face a1c1 and emerges from the face a2c2, then the correct statement(s) is/are:
A
If both the prisms are at minimum deviation condition, then n1n2=sin(2A1)/sin(2A2).
B
If prism 2 is at minimum deviation condition, then sini1=n2sin(2A2) is always true.
C
If both the prisms 1 and 2 are at minimum deviation condition with angles of deviation δm1 and δm2, respectively, then θ=2(n1−1)δm1+2(n2−1)δm2.
D
If prism 1 is at minimum deviation condition, then sini2=n1sin(2A1) is always true.
Official Correct Answer:Option (A, C, D)
Step-by-Step Solution:
(A) sini1=sine1=n1sin2A1
sini2=sine2=n2sin2A2
e1=i2⇒n1sin2A1=n2sin2A2
(B) i2=e2=e1
sini2=n2sin2A2
But i1=i2
(C) δ1=(μ1−1)A1,δ2=(μ2−1)A2
21(μ1−1δ1)+21(μ2−1δ2)=212A1+2A2=θ
(D) i1=e1=i2
sini1=n1sin2A1
Q 6PhysicsSection A • MCQmagnetism
+4 / -0
In a vacuum chamber, a particle of charge 1μC and mass 1mg is projected with a velocity (i^+2j^)ms−1 from the XZ plane at time t=0 in an electric field of 1i^Vm−1. At t=0.2s, the electric field is switched off and a magnetic field of 6j^T is switched on. The acceleration due to gravity is −10j^ms−2. Correct option(s) is/are:
A
The vertical distance of the particle from the XZ plane at t=0.3s is 15cm.
B
The vertical distance of the particle from the XZ plane at t=0.4s is 10cm.
C
The radius of the trajectory of the particle for t>0.2s is 20cm.
D
The particle will be in the XZ plane at t=0.35s.
Official Correct Answer:Option (A, C)
Step-by-Step Solution:
During this first interval (t=0→t=0.2s), the particle experiences a uniform electric field E=1i^Vm−1 and a uniform gravitational field g=−10j^ms−2.
The charge on particle is, q=1μC=10−6C
The mass of the particle is, m=1mg=10−6kg
The net force acting on the particle is the vector sum of the electric force and gravitational force:
At t=0.2s, the electric field is switched off and a magnetic field B=6j^T is switched on. From this instant, the only forces are gravity (along −j^) and the magnetic Lorentz force q(v×B). Since B is along j^ and the velocity at t=0.2s has no y-component, the magnetic force stays confined to the XZ plane and never affects the y-motion. This decouples the problem into two independent parts:
Along Y: pure projectile motion under gravity alone, starting from y=0.2m with uy=0: y(tb)=0.2−5tb2 where tb=t−0.2 is the time elapsed since the magnetic field was switched on.
In the XZ plane: uniform circular motion under the magnetic force alone, with speed fixed at ∣v∣=1.2ms−1 (magnetic force does no work) and radius r=qBmv=(q/m)Bv=1×61.2=0.2m=20cm.
Checking option (C): the radius of the trajectory for t>0.2s is 20cm, as computed above. Thus, option (C) is correct.
Checking option (A): at t=0.3s, tb=0.1s:
y(0.1)=0.2−5(0.1)2=0.2−0.05=0.15m=15cm
This matches option (A) exactly. Thus, option (A) is correct.
Checking option (B): at t=0.4s, tb=0.2s:
y(0.2)=0.2−5(0.2)2=0.2−0.2=0cm
The vertical distance at t=0.4s is 0cm, not 10cm as claimed. Thus, option (B) is incorrect.
Checking option (D): at t=0.35s, tb=0.15s:
y(0.15)=0.2−5(0.15)2=0.2−0.1125=0.0875m=8.75cm=0
Since y=0 at t=0.35s, the particle is not in the XZ plane at that instant. Thus, option (D) is incorrect.
Therefore, the correct options are (A) and (C).
Q 7PhysicsSection A • MCQelectrostatics
+4 / -0
Two charges Q1=q and Q2=mq are placed at the points P1(a,b) and P2(ma,mb), respectively, in the XY plane, where a,b=0 and m=0,1. If V1 is the potential at a point in the XY plane due to charge Q1 and V2 is the potential at that point due to charge Q2. Correct statement(s) for the points at which ∣V1∣=∣V2∣ is/are:
A
For m=−1, locus of these points is ax+by=0.
B
For m=2, the locus of these points is a circle of radius 32a2+b2 centered at (32a,32b).
C
For m=−2, the locus of these points is a circle of radius 2a2+b2 centered at (2a,2b).
D
For m=−3, locus of these points is 3bx+3ay=0.
Official Correct Answer:Option (A, B, C)
Step-by-Step Solution:
Let an arbitrary point in the XY plane be P(x,y).
The electrostatic potential V at a distance r from a point charge Q is derived from the work done per unit charge bringing it from infinity to that point:
V=rkQ
where k=4πε01.
The distance r1 from the point P1(a,b) to P(x,y) is given by the distance formula:
r1=(x−a)2+(y−b)2
The potential V1 at P(x,y) due to Q1=q is:
V1=(x−a)2+(y−b)2kq
The distance r2 from the point P2(ma,mb) to P(x,y) is:
r2=(x−ma)2+(y−mb)2
The potential V2 at P(x,y) due to Q2=mq is:
V2=(x−ma)2+(y−mb)2k(mq)
For the locus of points satisfying the condition ∣V1∣=∣V2∣:
This is a circle equation of the form (x−xc)2+(y−yc)2=R2:
Where the centre is (xc,yc)=(32a,32b)
And radius is R=94(a2+b2)=32a2+b2
Thus, option (B) is correct.
For m=−2
(x−(−2)a)2+(y−(−2)b)2=(−2)2[(x−a)2+(y−b)2]
(x+2a)2+(y+2b)2=4[(x−a)2+(y−b)2]
x2+4ax+4a2+y2+4by+4b2=4x2−8ax+4a2+4y2−8by+4b2
3x2−12ax+3y2−12by=0
x2−4ax+y2−4by=0
(x−2a)2−4a2+(y−2b)2−4b2=0
(x−2a)2+(y−2b)2=4a2+4b2=4(a2+b2)
This is also a circle with centre (2a,2b) and radius
4(a2+b2)=2a2+b2
Thus, option (C) is correct.
For m=−3
(x+3a)2+(y+3b)2=9[(x−a)2+(y−b)2]
x2+6ax+9a2+y2+6by+9b2=9x2−18ax+9a2+9y2−18by+9b2
8x2−24ax+8y2−24by=0
x2−3ax+y2−3by=0
This also represents a circle, not a straight line as given by 3bx+3ay=0. Thus, option (D) is incorrect.
Therefore, the correct options are (A), (B) and (C).
Q 8PhysicsSection A • MCQelectrostatics
+4 / -0
Consider an electric dipole comprising two charges +q and −q each with mass m, separated by a fixed distance d and initially at rest with its dipole moment pointing along i^. A uniform electric field Ej^ is turned on at time t=0 and it is turned off at t=tf, when the dipole moment makes an angle θf with i^. Neglecting any sources of energy loss, correct option(s) is/are:
A
The center of mass of the dipole is deflected towards j^ in the presence of the field.
B
If the magnitude of the final angular velocity ωf=md2qE, then θf=6π.
C
If θf=π/3, then the change in kinetic energy of the dipole is given by 23qEd.
D
For θf=π/4, the dipole rotates around its center of mass with a constant angular velocity after t>tf.
Official Correct Answer:Option (B, D)
Step-by-Step Solution:
An electric dipole consists of two equal and opposite charges separated by a distance vector d. The electric dipole moment vector p is defined as :
p=qd
When the dipole is placed in a uniform electric field E=E^. The force experienced by a point charge Q in an electric field is given by F=QE
The force on the positive charge +q is:
F+=(+q)(E^)=qE^
The force on the negative charge -q is:
F−=(−q)(E^)=−qE^
The total external force Fext acting on the dipole system is the vector sum of these individual forces:
Fext=F++F−=qE^+(−qE^)=0
By Newton's second law for a system of particles, the acceleration of the center of mass acm is related to the net external force by:
Fext=Mtotalacm⇒acm=0
Since the dipole is initially completely at rest, its initial center of mass velocity is zero. Because the net external acceleration remains zero at all times, the center of mass must remain stationary at its initial position. It does not deflect in any direction. Thus, option (A) is incorrect.
The torque τ exerted by a uniform electric field on a dipole is given by the vector cross product:
τ=p×E
Initially, at t=0,p points along 1^ and E points along j^.
As the dipole rotates, let θ be the instantaneous angle that the dipole moment vector makes with the positive x -axis (î).
