Official NTA Question PaperFull Solved Paper2023Paper 1
JEE Advanced 2023 Paper 1 Question Paper with Solutions
Official solved question paper for Joint Entrance Examination (Advanced). Review all 51 questions, official answer keys, and detailed step-by-step solutions below, or attempt online with timer and negative marking.
A bar of mass M=1.00kg and length L=0.20m is lying on a horizontal frictionless surface. One end of the bar is pivoted at a point about which it is free to rotate. A small mass m=0.10kg is moving on the same horizontal surface with 5.00ms−1 speed on a path perpendicular to the bar. It hits the bar at a distance L/2 from the pivoted end and returns back on the same path with speed v. After this elastic collision, the bar rotates with an angular velocity ω.
Which of the following statement is correct?
A
ω=6.98rads−1 and v=4.30ms−1
B
ω=3.75rads−1 and v=4.30ms−1
C
ω=3.75rads−1 and v=10.0ms−1
D
ω=6.80rads−1 and v=4.10ms−1
Official Correct Answer:Option (A)
Step-by-Step Solution:
A bar, having a mass of M=1 kg and a length of L=0.2 m, is hinged at a point P. A particle with a mass of m=0.1 kg moves in a direction perpendicular to the bar at a velocity of u=5 m/s. This particle collides elastically with the bar at a point that is 2L (0.1 m) away from the pivot point P. As a result of this collision, the bar begins to rotate with an angular velocity ω, and the particle recoils with a new velocity v.
We can analyze the bar and the particle as a combined system. Initially, before the impact occurs, the system's angular momentum around the pivot point P is in a clockwise direction. The magnitude of this initial angular momentum can be expressed as
Li=mu(2L)
Following the collision, the angular momentum of the system about the pivot point P changes. This final angular momentum can be represented as
Lf=Ibarω−mv(2L)
Here, Ibar, the moment of inertia of the bar, is given by 31ML2, and the term −21mvL accounts for the particle's contribution post-collision.
During the collision, the angular momentum of the system around the pivot point P is conserved. This means Li=Lf. Applying this principle, we derive the following relationship :
2MLω=3m(u+v) ..........(i)
This equation represents the conservation of angular momentum in the system, correlating the initial and final states of the bar and the particle.
The kinetic energy of the system is conserved in an elastic collision. The kinetic energy of the system before the collision is
Ki=21mu2.
In an elastic collision, the total kinetic energy of the system is preserved. Prior to the collision, the kinetic energy of the system can be quantified as
Ki=21mu2
This equation denotes the initial kinetic energy, primarily attributed to the particle's motion.
After the collision takes place, the kinetic energy of the system can be expressed as :
Kf=21mv2+21Irotω2=21mv2+21×31ML2ω2
Here, the first term represents the kinetic energy due to the particle's velocity post-collision, and the second term represents the rotational kinetic energy of the bar.
By applying the principle of conservation of kinetic energy, which states Ki=Kf, we obtain the following relation :
ML2ω2=3m(u2−v2) ............(ii)
This equation links the initial and final kinetic energies of the system, comprising the particle and the rotating bar.
By resolving equations (i) and (ii), we determine that the velocity v of the particle post-collision is 4.3 m/s and the angular velocity ω of the bar is 6.98 rad/s.
Q 2PhysicsSection A • MCQatoms and nuclei
+3 / -1
List-I shows different radioactive decay processes and List-II provides possible emitted particles. Match each entry in List-I with an appropriate entry from List-II, and choose the correct option.
List - I
List - II
(P) 92238U→91234Pa
(1) one α particle and one β+particle
(Q) 82214Pb→82210Pb
(2) three β−particles and one α particle
(R) 81210Tl→82206Pb
(3) two β−particles and one α particle
(S) 91228Pa→88224Ra
(4) one α particle and one β−particle
(5) one α particle and two β+particles
A
P→4,Q→3,R→2,S→1
B
P→4,Q→1,R→2,S→5
C
P→5,Q→3,R→1,S→4
D
P→5,Q→1,R→3,S→2
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: $P \rightarrow 4, Q \rightarrow 3, R \rightarrow 2, S \rightarrow 1$
(S) 91Pa228→88Ra224N1=4228−224=1→1αN2−N3=(91−88)−24=1β+
Q 3PhysicsSection A • MCQalternating current
+3 / -1
A series LCR circuit is connected to a 45sin(ωt) Volt source. The resonant angular frequency of the circuit is 105rads−1 and current amplitude at resonance is I0. When the angular frequency of the source is ω=8×104rads−1, the current amplitude in the circuit is 0.05I0. If L=50mH, match each entry in List-I with an appropriate value from List-II and choose the correct option.