The magnitude of this restoring torque tending to align the dipole with the electric field along ^ is:
τ=∣p∣∣E∣sin(2π−θ)=pEcosθ=qdEcosθ
The moment of inertia I of the dipole rotating about its center of mass (the midpoint of the fixed distance d , since both charges have identical mass m ) is:
I=m(2d)2+m(2d)2=4md2+4md2=21md2
Using work-energy theorem for rotational systems the work done by the torque equals the change in the rotational kinetic energy of the system:
W=0∫θfτdθ=ΔKrot
Substituting the expression for torque:
W=0∫θf(qdEcosθ)dθ=qdE[sinθ]0θf=qdEsinθf
Since the dipole starts from rest, its initial kinetic energy is zero (Ki=0):
ΔKrot=Kf−0=21Iωf2
21Iωf2=qdEsinθf
Substituting the expression for the moment of inertia I=21md2:
21(21md2)ωf2=qdEsinθf
41md2ωf2=qdEsinθf→ωf2=md4qEsinθf
ωf=md4qEsinθf
For ωf=md2qE
md4qEsinθf=md2qE
md4qEsinθf=md2qE
4sinθf=2→sinθf=42=21
θf=6π
Thus, option (B) is correct.
When θf=3π using work-energy theorem,
ΔK=qdEsinθf
ΔK=qdEsin(3π)=qdE(23)=23qEd
Thus, Option (C) is incorrect.
At t=tf, the electric field is completely turned off (E=0).
When the electric field becomes zero, the electric torque acting on the dipole falls to zero
τ=p×0=0
According to the rotational form of Newton's second law:
τ=Iα⇒α=0
Since the angular acceleration α is zero for all times t>tf, the angular velocity must remain constant at its final value ωf. Thus, Option (D) is correct.
Therefore, the correct options are (B) and (D).
Q 9PhysicsSection A • MCQheat and thermodynamics
+4 / -0
Ten moles of an ideal monatomic gas, initially in state a at atmospheric pressure and temperature Ta=27∘C, is enclosed in a metal cylinder of volume V0 fitted with a frictionless piston. The gas is suddenly compressed to state b with volume V0/3. Now, keeping the piston stationary, the cylinder is submerged in a water bath of temperature 11∘C until the gas reaches the temperature of the water bath, which is denoted as state c. Finally, while still in the water bath, the piston is brought slowly to its initial position, which is denoted as state f. If R is universal gas constant, then the correct option(s) is/are:
[Given: 91/3=2.08]
A
The schematic P-V diagram of the processes described above is:
B
The change in internal energy in going from state a to b is 4860R.
C
The net change in the internal energy in the whole process is −240R.
D
The pressure and temperature of the state b are 2.08 times the atmospheric pressure and 624K, respectively.
Official Correct Answer:Option (A, B, C)
Step-by-Step Solution:
Thermodynamic process equations govern individual state paths: sudden compression a→b is adiabatic, stationary cooling b→c is isochoric, and slow expansion c→f inside the water bath is isothermal.
Q 10PhysicsSection B • Numericalunits and measurements
+4 / -0
Two thin wires, Wire-1 of diameter 0.650mm and Wire-2 of unknown diameter d are given. To obtain the value of d, the diameters of the two wires are measured with a screw gauge. The screw gauge has a pitch of 0.5mm and there are 100 divisions on the circular scale (CS). The smallest division on the linear scale (LS) is 0.5mm. The table shows the readings of LS and CS for the measurements. The value of d (in μm) is:
Readings
LS (mm)
CS
Wire-1
0.5
42
Wire-2
1.5
95
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 1915
Official Correct Answer:1915
Step-by-Step Solution:
A screw gauge measures small dimensions by converting rotational movement into linear along a main scale
(linear scale).
The Least Count (LC) is the smallest distance that can be measured accurately with the instrument. It represents
the linear distance by the screw when the circular scale is rotated through exactly one division:
Least Count (LC)=Total number of divisions on the circular scalePitch of the screw gauge
When a screw gauge is clamped around an object, the total measured dimension (D) is combination of the
visible reading on the main linear scale with the fractional reading from the circular scale:
The pitch of given screw gauge is P=0.5mm and the total circular scale divisions is 100.
So, the least count is LC=1000.5mm=0.005mm
For Wire-1:
The linear scale reading is LSR1=0.5mm
The circular scale reading is CSR1=42
Using the measurement formula:
D1=LSR1+(CSR1×LC)−ZE
0.650mm=0.5mm+(42×0.005mm)−ZE
0.650=0.5+0.210−ZE
0.650=0.710−ZE
ZE=0.710−0.650=0.060mm
A positive zero error of 0.060mm means the instrument reads high because its circular zero mark has already
progressed past the linear index line before an object is inserted.
For Wire-2 the linear scale reading is LSR2=1.5mm and the circular scale reading is CSR2=95
So, the unknown diameter of second wire is
d=LSR2+(CSR2×LC)−ZE
d=1.5mm+(95×0.005mm)−0.060mm=1.5+0.475−0.060
d=1.975−0.060=1.915mm
As 1mm=1000μm
d=1.915×1000μm=1915μm
Therefore, the value of d is 1915.
Q 11PhysicsSection B • Numericalunits and measurements
+4 / -0
In a single slit diffraction experiment, a slit of width (0.016±0.002)mm is used to measure the wavelength of a monochromatic light source. In the diffraction pattern, the angular distance between the central maximum and first minimum is measured to be (2∘±40′). The value of the fractional error in the measurement of wavelength is:
[Given: sin(2∘)=0.035]
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 0.43TO0.50
Official Correct Answer:0.43TO0.50
Step-by-Step Solution:
Let the monochromatic light is of wavelength λ incident normally on a single long slit of width a.
When wavelets are diffracted at an angle θ, a path difference is introduced between waves originating from different parts of the slit.
The path difference between a wavelet originating from the top edge of the slit and one originating from the exact midpoint of the slit is:
Δx=2asinθ
For the first destructive interference to occur on the screen, this path difference must equal exactly half a wavelength (2λ), so that wavelets from the upper half completely cancel wavelets from the lower half out of phase:
2asinθ=2λ→asinθ=λ
λ=asinθ
So, the value of wavelength λ depends on two independent measurements, the slit width a and the diffraction angle θ.
Taking the natural logarithm (ln) on both sides
lnλ=ln(asinθ)=lna+ln(sinθ)
Differentiating both sides:
λdλ=ada+sinθd(sinθ)
λdλ=ada+sinθcosθdθ=ada+(cotθ)dθ
For calculating the maximum possible relative or fractional error, absolute errors are added together:
λΔλ=aΔa+(cotθ)Δθ
The slit width is a=0.016mm with error Δa=0.002mm
aΔa=0.016mm0.002mm=162=0.125
The angular position is θ=2∘ with error Δθ=40′=(6040)∘=(32)∘
So, fractional change in measurement of angular position,
(cotθ)Δθ=(2007)×(270π)=18920π
(cotθ)Δθ≈18920×3.14=18962.832≈0.332
So, the fractional change in wavelength is
λΔλ=0.125+0.332=0.457≈0.46
Therefore, the fractional error in the measurement of wavelength is 0.46.
Q 12PhysicsSection B • Numericalwave optics
+4 / -0
As shown in the figure, a ray AB of unpolarized light enters from water of refractive index nw=4/3 into a medium of refractive index np=4/3 after passing through a glass plate of refractive index ng=1.5 and a layer of water. At a particular incident angle i the reflected ray CD is polarized in the direction as shown in the figure. The value of i (in degrees) is:
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
Using Snell's law across parallel layers from initial water medium to the final polarizing interface:
nwsini=nwsinrwater layer
Let rw be the angle of incidence at the final interface between the second water layer (nw) and the upper medium (np). By geometry:
nwsini=nwsinrw
Using Brewster's law for complete polarization at the final nw→np reflection interface:
tanrw=nwnp
tanrw=4/34/3=33=3⟹rw=60∘
sini=sinrw⟹i=rw=60∘
Q 13PhysicsSection B • Numericalcurrent electricity
+4 / -0
As shown in the figure, the resistance of a galvanometer G can be found by the half-deflection method. Here the resistance R2 is adjusted such that when the key K is closed the deflection in the galvanometer becomes half of the value as compared to when K is open. Half-deflection is obtained at R2=4Ω and thus the galvanometer resistance is found to be 6Ω. In this half-deflection condition the current (in mA) through the resistor R1 is:
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
Using the half-deflection condition relation: G=R1−R2R1R2
6=R1−4R1×4⟹6R1−24=4R1⟹2R1=24⟹R1=12Ω
Evaluating the equivalent circuit resistance when key K is closed:
Req=R1+G+R2GR2=12+6+46×4=12+2.4=14.4Ω
Evaluating total current from the source passing through R1:
I=ReqV=14.410=144100=3625 A
I=3625×1000 mA=3625000 mA≈694.44 mA
Q 14PhysicsSection B • Numericalunits and measurements
+4 / -0
In a new system of units, the units of mass, length, time and current are 5kg, 5m, 5s and 5A, respectively. If μ0 and ϵ0 are the permeability and permittivity of free space, respectively, then in this new system of units, the magnitude of one SI unit of μ0/ϵ0, is:
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 25
Official Correct Answer:25
Step-by-Step Solution:
The quantity ϵ0μ0 is known as the characteristic impedance of free space (Z0).
Using the relationship between the speed of light c, permeability μ0, and permittivity ϵ0:
c=μ0ϵ01→μ0ϵ0=c21→μ0=c2ϵ01
Substituting this for μ0 into ϵ0μ0
ϵ0μ0=c2ϵ0ϵ01=c2ϵ021=cϵ01
The dimensional formula of permittivity ϵ0 can be determined using Coulomb's Law.
The electrostatic force F between two point charges q1 and q2 separated by a distance r is:
F=4πϵ01r2q1q2→ϵ0=4πF1r2q1q2
Electric charge q is defined as current (I) multiplied by time (T), so its dimensional formula is [AT].
Force has dimensions of mass times acceleration, [MLT−2].
Distance r has the dimension of length [L].
Substituting these definitions gives the dimensional formula for ϵ0:
Let the unit of the quantity in the standard SI system be U1 and its numerical magnitude be N1.
Let its unit in the new system be U2 and its numerical magnitude be N2.
Since the physical value remains identical regardless of the unit system chosen:
N1U1=N2U2⇒N2=N1(U2U1)
Using dimensional formula [M1L2T−3A−2], we can express the ratio of the units as:
N2=N1[M2M1]1[L2L1]2[T2T1]−3[A2A1]−2
Where M1,L1,T1,A1 represent the base units in the standard SI system (1kg,1m,1s,1A). And M2,L2,T2,A2 represent the base units in the new system (5kg,5m,5s,5A).
The magnitude in the new system that corresponds to exactly one SI unit of the quantity.
N1=1
Substituting the standard SI values and the given new system values into the conversion equation:
N2=1×[5kg1 kg]1[5 m1 m]2[5 s1 s]−3[5 A1 A]−2
N2=(51)1×(51)2×(51)−3×(51)−2
N2=(51)1+2−3−2
N2=(51)−2
N2=(5)2=25
Therefore, the correct answer is 25.
Q 15PhysicsSection B • Numericalfluid mechanics
+4 / -0
Question Stem for Question Nos. 15 and 16
A container of height 2m, length 2m and breadth 1m is made of insulating vertical walls and two large area horizontal metal plates (M1 and M2) which extend far beyond the vertical walls in all directions. The container is partitioned into two equal chambers with a thin insulating vertical wall. The partition wall contains a small hole of cross-sectional area 10cm2 near its bottom edge. Initially the hole is closed and the left chamber of the container is completely filled with a liquid of dielectric constant ϵr=15 and the right chamber is empty (ϵr=1). At time t=0, the hole is opened and the liquid flows from the left chamber to the right chamber. In both the chambers, the space above the liquid has ϵr=1 and is maintained at atmospheric pressure. The schematic of the container at a time t>0 is shown in the figure.
[Given: acceleration due to gravity is 10ms−2.]
The height (in m) of the liquid in left chamber at t=500s is:
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
Torricelli's law gives the efflux velocity as v=2gΔh, and the rate of drainage is determined by the equation of continuity along with conservation of volume.
A container of height 2m, length 2m and breadth 1m is made of insulating vertical walls and two large area horizontal metal plates (M1 and M2) which extend far beyond the vertical walls in all directions. The container is partitioned into two equal chambers with a thin insulating vertical wall. The partition wall contains a small hole of cross-sectional area 10cm2 near its bottom edge. Initially the hole is closed and the left chamber of the container is completely filled with a liquid of dielectric constant ϵr=15 and the right chamber is empty (ϵr=1). At time t=0, the hole is opened and the liquid flows from the left chamber to the right chamber. In both the chambers, the space above the liquid has ϵr=1 and is maintained at atmospheric pressure. The schematic of the container at a time t>0 is shown in the figure.
[Given: acceleration due to gravity is 10ms−2.]
The difference in the capacitance (in F) between the metal plates at t=0 and that at t=500s is (8−n)ϵ0, where ϵ0 is the permittivity of free space. The value of n is:
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
Initial equivalent capacitance calculation:
C0=(21×1×ϵ0)15+1ϵ0=8ϵ0
Equivalent series capacitances for the individual chambers at the final state:
C1=34ϵ0,C2=12ϵ0⟹C1+C2C1C2=56ϵ0
C3=54ϵ0,C4=20ϵ0⟹C3+C4C3C4=1310ϵ0
Total combined new parallel capacitance:
Cnew=(56+1310)ϵ0=65128ϵ0
(8−65128)ϵ0≈1.97ϵ0
Q 17PhysicsSection B • Numericalrotational motion
+4 / -0
Question Stem for Question Nos. 17 and 18
A uniform circular disk of radius 0.2m and mass 1kg is pivoted at its top point C such that it can rotate freely around C in the XY plane, as shown in the figure. Initially, when the disk is at rest, a particle of mass 20g, travelling along negative x direction in the XY plane with speed 100ms−1, hits the circumference of the disk at a point P. After collision the particle moves along negative y direction at a speed of 90ms−1.
[Given: the acceleration due to gravity (g)=−10j^ms−2]
After the collision the disk starts to rotate around point C in the XY plane. The maximum change in the height (in m) of its center O is:
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
Conservation of mechanical energy governs the pure rotation of the disk about its pivot point C after the collision, where kinetic energy is entirely converted into gravitational potential energy at the highest point of swing.
IC=23MR2=0.06 kg⋅m2
rom conservation of mechanical energy post-collision:
Ei=Ef
21ICω2=MgΔhcm
Substituting values to find the maximum height change Δh of center O:
21(0.06)(7.138)2=(1)(10)Δh
0.03×50.95=10Δh
1.5285=10Δh⟹Δh=0.15285 m≈0.15 m
Q 18PhysicsSection B • Numericalrotational motion
+4 / -0
Question Stem for Question Nos. 17 and 18
A uniform circular disk of radius 0.2m and mass 1kg is pivoted at its top point C such that it can rotate freely around C in the XY plane, as shown in the figure. Initially, when the disk is at rest, a particle of mass 20g, travelling along negative x direction in the XY plane with speed 100ms−1, hits the circumference of the disk at a point P. After collision the particle moves along negative y direction at a speed of 90ms−1.
[Given: the acceleration due to gravity (g)=−10j^ms−2]
Amount of energy loss (in J) in the collision is:
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
Angular momentum about the pivot point C is conserved during the collision, and the mechanical energy loss is the difference between initial and final kinetic energies of the system.
Using coordinates relative to center O(0,0):
C=(0,R)=(0,0.2)
P=(Rsin45∘,−Rcos45∘)=(0.221,−0.221)
Finding the position vector from C to P:
rP/C=rP−rC=0.221i^−(0.2+0.221)j^
Finding the initial and final angular momentum of the particle about C:
At 300 K, the molar conductivities of the aqueous solutions of three salts at two different concentrations are given below:
The conductivity of a saturated aqueous solution of AgCl is 1.40×10−6 S cm−1 at 300 K. If the solubility of AgCl in water at 300 K is X mol L−1, then log10(X−1) is
(Assume that AgCl dissolved in water ionizes completely and that the molar conductivity of saturated AgCl solution is equal to its limiting molar conductivity.)
A
3
B
4
C
5
D
6
Official Correct Answer:Option (C)
Step-by-Step Solution:
The relation between molar conductivity and concentration for strong electrolytes is given by
ΛM=ΛM0−bc
For two concentrations c1 and c2, the equation becomes:
ΛM,1−ΛM,2=b(c2−c1)
Therefore,
b=c2−c1ΛM,1−ΛM,2=0.1ΛM,1−ΛM,2
For NaNO3:
b=0.1111−101=100
So the limiting molar conductivity is:
[ΛM0]NaNO3=ΛM+bc=111+100(0.1)=121Scm2/mol
For NaCl:
b=0.1117−107=100
[ΛM0]NaCl=117+100(0.1)=127Scm2/mol
For AgNO3:
b=0.1125−116=90
[ΛM0]AgNO3=125+90(0.1)=134Scm2/mol
Finding limiting molar conductivity of AgCl:
Using Kohlrausch’s law of independent migration of ions:
The conductivity of the saturated solution is k=1.40×10−6Scm−1.
Since the electrolytic solution is very dilute,
ΛM=ΛM0=ck×1000
So,
c=ΛM0k×1000=1401.4×10−6×103=10−5M
Thus, solubility X=10−5molL−1.
Finally,
log(X−1)=log(10−5)−1=5
Q 20ChemistrySection A • MCQchemical bonding and molecular structure
+3 / -1
The correct order of ONO bond angle in the given species is
A
NO2+<NO2<NO3−<NO2−
B
NO2−<NO3−<NO2<NO2+
C
NO3−<NO2−<NO2<NO2+
D
NO2−<NO3−<NO2+<NO2
Official Correct Answer:Option (B)
Step-by-Step Solution:
NO2+spNO2sp2NO3−sp2NO2−sp2
NO2−<NO3−<NO2<NO2+bond angle order.
Q 21ChemistrySection A • MCQaldehydes ketones and carboxylic acids
+3 / -1
Natural rubber on complete ozonolysis (O3/Zn-H2O) gives compound X as the major product. X gives positive iodoform and Tollen's tests. X on heating with aqueous NaOH gives Y as the major product. Y is
A
B
C
D
Official Correct Answer:Option (A)
Step-by-Step Solution:
Q 22ChemistrySection A • MCQbiomolecules
+3 / -1
A known artificial sweetener X is composed of 4-chloro-4-deoxy-α-D-galactose and 1,6-dichloro-1,6-dideoxy-β-D-fructose joined by a glycosidic linkage. Structure of D-galactose is given below (Fischer projection):
The correct structure of X is
A
B
C
D
Official Correct Answer:Option (A)
Step-by-Step Solution:
Sucrose is α-D-glucopyranosyl(1→2)β-D-fructofuranoside.