List - I
List - II
(P) I0 in mA
(1) 44.4
(Q) The quality factor of the circuit
(2) 18
(R) The bandwidth of the circuit in rads−1
(3) 400
(S) The peak power dissipated at resonance in Watt
A plane polarized blue light ray is incident on a prism such that there is no reflection from the surface of the prism. The angle of deviation of the emergent ray is δ=60∘ (see Figure-1). The angle of minimum deviation for red light from the same prism is δmin=30∘ (see Figure-2). The refractive index of the prism material for blue light is 3. Which of the following statement(s) is(are) correct?
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
When light strikes a surface at Brewster's angle, it becomes polarized perpendicular to the plane of incidence.
Therefore, there is no reflection of blue light observed.
This implies that the light must be polarized within the plane of incidence.
Q 5PhysicsSection B • Numericalunits and measurements
+4 / -0
In an experiment for determination of the focal length of a thin convex lens, the distance of the object from the lens is 10±0.1cm and the distance of its real image from the lens is 20±0.2cm. The error in the determination of focal length of the lens is n%. The value of n is ______.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 1
Next, we need to calculate the error in the determination of the focal length. For that, we find the differential of the lens formula :
Then, the derivative of the equation gives us the change in the focal length (df) in terms of the changes in the object distance (du) and the image distance (dv):
−v21dv+u21du=f2−1df
For maximum error, we get :
f21df=v21dv+u21du
This equation tells us how errors in (u) and v propagate to an error in f. Now, when you compute the relative error in the focal length, you get :
fdf×100=(v21dv+u21du)×1f×100
Plugging in your values of u=10cm, du=0.1cm, v=20cm, dv=0.2cm, and f=20/3cm, you indeed get:
fdf×100=(2020.2+1020.1)×320×100=1%
So, the error in the focal length of the lens is indeed 1% (i.e., n=1).
Q 6PhysicsSection B • Numericalheat and thermodynamics
+4 / -0
A closed container contains a homogeneous mixture of two moles of an ideal monatomic gas (γ=5/3) and one mole of an ideal diatomic gas (γ=7/5). Here, γ is the ratio of the specific heats at constant pressure and constant volume of an ideal gas. The gas mixture does a work of 66 Joule when heated at constant pressure. The change in its internal energy is _______ Joule.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 121
Official Correct Answer:121
Step-by-Step Solution:
First, we identify the heat capacities at constant volume for monatomic and diatomic gases.
For a monatomic ideal gas, the heat capacity at constant volume, Cv1, is (23)R. This comes from the degrees of freedom for a monatomic gas, which are three (x, y, and z motions).
For a diatomic ideal gas, the heat capacity at constant volume, Cv2, is (25)R. This comes from the degrees of freedom for a diatomic gas, which are five (x, y, and z motions and rotation about two axes).
Next, we find the average heat capacity at constant volume for the gas mixture, Cvmix, which is a weighted average based on the number of moles of each gas :
The change in internal energy ΔU for a given number of moles n and change in temperature ΔT is given by :
ΔU=nCvΔT
Given that the work done by the system at constant pressure is :
W=nRΔT
We can replace ΔT=nRW in the equation for ΔU to get :
ΔU=nCvmix×nRW=Cvmix×RW=611R×R66=121Joule
So the change in internal energy is indeed 121 Joule.
Q 7PhysicsSection B • Numericaldual nature of radiation
+4 / -0
A Hydrogen-like atom has atomic number Z. Photons emitted in the electronic transitions from level n=4 to level n=3 in these atoms are used to perform photoelectric effect experiment on a target metal. The maximum kinetic energy of the photoelectrons generated is 1.95eV. If the photoelectric threshold wavelength for the target metal is 310nm, the value of Z is _________.
[Given: hc=1240eV−nm and Rhc=13.6eV, where R is the Rydberg constant, h is the Planck's constant and c is the speed of light in vacuum]
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 3
Official Correct Answer:3
Step-by-Step Solution:
To find the atomic number Z for the hydrogen-like atom emitting photons that cause photoelectrons to eject from the metal surface with a maximum kinetic energy of 1.95eV, we need to make use of the concept of energy transitions in atoms, as well as the photoelectric effect equation. We are given the photoelectric threshold wavelength for the metal and the constants hc and Rhc.
First, let's calculate the energy of the photon emitted during the transition from level n=4 to level n=3 in the hydrogen-like atom. The energy of a photon emitted when an electron transitions between two levels in a hydrogen-like atom is given by :
ΔE=Z2Rhc(n121−n221)
where:
Z is the atomic number.
Rhc is the ionization energy of hydrogen (13.6 eV).
n1 and n2 are the principal quantum numbers of the initial and final energy levels, respectively.
For the transition from n1=4 to n2=3, the energy of the photon is:
ΔE=Z2⋅13.6⋅(321−421)eV
ΔE=Z2⋅13.6⋅(91−161)eV
ΔE=Z2⋅13.6⋅(14416−9)eV
ΔE=Z2⋅13.6⋅1447eV
Next, using the photoelectric effect equation, the maximum kinetic energy (K.E.) of the ejected photoelectrons is equal to the energy of the incident photon minus the work function (ϕ). The work function can be calculated using the given threshold wavelength :
ϕ=λhc
Given:
λ=310nmhc=1240eV⋅nm
So the work function is:
ϕ=3101240eV
ϕ=4eV
The maximum kinetic energy is given by :
K.E.=ΔE−ϕ
We are given K.E.=1.95eV, hence :
1.95=Z2⋅13.6⋅1447−4
⇒Z2⋅13.6⋅1447=1.95+4
⇒Z2=13.6⋅14471.95+4
⇒Z2=13.6×75.95×144
⇒Z2=95.2856.8
⇒Z2=9
⇒Z=9
⇒Z=3
Q 8PhysicsSection A • MCQheat and thermodynamics
+3 / -1
Match the temperature of a black body given in List-I with an appropriate statement in List-II, and choose the correct option.
[Given: Wien's constant as 2.9×10−3m−K and ehc=1.24×10−6V−m ]
List - I
List - II
(P) 2000K
(1) The radiation at peak wavelength can lead to emission of photoelectrons from a metal of work function 4eV.
(Q) 3000K
(2) The radiation at peak wavelength is visible to human eye.
(R) 5000K
(3) The radiation at peak emission wavelength will result in the widest central maximum of a single slit diffraction.
(S) 10000K
(4) The power emitted per unit area is 1/16 of that emitted by a blackbody at temperature 6000K.
(5) The radiation at peak emission wavelength can be used to image human bones.
A
P→3,Q→5,R→2,S→3
B
P→3,Q→2,R→4,S→1
C
P→3,Q→4,R→2,S→1
D
P→1,Q→2,R→5,S→3
Official Correct Answer:Option (C)
Step-by-Step Solution:
λmT=b
For option (P) temperature is minimum hence λm will be maximum.
λm=Tb=20002.9×10−3=1.45×10−6m=1450nm
⇒⇒sinθ=dλ2θ= width of central maximum width ∝λ.maximum width of (P)P→3
⇒ For option (Q),T=3000λm=Tb=300002.9×10−3λm=32.9×10−6=0.96×10−6=966.6nmP3000=6A(3000)4P6000=6A(6000)4P6000P3000=(21)4=161P3000=161P6000Q−4
⇒ For (R),T=5000Kλm=5×1032.9×10−3=0.58×10−6=580nm Visible to human eyes R−2
For (S),T=10,000K
λmT=b⇒λm=10,0002.9×10−3=290nm
ϕ⇒λT=4eV=41240=310nm
To emit photoelectron
λ0<λT⇒S→1
Q 9PhysicsSection B • Numericalimpulse and momentum
+4 / -2
A slide with a frictionless curved surface, which becomes horizontal at its lower end, is fixed on the terrace of a building of height 3h from the ground, as shown in the figure. A spherical ball of mass m is released on the slide from rest at a height h from the top of the terrace. The ball leaves the slide with a velocity u0=u0x^ and falls on the ground at a distance d from the building making an angle θ with the horizontal. It bounces off with a velocity v and reaches a maximum height h1. The acceleration due to gravity is g and the coefficient of restitution of the ground is 1/3. Which of the following statement(s) is(are) correct?