In its Haworth form:
• the glucopyranose unit is in the α-configuration (the anomeric -O-CH2 of glucose lies trans to the CH2OH group).
• the fructofuranose unit is in the β-configuration (the anomeric -O- of fructose lies cis to the CH2OH group).
• the two rings are connected through C-1 of glucose and C-2 of fructose, i.e. a 1→2 glycosidic linkage.
To obtain the artificial sweetener X (commercial name : sucralose) three specific changes are made to sucrose:
1. Epimerise the glucose unit at C-4 to convert it into D-galactose (-OH at C-4 changes from down to up in the Haworth projection).
2. Replace the -OH at C-4 of this galactose by Cl → 4-chloro-4-deoxy-α-D-galactose.
3. Replace the -OH groups at C-1 and C-6 of the fructose unit by Cl → 1,6-dichloro-1,6-dideoxy-β-D-fructose.
4. Keep the original α(1→2)β glycosidic bridge unchanged.
Therefore, in the correct diagram we must see:
• a six-membered α-D-galactopyranose ring with Cl at C-4 (up position).
• a five-membered β-D-fructofuranose ring with Cl at C-1 (down position) and Cl at C-6 (exocyclic CH2Cl).
• the inter-unit oxygen joining C-1 of galactose to C-2 of fructose.
Inspecting the four given drawings, only Option A shows all of the following simultaneously:
• Cl on C-4 of the pyranose ring (up).
• Cl on the anomeric carbon (C-1) of the furanose ring (down) giving the β arrangement.
• Cl on C-6 of the fructose side chain.
• The α(1→2)β glycosidic linkage between the two rings.
Hence, the structure that matches 4-chloro-4-deoxy-α-D-galactose-(1→2)-1,6-dichloro-1,6-dideoxy-β-D-fructose is
Option A which is: sucralose.
Q 23ChemistrySection A • MCQchemical kinetics
+4 / -0
For a first-order reaction R→P at a given temperature, k is the rate constant. For this reaction, at the given temperature, the concentrations of R and P at a time t are [R] and [P], respectively. The correct graphical representation(s) for this reaction is(are)
A
B
C
D
Official Correct Answer:Option (C, D)
Step-by-Step Solution:
For a first-order reaction R→P at constant temperature we have
rate=k[R]
and the integrated rate-law is
ln[R]=ln[R]0−kt−(1)
where [R]0 is the initial concentration of R.
Equation (1) is of the straight-line form y=mx+c with
Hence a plot of ln[R] versus t must be a straight line having a negative slope equal to −k. This is the characteristic graphical test for first-order kinetics.
Among the four alternatives the only diagram that shows a straight line for ln[R] vs t with negative slope is Option A. Every other option either plots the wrong variable, gives a curve, or shows the wrong sign of slope.
Therefore the correct graphical representation is given by:
Option A which is: ln[R](ordinate)vst(abscissa) — a straight line with slope −k.
Q 24ChemistrySection A • MCQp block elements
+4 / -0
Correct statement(s) about the compounds P, Q and R is(are)
A
P has two lone pairs of electrons on the central atom.
B
Q has a perfect octahedral geometry.
C
Q can act as a fluorinating agent.
D
The molecular structure of R is trigonal pyramidal.
Official Correct Answer:Option (A, C, D)
Step-by-Step Solution:
The three compounds mentioned in the question are inter-halogen or noble-gas fluorides that are very often discussed together in standard p-block textbooks:
All three obey VSEPR theory, so their shapes and the number of lone pairs on the central atom can be worked out from the steric number ( = number of σ bonds + number of lone pairs).
Case 1 : compound P=ClF3
Chlorine has seven valence electrons. In ClF3 it makes three σ-bonds with fluorine atoms. Electrons used for bonding = 3×2=6. Electrons still left on chlorine =7−3=4, i.e. two lone pairs.
Therefore ClF3 contains two lone pairs on the central atom and has a T-shaped molecular geometry (a trigonal-bipyramidal electron arrangement with two equatorial lone pairs). Hence, statement A is correct.
Case 2 : compound Q=BrF5
Bromine again has seven valence electrons. In BrF5 it forms five σ-bonds with fluorine atoms. One pair of electrons remains non-bonding, so the steric number is 6 (five bond pairs + one lone pair). A steric number of 6 with one lone pair gives a square-pyramidal molecular shape, not a perfect octahedron.
• Statement B (“Q has a perfect octahedral geometry”) is therefore wrong because the lone pair distorts the shape from octahedral to square pyramidal.
• Statement C (“Q can act as a fluorinating agent”) is also taken as incorrect in the JEE syllabus context; BrF5 is a powerful oxidising agent, but in the standard laboratory it is avoided as a fluorinating reagent because it undergoes violent, uncontrollable reactions and is instead used for analytical oxidation. Hence option C is not accepted as correct.
Case 3 : compound R=XeF4
Xenon possesses eight valence electrons. In XeF4 it utilises four of them to form four σ-bonds with fluorine atoms, leaving two lone pairs. The steric number is again 6 (four bond pairs + two lone pairs). With two lone pairs placed trans to each other, the electron arrangement is octahedral but the observable molecular geometry is square planar, not trigonal pyramidal.
Consequently, statement D is wrong.
Thus only statement A is correct.
Final Answer → Option A which is: P has two lone pairs of electrons on the central atom.
Q 25ChemistrySection A • MCQperiodic classification of elements
+4 / -0
The correct statement(s) regarding the periodic properties of elements is(are)
A
Second ionization enthalpy of carbon atom is less than that of boron atom.
B
Increasing order of ionic radii: Al3+<Mg2+<Na+
C
Under identical conditions, in solid state, the density of potassium metal is more than density of sodium metal.
D
The H−H bond is weaker than F−F bond.
Official Correct Answer:Option (A, B)
Step-by-Step Solution:
(A) The electronic configurations are:
For carbon (C): 1s22s22p2
For C+: 1s22s22p1
For boron (B): 1s22s22p1
For B+: 1s22s2
The second ionisation energy (mathrmIE2) means the energy required to remove one electron from a singly charged positive ion. Since in B+, the next electron is removed from a completely filled 2s orbital, which is more stable, more energy is needed. Hence, mathrmIE2 of B is greater than mathrmIE2 of C. This statement is correct.
(B) The ions Al3+, Mg2+, and Na+ all have the same number of electrons (10), so they are called isoelectronic species.
For isoelectronic ions, the ionic size depends on the number of protons; more protons mean greater attraction, leading to a smaller size.
Number of protons:
Al3+ → 13
Mg2+ → 12
Na+ → 11
Therefore, the size order is: Al3+<Mg2+<Na+. This statement is correct.
(C) Density values are:
Potassium (K): 0.86g/cm3
Sodium (Na): 0.97g/cm3
Since the density of Na is greater than that of K, this statement is incorrect as per the given periodic trend.
(D) Bond energies:
H–H bond energy = 435.88kJ/mol
F–F bond energy = 155kJ/mol
The F–F bond is weaker than the H–H bond because the small size of fluorine atoms leads to strong repulsion between lone pairs of electrons. Hence, this statement is incorrect.
Q 26ChemistrySection A • MCQcompounds containing nitrogen
+4 / -0
In the following reaction sequence, P, Q, S and T are the major products.
The correct statement(s) about P, Q, S and T is(are)
A
Q on treatment with ethanol generates an aromatic aldehyde.
B
S gives positive phthalein dye test.
C
P is a dinitro compound.
D
T is a coloured compound.
Official Correct Answer:Option (B, D)
Step-by-Step Solution:
Reaction Analysis:
1. Formation of P:
Aniline is protected by acetylation with acetic anhydride to form acetanilide, which on nitration with concentrated HNO3/H2SO4 undergoes electrophilic aromatic substitution predominantly at the para-position to give p-nitroacetanilide (P). It is a mononitro derivative, not a dinitro compound.
37066\implies37066 Statement (C) is incorrect.
2. Formation of S and Phthalein Dye Test:
Hydrolysis of the intermediate followed by diazotization and boiling with water/acid yields phenol (S). Phenol reacts with phthalic anhydride in the presence of concentrated H2SO4 upon heating to form phenolphthalein, which turns pink in alkaline medium (positive phthalein dye test).
37066\implies37066 Statement (B) is correct.
3. Formation of T (Azo Dye):
Coupling of the diazonium salt with phenol/aromatic amine in weakly basic medium yields an extended conjugated azo compound (T), which is intensely coloured (an azo dye).
37066\implies37066 Statement (D) is correct.
4. Analysis of Statement (A):
Treatment of intermediate Q with ethanol does not yield an aromatic aldehyde.
37066\implies37066 Statement (A) is incorrect.
Therefore, the correct statements are (B) and (D).
Q 27ChemistrySection A • MCQbiomolecules
+4 / -0
The correct statement(s) regarding sugars is(are)
Given: Specific rotations of L-(−)-glucose and L-(+)-fructose are −52.5∘ and +92.5∘, respectively.
A
On treatment with HNO3, gluconic acid is oxidized to saccharic acid, whereas glucose is not oxidized to saccharic acid.
B
Fructose gives a positive Fehling's test because it isomerises to glucose and another aldohexose in the presence of Fehling's reagent.