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
Reflect on the scenario of a ball sliding down a frictionless slope. Initially at rest, the ball descends through a height h. Applying the principle of conservation of mechanical energy, we deduce that the initial speed u0 is given by u0=2gh. Consequently, the velocity of the ball as it reaches the end of the slide can be expressed as :
$
\vec{u}_0 = \sqrt{2gh} \, \hat{\imath} .
$
In this scenario where a ball is launched horizontally with an initial speed u0 from the top of a building that is 3h tall, we calculate the time t it takes for the ball to descend the vertical distance of 3h. This time duration can be determined using the equation of motion under gravity, leading to :
$
t = \sqrt{\frac{2(3h)}{g}} = \sqrt{\frac{6h}{g}}.
$
Considering the horizontal distance covered over the time period t, we can express it as :
$
d = u_0 t = \sqrt{2gh} \cdot \sqrt{\frac{6h}{g}} = 2\sqrt{3}h
$ ..............(1)
When the ball impacts the ground, its velocity u comprises two components : a horizontal component ux along ^ and a vertical component uy along ^. The horizontal velocity component remains unchanged throughout the motion and is given by ux=2gh. On the other hand, the vertical velocity component just before the ball hits the ground can be described as :
$
u_y = -\sqrt{2g(3h)} = -\sqrt{6gh}
$
Now, let's focus on the ball's impact with the ground. Since the ground can only exert an impulse in the vertical direction, the horizontal momentum of the ball remains unchanged. This means the horizontal component of the ball's velocity after collision (represented as vcosϕ) is equal to its horizontal velocity component before the collision. Therefore, we can write this relationship as :
$
v \cos \phi = u_x = \sqrt{2gh}
$ ..........(2)
In the vertical axis, the approach velocity, denoted as va, equals the absolute value of uy, which is 6gh. The separation velocity, denoted as vs, is expressed as vsinϕ. Using the coefficient of restitution e, which is defined as 31, we can establish the relationship :
From these two equations (2) and (3), it's clear that vcosϕ and vsinϕ are equal. This equality suggests that ϕ=45∘, as the sine and cosine of 45 degrees are equal.
To find v, we can use either of the two equations. Let's use the first one :
vcos45∘=2gh
Since cos45∘=21, we can rearrange and solve for v:
v=2gh×2=4gh
Thus, ϕ=45∘ and v=4gh.
The ball bounces off with velocity v composed of both horizontal and vertical components, as we have established that both vcosϕ and vsinϕ) are equal to 2gh, and the angle ϕ is 45∘.
In vector form, the velocity of the ball after bouncing can be represented as the sum of its horizontal and vertical components. Given that both components are equal to 2gh and considering the direction of these components along the unit vectors ^ (horizontal) and ^ (vertical), the velocity vector v can be expressed as :
Using the fact that sin45∘ is 21 and simplifying, we find that :
$
h_1 = h = \frac{d}{2\sqrt{3}},
$
where the equation (1) has been applied to establish the relationship.
Q 10PhysicsSection B • Numericalray optics
+4 / -0
An optical arrangement consists of two concave mirrors M1 and M2, and a convex lens L with a common principal axis, as shown in the figure. The focal length of L is 10cm. The radii of curvature of M1 and M2 are 20cm and 24cm, respectively. The distance between L and M2 is 20cm. A point object S is placed at the mid-point between L and M2 on the axis. When the distance between L and M1 is n/7cm, one of the images coincides with S. The value of n is _______.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 80OR150OR220
Official Correct Answer:80OR150OR220
Step-by-Step Solution:
Case-1 : if Ist refraction on lens :
Given that the object is positioned at the focal point, the resulting light rays will transition to a parallel alignment.
Upon the first reflection at Mirror M1:
As the incoming light rays are parallel, the resultant image will be formed at the focal point.
Two point-like objects of masses 20gm and 30gm are fixed at the two ends of a rigid massless rod of length 10cm. This system is suspended vertically from a rigid ceiling using a thin wire attached to its center of mass, as shown in the figure. The resulting torsional pendulum undergoes small oscillations. The torsional constant of the wire is 1.2×10−8Nmrad−1. The angular frequency of the oscillations in n×10−3rads−1. The value of n is _________ .
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 10
If the system is rotated by small angle ' θ ', the restoring torque is τ(R)=−kθ
And dt2d2θ=l−k⋅θ=−ω2θ=1200×10−7−1.2×10−8⋅θ
∴ω2=10−4
So, ω=1001rad/s⇒ω=10×10−3rad/s
Q 12PhysicsSection A • MCQcapacitor
+3 / -1
A container has a base of 50cm×5cm and height 50cm, as shown in the figure. It has two parallel electrically conducting walls each of area 50cm×50cm. The remaining walls of the container are thin and non-conducting. The container is being filled with a liquid of dielectric constant 3 at a uniform rate of 250cm3s−1. What is the value of the capacitance of the container after 10 seconds?
[Given: Permittivity of free space ϵ0=9×10−12C2N−1m−2, the effects of the non-conducting walls on the capacitance are negligible]
Two satellites P and Q are moving in different circular orbits around the Earth (radius R ). The heights of P and Q from the Earth surface are hP and hQ, respectively, where hP=R/3. The accelerations of P and Q due to Earth's gravity are gP and gQ, respectively. If gP/gQ=36/25, what is the value of hQ ?
A
53R
B
6R
C
56R
D
55R
Official Correct Answer:Option (A)
Step-by-Step Solution:
The formula to calculate the acceleration due to gravity at a height ( h ) from the surface of the Earth is expressed as :
g=(Re+h)2GMe
To find the ratio of gravitational acceleration at two different heights ( h_P ) and ( h_Q ) above the Earth's surface, use the formula for each and form a ratio :
Solving for hQ in terms of Re yields hQ=53Re.
Q 14PhysicsSection B • Numericalcapacitor
+4 / -2
In a circuit shown in the figure, the capacitor C is initially uncharged and the key K is open. In this condition, a current of 1A flows through the 1Ω resistor. The key is closed at time t=t0. Which of the following statement(s) is(are) correct?
[Given: e−1=0.36 ]
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
At t<t0,
At t<t0
i1⇒R=1=3+R3R(3+R45)−5=3+4R45−15−5R=3Ω
(A) is correct.
I1=3+43215⇒I1=2A
(B) is correct.
At t>t0
rεr1ε At t→∞q=315+15+30=31+11+31=35=10×53⇒6V=Cε=2×10−6×6=12μC
Time constant τ=RC=(r+3)2μC=(53+3)×12=7.2μsi=i.e−t/τi0=r+3ε=(3+53)6
⇒i=5186×e−7.2/1.2=35×0.36=0.6A
All options are correct.
Q 15PhysicsSection B • Numericalmotion
+4 / -0
A person of height 1.6m is walking away from a lamp post of height 4m along a straight path on the flat ground. The lamp post and the person are always perpendicular to the ground. If the speed of the person is 60cms−1, the speed of the tip of the person's shadow on the ground with respect to the person is ____________ cms−1.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 40
Official Correct Answer:40
Step-by-Step Solution:
Given that dtdx1= speed of person =60cm/s
Also dtdx2= speed of tip of person's shadow
Applying similar triangle rule in △ABE and △DCE
x24=x2−x11.64x2−4x1=1.6x22.4x2=4x1
Differentiate both sides w.r.t. t
2.4dtdx2=4dtdx1dtdx2=2.44(60)=100cm/s
This is the speed of the tip of the person's shadow with respect to the lamp post. But, we need to find the speed of the shadow's tip with respect to the person, which is the relative speed :
vSPvSP=vSG−vPG=100cms−1−60cms−1=40cms−1
Q 16PhysicsSection A • MCQheat and thermodynamics
+3 / -1
One mole of an ideal gas expands adiabatically from an initial state (TA,V0) to final state (Tf,5V0). Another mole of the same gas expands isothermally from a different initial state (TB,V0) to the same final state (Tf,5V0). The ratio of the specific heats at constant pressure and constant volume of this ideal gas is γ. What is the ratio TA/TB ?