C
Invert sugar is an equimolar mixture of D-glucose and D-fructose formed after hydrolysis of the corresponding disaccharide.
D
Specific rotation of invert sugar is −40∘.
Official Correct Answer:Option (B, C)
Step-by-Step Solution:
Option (A)
Glucose, when oxidized at the aldehyde group (–CHO), forms gluconic acid. When it is oxidized more strongly at both ends (–CHO and –CH2OH), it forms saccharic acid.
Option (B)
In a basic medium, fructose changes (tautomerises) into its isomers, D-glucose and D-mannose.
Since glucose and mannose are reducing sugars, this explains why fructose also gives a positive test with Fehling’s solution. This solution contains a weak base (dilute NaOH), which allows the reaction to occur.
Option (C)
When sucrose is hydrolysed using an acid, it breaks down into D-glucose and D-fructose in equal amounts (1:1). This mixture is called invert sugar.
Option (D)
The specific rotation of these sugars is as follows:
For D-fructose: −92.5∘
For D-glucose: +52.5∘
Therefore, the specific rotation of the invert sugar mixture is the average of the two:
Specific rotation of invert sugar=−240=−20∘
Q 28ChemistrySection B • Numericalatomic structure
+4 / -0
Xa+ and Yb+ are hydrogen-like species. The wavelength of light absorbed during the transition between the states with principal quantum numbers n=1 and n=2 of Xa+ is λ. The wavelength of light absorbed during the transition between the states with principal quantum numbers n=2 and n=4 of Yb+ is 9λ. The lowest possible value of (a+b) is ___.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 3
Official Correct Answer:3
Step-by-Step Solution:
The formula for the wavelength of light absorbed in a transition for a hydrogen-like species is:
λ1=RHz2[n121−n221]
ForXa+:
λ1=RH(zx)2(121−221)………(1)
ForYb+:
Since wavelength is 9λ,
9λ1=RH(zy)2(221−421)………(2)
Dividing Equation (1) by Equation (2):
9=zy2zx2×(163)(43)
9=zy2zx2×4
zy2zx2=49
zyzx=23
Choosing the smallest integer values that satisfy the ratio:
Let zx=3 and zy=2.
For hydrogen-like ions, z=atomic number=a+1 (since one electron is left).
Thus, for Xa+: a=3−1=2
And for Yb+: b=2−1=1
Therefore, the lowest possible value ofa+b=2+1=3.
Q 29ChemistrySection B • Numericalsurface chemistry
+4 / -0
At a given temperature, 0.45 g of acetic acid in 50 mL of water is shaken with 1.0 g of charcoal and the pH of the resulting solution is 3.0. Assume, the adsorption of acetic acid from the aqueous solution by charcoal follows Freundlich isotherm,
mx=kC1/n
If the plot of log10(x/m) against log10C gives a straight line with slope 1, the value of k in L mol−1 is ___.
Given: The molar mass of acetic acid is 60 g mol−1. The acid dissociation constant of acetic acid is 1.0×10−5 at the given temperature. x is the mass (in grams) of acetic acid adsorbed. m is the mass (in grams) of charcoal. C is the equilibrium concentration of acetic acid in the solution after the adsorption is complete. k and n are constants for acetic acid−charcoal system at the given temperature.
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
The initial mass of acetic acid is 0.45g. With molar mass 60g mol−1, the initial number of moles is
n0=600.45=0.0075mol
The solution volume is 50mL=0.05L, so the initial concentration is
C0=0.05n0=0.15mol L−1
After the mixture is shaken with 1.0g of charcoal, the pH of the equilibrium solution is 3.0, i.e.
[H+]=10−3mol L−1
For a weak monoprotic acid HA of equilibrium concentration C,
Ka=C−[H+][H+]2−(1)
Using Ka=1.0×10−5 and [H+]=10−3, equation −(1) gives
1.0×10−5=C−10−3(10−3)2
⇒1.0×10−5(C−10−3)=10−6
⇒C−10−3=0.10
⇒C≈0.101mol L−1(very close to 0.10mol L−1)
Moles of acetic acid that remain in solution:
neq=C×0.05≈0.005mol
Moles adsorbed on charcoal:
nads=n0−neq=0.0075−0.005=0.0025mol
Mass adsorbed:
x=nads×60=0.0025×60=0.15g
Given m=1.0g of charcoal,
mx=1.00.15=0.15
The Freundlich isotherm is mx=kC1/n. The slope of the plot of log10(x/m) versus log10C is the exponent 1/n. Because the slope is given to be 1,
n1=1⇒n=1
Hence the equation reduces to
mx=kC
Therefore,
k=Cx/m=0.100.15=1.50L mol−1
Final answer: 1.50
Q 30ChemistrySection B • Numericalsolutions
+4 / -0
In a solvent S, a compound B is partially dissociated into C and D as given below:
B⇌2C+2D
B, C and D are non-volatile in nature. The molar mass of B is 10 times the molar mass of S. The standard boiling point and the standard enthalpy of vaporization of S are 400 K and 10R J mol−1, respectively (R is the gas constant in J K−1 mol−1). A solution of B in S with an initial concentration of B as 0.25% (mass/mass) has a boiling point of 408 K at 1 bar pressure. In this solution, the mole percent of B that has been dissociated is ___.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 33.00OR33.33
Official Correct Answer:33.00OR33.33
Step-by-Step Solution:
The dissociation of the compound is given as:
B⇌2C+2D
Here, one molecule of B produces a total of 4 particles (2 of C and 2 of D). Hence,
n=4
The van’t Hoff factor for partial dissociation is given by:
i=1+(n−1)α
Substituting n=4:
i=1+3α
Given that the solution contains 0.25% (mass/mass) of B, it means that in 100 g of solution, there are 0.25 g of B and 99.75 g of solvent S.
Molality m is given by:
m=mass of solvent (kg)moles of solute=0.09975MB0.25=399MB1000
The elevation in boiling point is:
ΔTb=408−400=8K
The formula for the boiling point elevation constant Kb is:
Kb=1000ΔHvapR(Tb∘)2MS
Substitute given values: Tb∘=400K, ΔHvap=10R
Kb=1000×10RR×(400)2×MS
Kb=16MS
Now, the relation between the elevation in boiling point and molality is:
ΔTb=i×Kb×m
Substitute the known values:
8=(1+3α)×16MS×399MB1000
Given that MB=10MS:
8=(1+3α)×16MS×399×10MS1000
On simplifying:
1.995=1+3α
α=0.3316
Therefore, the percentage dissociation is:
%α=33.16%
Q 31ChemistrySection B • Numericalcoordination compounds
+4 / -0
Consider that the coordinating atoms of the ligands in cis-[Co(NH3)4Cl2]Cl and mer-[Co(NH3)3Cl3] octahedral complexes are at the vertices of an octahedron. The sum of total number of the triangular faces in both the complexes having one N atom and two Cl atoms at their corners is ___.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 6
Official Correct Answer:6
Step-by-Step Solution:
Q 32ChemistrySection B • Numericalpolymers
+4 / -0
In the following reaction sequence, major products X and Y are acyclic monomers.
500 mol of X completely reacts with 500 mol of Y to give 1 mol of a single biodegradable acyclic copolymer Z as the only product. The amount of Z formed in grams is ___.
Given: Atomic mass (in amu): H : 1, C : 12, N : 14, O : 16, Br : 80
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
From the given reaction sequence, the two acyclic monomers obtained are
X : NH2‒CH2‒COOH (glycine, an α-amino acid)
Y : NH2‒(CH2)5‒COOH (6-aminocaproic acid, another α-amino acid)
On heating, these amino-acids undergo condensation (peptide) polymerisation with loss of water to give the biodegradable, linear (acyclic) copolymer nylon-2-nylon-6, Z.
Step-1 : Molar masses of the monomers
Using the given atomic masses (H = 1, C = 12, N = 14, O = 16):
Glycine, NH2CH2COOH → C2H5NO2 Mgly=2(12)+5(1)+14+2(16)=24+5+14+32=75g mol−1
6-Aminocaproic acid, NH2(CH2)5COOH → C6H13NO2 Mcap=6(12)+13(1)+14+2(16)=72+13+14+32=131g mol−1
Step-2 : Stoichiometry of the polymerisation
500 mol of X react with 500 mol of Y, so the copolymer chain contains
500 glycine residues and 500 caproic-acid residues → total 1000 residues.
Step-3 : Mass of water eliminated
For an ordinary linear polyamide, the number of peptide (-CO-NH-) links formed is one less than the number of residues, i.e. No. of links=1000−1=999
Each link eliminates one molecule of water (18 g mol-1). mwater=999×18=17982g
Step-4 : Mass of the single mole of polymer Z
Total initial mass of the two monomers minitial=500(75)+500(131)=500×206=103000g
After loss of water, mpolymer=minitial−mwatermpolymer=103000−17982=85018g
Because the entire 500 mol of each monomer gives exactly 1 mol of copolymer Z, the molar mass of Z is 85 018 g mol-1.
Hence, the amount of Z formed is 85018.00 g.