A
5γ−1
B
51−γ
C
5γ
D
51+γ
Official Correct Answer:Option (A)
Step-by-Step Solution:
The expansion of an ideal gas can be analyzed using the thermodynamic relations for adiabatic and isothermal processes.
Adiabatic Expansion: For an adiabatic process, we use the relation involving temperatures and volumes at the initial and final states, which is given by :
TVγ−1=constant
Therefore, for the adiabatic expansion from (TA,V0) to (Tf,5V0), we have :
TAV0γ−1=Tf(5V0)γ−1
Simplifying, we get :
TA=Tf×5γ−1
Isothermal Expansion : In an isothermal process, the temperature remains constant. So, TB=Tf for the isothermal expansion from (TB,V0) to (Tf,5V0).
To find the ratio TA/TB, we substitute the expressions for TA and TB :
TBTA=TfTf×5γ−1
TBTA=5γ−1
Therefore, the ratio TA/TB is 5γ−1, which corresponds to Option A.
Q 17PhysicsSection A • MCQelectromagnetic induction
+3 / -1
A thin conducting rod MN of mass 20gm, length 25cm and resistance 10Ω is held on frictionless, long, perfectly conducting vertical rails as shown in the figure. There is a uniform magnetic field B0=4T directed perpendicular to the plane of the rod-rail arrangement. The rod is released from rest at time t=0 and it moves down along the rails. Assume air drag is negligible. Match each quantity in List-I with an appropriate value from List-II, and choose the correct option.
[Given: The acceleration due to gravity g=10ms−2 and e−1=0.4 ]
List - I
List - II
(P) At t=0.2s, the magnitude of the induced emf in Volt
(1) 0.07
(Q) At t=0.2s, the magnitude of the magnetic force in Newton
(2) 0.14
(R) At t=0.2s, the power dissipated as heat in Watt
(3) 1.20
(S) The magnitude of terminal velocity of the rod in ms−1
Q 18ChemistrySection B • Numericalalcohols phenols and ethers
+4 / -2
Consider the following reaction scheme and choose the correct option(s) for the major products Q, R and S.
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
Q 19ChemistrySection A • MCQelectrochemistry
+3 / -1
Plotting 1/Λm against cΛm for aqueous solutions of a monobasic weak acid (HX) resulted in a straight line with y-axis intercept of P and slope of S. The ratio P/S is
Q 20ChemistrySection B • Numericalaldehydes ketones and carboxylic acids
+4 / -2
In the following reactions, P,Q,R, and S are the major products.
The correct statement(s) about P,Q,R, and S is(are) :
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
Q 21ChemistrySection A • MCQionic equilibrium
+3 / -1
On decreasing the pH from 7 to 2 , the solubility of a sparingly soluble salt (MX) of a weak acid (HX) increased from 10−4molL−1 to 10−3molL−1. The pKa of HX is
A
3
B
4
C
5
D
2
Official Correct Answer:Option (B)
Step-by-Step Solution:
Relationship between solubility, H+and Ka is given by
S If pH=7S=Ka(KSP[H+]+Ka)⇒(H+)=10−7=10−4mol/L
A gas has a compressibility factor of 0.5 and a molar volume of 0.4dm3mol−1 at a temperature of 800K and pressure x atm. If it shows ideal gas behaviour at the same temperature and pressure, the molar volume will be ydm3mol−1. The value of x/y is __________.
[Use: Gas constant, R=8×10−2L atm K−1mol−1 ]
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 100
Q 26ChemistrySection B • Numericalchemical equilibrium
+4 / -0
The plot of logkf versus 1/T for a reversible reaction A(g)⇌P(g) is shown.
Pre-exponential factors for the forward and backward reactions are 1015s−1 and 1011s−1, respectively. If the value of logK for the reaction at 500K is 6 , the value of ∣logkb∣ at 250K is ______.