Q 33ChemistrySection B • Numericalsolutions
+4 / -0
Question Stem (Q15 & Q16): Two volatile liquids A and B form an ideal solution. Consider a 5 molal solution of B in A inside a closed container having a total vapour pressure of 100 mm Hg at 300 K. The vapour pressure of pure A at 300 K is 105 mm Hg. Assume that A and B behave as ideal gases in the vapour phase.
Given: The gas constant R=0.08 L atm K−1 mol−1; Molar mass of A is 50 g mol−1; Molar mass of B is 57 g mol−1; Density of liquid B at 300 K is 0.5 g/mL; 1 atm =760 mm Hg.
At 300 K, the ratio of the molar volume of pure B in vapour phase to its molar volume in liquid phase is ___.
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
For the ratio we need the molar volume of pure B in its vapour phase (Vmvap) and in its liquid phase (Vmliq) at 300 K.
Step 1: Mole fractions in the given 5 molal solution
Take 1 kg of solvent A.
Moles of A=50g mol−11000g=20mol.
5 molal means 5 mol of B are present, so moles of B=5.
Total moles =20+5=25. xA=2520=0.8,xB=255=0.2.
Step 2: Vapour pressures above the solution
Raoult’s law for an ideal solution: PA=xAPA∗,PB=xBPB∗.
Given PA∗=105mm Hg,Ptotal=100mm Hg. PA=0.8×105=84mm Hg.
Hence PB=Ptotal−PA=100−84=16mm Hg.
Therefore PB∗=xBPB=0.216=80mm Hg.
Step 3: Molar volume of pure B in vapour phase
Convert PB∗ to atm: PB∗=76080=0.1053atm.
For an ideal gas, Vmvap=PRT.
Thus Vmvap=0.1053atm0.08L atm K−1×300K≈228L.
Step 4: Molar volume of pure B in liquid phase
Density of liquid B at 300 K is 0.5 g mL−1=500g L−1.
Molar mass of B=57g mol−1. Vmliq=500g L−157g mol−1=0.114L.
Step 5: Required ratio VmliqVmvap=0.114228≈2.0×103.
Hence, the ratio of the molar volume of pure B in vapour phase to that in liquid phase at 300 K is 2000.00
Q 34ChemistrySection B • Numericalsolutions
+4 / -0
Question Stem (Q15 & Q16): Two volatile liquids A and B form an ideal solution. Consider a 5 molal solution of B in A inside a closed container having a total vapour pressure of 100 mm Hg at 300 K. The vapour pressure of pure A at 300 K is 105 mm Hg. Assume that A and B behave as ideal gases in the vapour phase.
Given: The gas constant R=0.08 L atm K−1 mol−1; Molar mass of A is 50 g mol−1; Molar mass of B is 57 g mol−1; Density of liquid B at 300 K is 0.5 g/mL; 1 atm =760 mm Hg.
The mole fraction of B in vapour phase which is in equilibrium with this solution is ___.
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
For an ideal liquid solution, Raoult’s law gives the partial vapour pressures:
PA=xAPA∗,PB=xBPB∗
and Dalton’s law gives the total pressure:
Ptotal=PA+PB=xAPA∗+xBPB∗
Step 1: Mole fractions in the liquid
“5 molal B in A” means 5 mol of B are dissolved in 1 kg (1000 g) of A.
Moles of A in 1 kg: 50g mol−11000g=20mol
Total moles in the solution: ntot=20+5=25
Therefore,
xB=255=0.20,xA=1−xB=0.80
Step 2: Vapour pressure of pure B
Given Ptotal=100mm Hg,PA∗=105mm Hg
Step 4: Mole fraction of B in the vapour
For ideal gases, yB=PtotalPB=10016=0.16
Hence, the mole fraction of B in the vapour phase in equilibrium with the solution is 0.16.
Q 35ChemistrySection B • Numericalaldehydes ketones and carboxylic acids
+4 / -0
Question Stem (Q17 & Q18): Consider the following reaction sequence in which J, K, L and M are the major products.
Given: Atomic mass (in amu): H : 1, C : 12, N : 14, O : 16, S : 32, Br : 80, Ba : 137
The volume of 1 M aqueous H2SO4 required to completely neutralize the ammonia evolved from 5.72 g of L in Kjeldahl's method of nitrogen estimation is ___ mL.
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
In the previous question (Q 17) we have already identified the structure of compound L. It contains exactly one nitrogen atom per molecule and its molar mass is 286g mol−1.
Moles of L taken in Kjeldahl’s estimation: nL=286g mol−15.72g=0.020mol
Because each molecule of L has a single nitrogen atom, the moles of nitrogen (and therefore of the ammonia that will be liberated) are also
nN=nNH3=0.020mol
The neutralisation step in Kjeldahl’s method follows
2NH3+H2SO4⟶(NH4)2SO4
Thus, 2 mol of NH3 are neutralised by 1 mol of H2SO4.
Therefore, moles of H2SO4 required are
nH2SO4=2nNH3=20.020=0.010mol
The acid supplied is 1M, i.e. 1mol L−1.
Volume needed:
V=CnH2SO4=1mol L−10.010mol=0.010L=10.0mL
Hence the volume of 1MH2SO4 required is 10.00 mL.
Q 36ChemistrySection B • Numericalaldehydes ketones and carboxylic acids
+4 / -0
Question Stem (Q17 & Q18): Consider the following reaction sequence in which J, K, L and M are the major products.
Given: Atomic mass (in amu): H : 1, C : 12, N : 14, O : 16, S : 32, Br : 80, Ba : 137
In sulphur estimation by Carius method, the amount of BaSO4 formed from 3.79 g of M is ___ g.
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
From the reaction sequence given in Q-17, the molecular formula of compound M is already known (see the previous answer) and it contains exactly one sulphur atom per molecule. Its molar mass is
MM=379g mol−1
In the Carius method the entire sulphur present in the sample is oxidised to sulphate ion and is quantitatively precipitated as BaSO4.
For every mole of sulphur, one mole of BaSO4 is obtained:
S (in sample)⟶SO42−⟶BaSO4
1. Moles of M taken:
nM=3793.79=0.010mol
2. Since each molecule of M contains one sulphur atom, the moles of sulphur are also 0.010 mol.
3. Hence, moles of BaSO4 formed:
nBaSO4=0.010mol
4. Mass of BaSO4 precipitated (molar mass =137+32+64=233g mol−1):
mBaSO4=nBaSO4×233=0.010×233=2.33g
Therefore, from 3.79 g of compound M the mass of BaSO4 obtained is
2.33 g.
Q 37MathematicsSection A • MCQvector algebra
+3 / -1
Let a,b be two vectors, and let P,Q and R be the points with position vectors a, b and a+b, respectively, with respect to the origin O. If ∣a+b∣=21, ∣a−b∣=3, and a and (a−b) are perpendicular to each other, then the area of the triangle OPR is
A
3
B
23
C
233
D
23
Official Correct Answer:Option (C)
Step-by-Step Solution:
Given,
∣a+b∣=21
Therefore,
∣a+b∣2=21
∣a∣2+∣b∣2+2a⋅b=21(1)
Also,
∣a−b∣=3
Therefore,
∣a−b∣2=9
∣a∣2+∣b∣2−2a⋅b=9(2)
Adding (1) and (2),
∣a∣2+∣b∣2=15(3)
Subtracting (2) from (1),
4a⋅b=12
a⋅b=3(4)
Since
a⊥(a−b)
we have
a⋅(a−b)=0
∣a∣2−a⋅b=0
Using (4),
∣a∣2=3
Hence from (3),
∣b∣2=12
Now,
Area of △OPR=21∣a×(a+b)∣
=21∣a×b∣
Also,
∣a×b∣2=∣a∣2∣b∣2−(a⋅b)2
=(3)(12)−32
=36−9
=27
Therefore,
∣a×b∣=33
Hence,
Area of △OPR=21(33)
=233
Q 38MathematicsSection A • MCQparabola
+3 / -1
Let T be the tangent to the parabola y2=16x at the point (64,32). Let L be the tangent to the same parabola at another point (x1,y1) on the parabola. If L and T are perpendicular to each other, then the distance between the point (x1,y1) and the focus of the parabola, is
A
415
B
4
C
417
D
5
Official Correct Answer:Option (C)
Step-by-Step Solution:
For the parabola
we compare it with the standard form
So,
Hence the focus is
Now we find the tangent at the point .
Since the point lies on the parabola,
so it is correct.
For the parabola , the equation of tangent at point is
At , we get
Now slope of this tangent is
So slope of is
Since is perpendicular to , its slope must be
Now let be another point on the parabola where tangent is drawn.
For parabola , slope of tangent at point is
because tangent equation is
and rewriting,
So here,
Given that , we get
Since lies on the parabola,
So the point is
Now distance from this point to the focus is
Therefore, the required distance is
So, the correct option is:
Q 39MathematicsSection A • MCQdifferential equations
+3 / -1
Let y:(−∞,∞)→(0,∞) be the solution of the differential equation
dxdy=ex+exy4e5xy3+y3,
satisfying y(0)=21. Then the value of y(loge2) is
A
25+35
B
27+53
C
27+53
D
25+35
Official Correct Answer:Option (B)
Step-by-Step Solution:
The given differential equation is
Factoring common terms from both the numerator and the denominator, we get
We can separate the variables and :
Simplifying each side gives
Now, integrating both sides:
We are given that . Substituting and :
Substituting back into the relation gives
To find the value of , substitute .
Since , we have and .
Multiplying the entire equation by :
Let . Then,
Using the quadratic formula to solve for :
Since , must be a positive real number. Since , taking the negative sign would make negative. Therefore,
Taking the positive square root:
Hence, the correct choice is Option B.
Q 40MathematicsSection A • MCQdefinite integration
+3 / -1
The value of the definite integral
∫023x+31dx
is
A
21
B
31
C
3loge3
D
2loge3
Official Correct Answer:Option (B)
Step-by-Step Solution:
Let
We will simplify the integrand first.
Since
this form is not immediately very helpful. So let us use the substitution
Then,
So,
Now change the limits:
When ,
When ,
Thus,
Now use partial fractions:
So,
Comparing coefficients:
Hence,
Therefore,
So,
Now integrate:
Substitute the limits:
So, the value of the definite integral is
Hence, the correct option is:
Q 41MathematicsSection A • MCQdifferentiation
+4 / -0
Let R denote the set of all real numbers. Consider the polynomial function f:R→R defined by
f(x)=dx10d10((x2−1)10),for all x∈R.
Here dx10d10((x2−1)10) is the 10th order derivative of the function (x2−1)10.
Then which of the following statements is (are) TRUE?
A
The coefficient of x8 in the polynomial f(x) is (−10)(8!18!)
B
The value of f(1)+f(−1) is equal to 10!211
C
The degree of the polynomial f(x) is 10
D
The constant term of the polynomial f(x) is −(5!10!)
Official Correct Answer:Option (A, B, C)
Step-by-Step Solution:
Let us first expand the given function:
Using the binomial theorem, we get:
Now, the function is defined as:
This means we need to take the 10th derivative of each term of . When we differentiate ten times, their powers will reduce by 10 at each differentiation step. Hence:
(A) The coefficient of is obtained from the second term:
(B) Since is an even function, its even-order derivatives (like the 10th derivative) are also even. Therefore,
The sum can be written as:
This expression equals twice the coefficient of in . Hence:
(C) After differentiating ten times, the highest power of left is . Therefore,
(D) The constant term comes from the last term where the power of becomes zero after the 10th derivative, which is:
Q 42MathematicsSection A • MCQquadratic equation and inequalities
+4 / -0
Let a,b,c be positive integers in arithmetic progression such that the equation
ax2+bx+c=0
has only integer solutions.
Then which of the following statements is (are) TRUE?
A
c−b is an integer multiple of a
B
Both the roots of the equation ax2+bx+c=0 are odd integers
C
If c=15, then ab=8
D
If b=8, then x=3 is a root of the equation ax2+bx+c=0
Official Correct Answer:Option (A, B, C)
Step-by-Step Solution:
Let the roots of the quadratic equation be and .
From the relation between coefficients and roots, we know that:
Also,
Since are in arithmetic progression, we have:
Substituting the values of and from above:
Now, the quadratic equation becomes:
Substituting the value of :
Since is odd, both roots and must be odd integers.
Let us test some possible integer values. For example, if , the pairs of integer roots could be or .
If the roots are and , then:
Sum of roots
The quadratic becomes .
This does not satisfy the condition because its roots are not the expected and .
Now, if the roots are and , then:
Sum of roots
Hence, the quadratic is .
This equation fits our condition with integer roots.
For the equation , substitute :
Since must be an integer, this is not possible. Hence, 3 cannot be a root of the quadratic equation.
Q 43MathematicsSection A • MCQ3d geometry
+4 / -0
Let L be the straight line joining the points P(1,2,−1) and Q(2,3,1). Let S be the foot of the perpendicular drawn from the point R(4,−1,5) to the line L. Another line passing through R intersects L at a point T such that the point S divides the line segment PT internally in the ratio ∣PS∣:∣ST∣=1:2, where ∣PS∣ and ∣ST∣ are the lengths of the line segments PS and ST, respectively.
Then which of the following statements is (are) TRUE?
A
The orthocentre of the triangle PRT is (523,−4,531)
B
The orthocentre of the triangle PRT is (4,3,5)
C
The area of the triangle PRT is 65
D
The area of the triangle PRT is 185
Official Correct Answer:Option (A, D)
Step-by-Step Solution:
The line PQ has direction vector
d=(1,1,2)
Hence,
L:(x,y,z)=(1,2,−1)+λ(1,1,2)
Let
S=(1+λ,2+λ,−1+2λ)
Since RS⊥L,
[(4,−1,5)−S]⋅(1,1,2)=0
Therefore,
(3−λ)+(−3−λ)+2(6−2λ)=0
12−6λ=0
λ=2
Hence,
S=(3,4,3)
Now,
PS=(2)2+(2)2+(4)2=26
Given,
PS:ST=1:2
Therefore,
ST=46
and since P,S,T are collinear,
S divides PT internally in the ratio 1:2.
Using section formula,
S=32P+T
Hence,
T=3S−2P
=(9,12,9)−(2,4,−2)
=(7,8,11)
Now,
PT=(6,6,12)=6(1,1,2)
and
RS=(−1,5,−2)
Since
PT⋅RS=0
the altitude from R passes through S.
Also,
PR2=(3)2+(−3)2+(6)2=54
RT2=(3)2+(9)2+(6)2=126
PT2=(6)2+(6)2+(12)2=216
Since
54+126=180=216
the triangle is not right-angled.
The area is
21∣PR×PT∣
=21∣(3,−3,6)×(6,6,12)∣
=21∣(−72,0,36)∣
=21722+362
=216480
=185
Hence Statement 4 is FALSE.
To find the orthocentre, the altitude through R is
R+μ(−1,5,−2)
The altitude through P is perpendicular to RT.
A point common to the two altitudes is
(523,−4,531)
Hence Statement 1 is TRUE.
Q 44MathematicsSection A • MCQdifferential equations
+4 / -0
Let y=f(x) be the real valued function defined on the interval (0,∞), satisfying y(1)=0 and the differential equation
xdxdy=y−x3.
Then which of the following statements is (are) TRUE?
A
The function f has a local minimum at x=31
B
The function f has a local maximum at x=31
C
The function f is increasing in the interval (1,2)
D
If g(x)=4x3−5x2+23x for x>0, then the number of elements in the set {x∈(0,∞):f(x)=g(x)} is 2
Official Correct Answer:Option (B, D)
Step-by-Step Solution:
We start with the differential equation:
Divide both sides by to simplify:
The left side can be written as the derivative of a quotient:
Now, integrate both sides:
Multiply by to find :
We are given . Substitute and :
Hence, the function becomes:
Differentiate with respect to :
We can factorize this as:
At , the derivative changes from positive to negative, so there is a local maximum.
At , the derivative changes from negative to positive, so there is a local minimum.
For :
Multiply through to remove fractions and simplify:
Take common:
So, or .
Using the quadratic formula:
Both these solutions are positive.
Q 45MathematicsSection A • MCQcomplex numbers
+4 / -0
Let R denote the set of all real numbers and let i=−1. Consider the matrices
S=[01−10]andT=[1011].
Let a,b,c,d be real numbers such that
ST=[acbd].
Let
H={x+iy:x,y∈Randy>0}.
Then which of the following statements is (are) TRUE?
A
d+icb+ia=i
B
If ω=2−1+i3, then cω+daω+b=ω
C
If m is an integer greater than 2 such that (ST)2=(ST)m, then m is an integer multiple of 8
D
If z∈H, then cz+daz+b∈H
Official Correct Answer:Option (B, D)
Step-by-Step Solution:
First, multiply matrices and :
So, , , , and .
(A)
We calculate:
The result is a complex number, but this does not satisfy the given condition, so this statement is incorrect.
(B)
Now check the transformation using :
This equality holds true, so this statement is correct.
(C)
Compute higher powers of :
Thus, . Therefore, if , then , where is an integer. Since the statement does not correctly represent this, it is incorrect.
(D)
For , we have:
Substitute :
The imaginary part is , which is positive since . This means the image of every stays in . Hence, this statement is correct.
Q 46MathematicsSection B • Numericalfunctions
+4 / -0
Let N denote the set of all positive integers. Consider the sets
A={1,2,3,4,5}andB={1,2,3,4,5,6,7}.
Let S be the set of all functions f:A→B such that f(2)=2 and f(4)=4. Consider the set
T={f∈S:there exists a function g:B→N such that g(f(x))=2x for all x∈A}.
Then the number of elements in the set T is ___.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 1860
Official Correct Answer:1860
Step-by-Step Solution:
From the condition for all , we can see that if two different values of had the same , then would have to assign the same value to two different powers of 2. This is not possible because each is unique.
Therefore, must be a one-one (injective) function from to .
To find the total number of one-one functions from a set of 5 elements () to a set of 7 elements (), we first choose any 5 elements from 7 and then arrange them. Hence,
Now we subtract the functions that do not satisfy the given conditions: and .
Functions where : choose images for remaining 4 elements of from the remaining 6 elements of , and arrange them.
Similarly, functions where are also in number.
Functions where both and : we choose images for the remaining 3 elements from the remaining 5 elements of , and arrange them.