[K= equilibrium constant of the reaction kf= rate constant of forward reaction kb= rate constant of backward reaction ]
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 5
Official Correct Answer:5
Step-by-Step Solution:
For reaction A(g)⇌P(g)
logkf=2.303RT−Ef+logAf [Arrhenius equation for forward reaction]
From plot when, T1=0.002,logkf=9
⇒9=2.303R−Ef(0.002)+log(Af) Given :Af=1015s−1⇒9=2.303R−Ef(0.002)+15⇒2.303REf=0.0026=3000
⇒logkb=2.303RT−Eb+logAb At 250K,⇒logkb=−2504000+log(1011) [From equation (1)] =−16+11=−5∣logkb∣=5
Q 27ChemistrySection A • MCQbasics of organic chemistry
+3 / -1
Match the reactions in List-I with the features of their products in List-II and choose the correct option.
List - I
List - II
(P)
(1) Inversion of configuration
(Q)
(2) Retention of configuration
(R)
(3) Mixture of enantiomers
(S)
(4) Mixture of structural isomers
(5) Mixture of diastereomers
A
P→1;Q→2;R→5;S→3
B
P→2;Q→1;R→3;S→5
C
P→1;Q→2;R→5;S→4
D
P→2;Q→4;R→3;S→5
Official Correct Answer:Option (B)
Step-by-Step Solution:
Q 28ChemistrySection B • Numericalcompounds containing nitrogen
+4 / -0
The total number of sp2 hybridised carbon atoms in the major product P (a non-heterocyclic compound) of the following reaction is ______.
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 28
Official Correct Answer:28
Step-by-Step Solution:
Q 29ChemistrySection B • Numericalthermodynamics
+4 / -0
In a one-litre flask, 6 moles of A undergoes the reaction A(g)⇌P(g). The progress of product formation at two temperatures (in Kelvin), T1 and T2, is shown in the figure:
If T1=2T2 and (ΔG2Θ−ΔG1Θ)=RT2lnx, then the value of x is _______.
[ΔG1Θ and ΔG2Θ are standard Gibb's free energy change for the reaction at temperatures T1 and T2, respectively.]
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 8
Q 30ChemistrySection B • Numericalsome basic concepts of chemistry
+4 / -0
The stoichiometric reaction of 516g of dimethyldichlorosilane with water results in a tetrameric cyclic product X in 75% yield. The weight (in g) of X obtained is _______.
[Use, molar mass (gmol−1):H=1,C=12,O=16,Si=28,Cl=35.5 ]
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 222
Official Correct Answer:222
Step-by-Step Solution:
No. of moles = Molar mass Given mass =129516=4
∴ Percentage yield =10075=0.75∴ Mole formed of cyclic tetramer =0.75∴ Weight =0.75×296=222g
Q 31ChemistrySection B • Numericalthermodynamics
+4 / -0
One mole of an ideal monoatomic gas undergoes two reversible processes (A→B and B→C) as shown in the given figure:
A→B is an adiabatic process. If the total heat absorbed in the entire process (A→B and B→C) is RT2ln10, the value of 2logV3 is _______.
[Use, molar heat capacity of the gas at constant pressure, Cp,m=25R ]
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 7
Q 32ChemistrySection A • MCQalcohols phenols and ethers
+3 / -1
In the given reaction scheme, P is a phenyl alkyl ether, Q is an aromatic compound; R and S are the major products.
The correct statement about S is :
A
It primarily inhibits noradrenaline degrading enzymes.
B
It inhibits the synthesis of prostaglandin.
C
It is a narcotic drug.
D
It is ortho-acetylbenzoic acid.
Official Correct Answer:Option (B)
Step-by-Step Solution:
P is phenyl alkyl ether
Q is aromatic compound
R and S are the major product i.e.
Correct ans is (B)
Aspirin inhibits the synthesis of chemicals known as prostaglandin's.
Q 33ChemistrySection A • MCQaldehydes ketones and carboxylic acids
+3 / -1
The major products obtained from the reactions in List-II are the reactants for the named reactions mentioned in List-I. Match List-I with List-II and choose the correct option.