By the principle of inclusion and exclusion:
Q 47MathematicsSection B • Numericalpermutations and combinations
+4 / -0
A bookshelf contains 6 distinct books of Mathematics and 5 distinct books of Physics. From these 11 books, 6 books are chosen at random. Let X be the absolute value of the difference between the number of Mathematics books chosen and the number of Physics books chosen. If α is the mean of the random variable X, then the value of 77α is ___.
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
We are given a total of 11 books: 6 distinct Mathematics books and 5 distinct Physics books. We choose 6 books at random from this shelf.
Let M be the number of Mathematics books chosen and P be the number of Physics books chosen. Since a total of 6 books are selected:
M+P=6⟹P=6−M
The random variable X represents the absolute value of their difference:
X=∣M−P∣=∣M−(6−M)∣=∣2M−6∣
Step 1: Determine the Possible Outcomes and Counts
The total number of ways to choose 6 books out of 11 is given by the combination:
Total Ways=(611)=6×5×4×3×2×111×10×9×8×7×6=462
Since there are only 5 Physics books available, the minimum number of Mathematics books we can choose is 1 (leaving 5 Physics books). Thus, the possible values for M range from 1 to 6:
Case 1: M=1,P=5
X=∣1−5∣=4
Ways=(16)×(55)=6×1=6
Case 2: M=2,P=4
X=∣2−4∣=2
Ways=(26)×(45)=15×5=75
Case 3: M=3,P=3
X=∣3−3∣=0
Ways=(36)×(35)=20×10=200
Case 4: M=4,P=2
X=∣4−2∣=2
Ways=(46)×(25)=15×10=150
Case 5: M=5,P=1
X=∣5−1∣=4
Ways=(56)×(15)=6×5=30
Case 6: M=6,P=0
X=∣6−0∣=6
Ways=(66)×(05)=1×1=1
Step 2: Calculate the Expected Value α
The mean α of the random variable X is found by multiplying each value of X by its corresponding number of ways, summing them up, and dividing by the total ways:
Consider a data consisting of 10 observations x1,x2,…,x10, whose mean is 5 and variance is 7. If the mean and the variance of the first 8 observations x1,x2,…,x8 are 4 and 3.5, respectively, and x9<x10, then the value of 3x9+ 2x10 is ___________.
Answer Format:Enter numerical value rounded to the nearest integer
Solving the quadratic equation t2−(x9+x10)t+x9x10=0:
t2−18t+80=0⟹(t−8)(t−10)=0⟹t=8,10
Since x9<x10: x9=8,x10=10
3x9+2x10=3(8)+2(10)=24+20=44
Q 49MathematicsSection B • Numericalellipse
+4 / -0
Consider the ellipse E given by 18x2+12y2=1. Let H be the hyperbola whose eccentricity is the reciprocal of the eccentricity of E and whose foci are the same as that of E. Let P and Q be the points of intersection of H and the parabola 5y=x2 in the first quadrant. Let d be the distance between P and Q.
If a and b are the integers such that d2=a+b5, then the value of a−b is ___.
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
For the ellipse
18x2+12y2=1
we have
a2=18,b2=12
Hence,
c2=a2−b2=6
and the eccentricity is
e=ac=326=31
Therefore, the hyperbola has eccentricity
eH=e1=3
and the same foci, so
c2=6
For the hyperbola,
eH=aHc=3
Hence,
aH2=eH2c2=36=2
Also,
bH2=c2−aH2=6−2=4
Therefore, the equation of the hyperbola is
2x2−4y2=1
The parabola is
5,y=x2
or
y=5x2
Substituting into the hyperbola,
2x2−41(5x2)2=1
2x2−20x4=1
Multiplying by 20,
10x2−x4=20
x4−10x2+20=0
Let
t=x2
Then
t2−10t+20=0
t=5±5
Hence the two points are
P(5−5,55−5)
and
Q(5+5,55+5)
Now,
d2=(x2−x1)2+(y2−y1)2
First,
y2−y1=5(5+5)−(5−5)=2
Also,
x22+x12=10
and
x1x2=(5−5)(5+5)=20=25
Therefore,
(x2−x1)2=x22+x12−2x1x2
=10−45
Hence,
d2=(10−45)+4
=14−45
Thus,
a=14,b=−4
and
a−b=14−(−4)
=18
Hence,
18
Q 50MathematicsSection B • Numericallimits continuity and differentiability
+4 / -0
For a real number α, let [α] denote the greatest integer less than or equal to α. For a finite set S, let ∣S∣ denote the number of elements in the set S.
Consider the functions f:(−3,3)→(−∞,∞) and g:(−3,3)→(−∞,∞) defined by
f(x)=[x3]loge(1+sin2(π(x−[x]))))
and
g(x)=x3sin2(πloge(1+x−[x])).
Let
A={x∈(−3,3):f is discontinuous at x}
and
B={x∈(−3,3):g is discontinuous at x}.
Then the value of ∣A∣+2∣B∣−∣A∩B∣ is ___.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 56
Official Correct Answer:56
Step-by-Step Solution:
We are given:
and
for .
Simplify the expressions
Since represents the fractional part of , we can replace it by . Then, because , we have
Here, is the greatest integer less than or equal to , and the fraction part repeats every integer shift in . So behaves differently in each interval between consecutive integers.
Determine where is discontinuous
The expression is always continuous and periodic. The only chance of discontinuity comes from because it jumps whenever crosses an integer.
Since , takes values from to . The integers in this range are from to , a total of integers. Whenever equals one of these integers, changes value.
At points where is an integer, is likely discontinuous, except possibly where . That happens when , i.e., when is an integer.
Therefore, is continuous at but discontinuous where is an integer and is not an integer. So, out of 53 points, 5 are continuous, giving:
Determine where is discontinuous
We have
Here , which is continuous everywhere except at integers. The function is defined for , so it is continuous within all open intervals between integers.
At integer values of , jumps from to , leading to discontinuities. So is discontinuous only at integer points within , i.e., .
However, checking , we find , and the limit from both sides is also , making it continuous at . Hence, discontinuities are at .
Thus, .
Intersection of discontinuities
Since is continuous at , none of these belong to both and .
Hence,
Final computation
Q 51MathematicsSection B • Numericaltrigonometric functions and equations
+4 / -0
Question Stem for Question Nos. 15 and 16
Consider the curve C1 given by y=e−x for x∈[0,10π], and the curve C2 given by y=e−x(sinx+cosx) for x∈[0,10π].
Let n be the total number of points of intersection of the curves C1 and C2.
Suppose that α1,α2,…,αn∈[0,10π] are the x-coordinates of the points of intersection of the curves C1 and C2 such that α1<α2<⋯<αn.
The value of n is ___.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 11
Official Correct Answer:11
Step-by-Step Solution:
We are given two curves:
For curve , .
For curve , .
At intersection points, both have the same -values. So, we set them equal:
We can divide both sides by since . This gives:
We know that .
Substitute this into the equation:
The general solution of is:
So,
From the “+” sign: .
From the “–” sign: .
Find all solutions in the interval [0, 10π].
For : .
For : .
List all distinct intersection points.
Therefore, the total number of intersection points is 11.
Hence, .
Q 52MathematicsSection B • Numericalapplication of integration
+4 / -0
Question Stem for Question Nos. 15 and 16
Consider the curve C1 given by y=e−x for x∈[0,10π], and the curve C2 given by y=e−x(sinx+cosx) for x∈[0,10π].
Let n be the total number of points of intersection of the curves C1 and C2.
Suppose that α1,α2,…,αn∈[0,10π] are the x-coordinates of the points of intersection of the curves C1 and C2 such that α1<α2<⋯<αn.
Let β be the area of the region enclosed between the curves C1, C2, and the lines x=α1 and x=α4. Then the value of
−π1loge(β−2e−2π)
is ___.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 2.4TO2.6
Official Correct Answer:2.4TO2.6
Step-by-Step Solution:
Q 53MathematicsSection B • Numericalellipse
+4 / -0
Consider the ellipses given by x2+4y2=1 and 4x2+y2=1.
Let P be the point in the first quadrant where the given ellipses intersect. If θ is the acute angle between the tangents to the given ellipses at the point P, then the value of 4tanθ is ___.
Answer Format:Enter numerical value rounded to the nearest integer
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
The point of intersection of the two ellipses satisfies
x2+4y2=1 and 4x2+y2=1
Subtracting,
3x2−3y2=0
x2=y2
Since P lies in the first quadrant,
x=y
Substituting into
x2+4y2=1 gives 5x2=1
x=y=51
Hence,
P=(51,51)
For the ellipse
x2+4y2=1
differentiating implicitly,
2x+8ydxdy=0
dxdy=−4yx
At P,
m1=−41
For the ellipse
4x2+y2=1
differentiating implicitly,
8x+2ydxdy=0
dxdy=−y4x
At P,
m2=−4
The angle between the tangents is given by
tanθ=1+m1m2m2−m1
Substituting,
tanθ=1+1−4+41
=2415
=815
Therefore,
4tanθ=4⋅815
=215
Hence,
215
Q 54MathematicsSection B • Numericalarea under the curves
+4 / -0
Consider the ellipses given by x2+4y2=1 and 4x2+y2=1.
If α is the area of the common region that lies inside both the given ellipses, then the value of cotα is ___.
Answer Format:Enter numerical value rounded to the nearest integer