List - I
List - II
(P) Etard reaction
(1) Acetophenone ⟶Zn−Hg,HCl
(Q) Gattermann reaction
(2) Toluene (ii) SOCl2⟶ (i) KMnO4,KOH,Δ
(R) Gattermann-Koch reaction
(3) Benzene anhyd. AlCl3⟶CH3Cl
(S) Rosenmund reduction
(4) Aniline 273−278K⟶NaNO2/HCl
(5) Phenol ⟶Zn,Δ
A
P→2;Q→4;R→1;S→3
B
P→1;Q→3;R→5;S→2
C
P→3;Q→2;R→1;S→4
D
P→3;Q→4;R→5;S→2
Official Correct Answer:Option (D)
Step-by-Step Solution:
(P)→(3)
(Q)→(4)
(R)→(5)
(S)→(2)
Q 34ChemistrySection A • MCQp block elements
+3 / -1
Match the reactions (in the given stoichiometry of the reactants) in List-I with one of their products given in List-II and choose the correct option.
List - I
List - II
(P) P2O3+3H2O→
(1) P(O)(OCH3)Cl2
(Q) P4+3NaOH+3H2O→
(2) H3PO3
(R) PCl5+CH3COOH→
(3) PH3
(S) H3PO2+2H2O+4AgNO3→
(4) POCl3
(5) H3PO4
A
P→2;Q→3;R→1;S→5
B
P→3;Q→5;R→4;S→2
C
P→5;Q→2;R→1;S→3
D
P→2;Q→3;R→4;S→5
Official Correct Answer:Option (D)
Step-by-Step Solution:
To match the reactions given in List-I with the products in List-II, let's analyze each reaction individually based on its reactants and expected products.
Reaction (P):P2O3+3H2O→ involves the hydration of phosphorus trioxide. The product of this reaction is phosphorous acid:
P2O3+3H2O→2H3PO3
Hence, P matches with (2) H3PO3.
Reaction (Q):P4+3NaOH+3H2O→ involves the reaction of phosphorus with a base (NaOH) and water, leading to the production of phosphine and sodium hypophosphite, not exactly reflected in the products listed, but given the context and possible products, we align with phosphorus chemistry principles. Typically, reactions involving phosphorus and strong bases can generate phosphine:
P4+NaOH+3H2O→PH3+NaH2PO2
Thus, Q matches best with (3) PH3 given the options, acknowledging the simplicity of the given answer choices.
Reaction (R):PCl5+CH3COOH→ involves phosphorus pentachloride and acetic acid. The key reaction here is that PCl5 reacts with CH3COOH to replace OH groups in acetic acid with Cl, creating acetyl chloride CH3COCl and POCl3:
PCl5+CH3COOH→CH3COCl+POCl3
Therefore, R matches with (4) POCl3.
Reaction (S):H3PO2+2H2O+4AgNO3→ involves hypophosphorous acid reacting in an oxidative environment given by silver nitrate, leading to the production of orthophosphoric acid among other products:
H3PO2+2H2O+4AgNO3→H3PO4+Ag+HNO3
S, therefore, matches with (5) H3PO4.
Given these reactions and the best fits for the products listed,
P matches with 2,
Q matches with 3,
R matches with 4,
S matches with 5.
Thus, the correct option is Option D: P→2;Q→3;R→4;S→5.
Q 35MathematicsSection B • Numericalsequences and series
+4 / -0
Let 75⋯5r7 denote the (r+2) digit number where the first and the last digits are 7 and the remaining r digits are 5 . Consider the sum S=77+757+7557+⋯+75⋯5987. If S=n75⋯5997+m, where m and n are natural numbers less than 3000 , then the value of m+n is
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 1219
Consider the given data with frequency distribution
xifi35821131025444
Match each entry in List-I to the correct entries in List-II.
List - I
List - II
(P) The mean of the above data is
(1) 2.5
(Q) The median of the above data is
(2) 5
(R) The mean deviation about the mean of the above data is
(3) 6
(S) The mean deviation about the median of the above data is
(4) 2.7
(5) 2.4
The correct option is:
A
(P)→(3)(Q)→(2)(R)→(4)(S)→(5)
B
(P)→(3)(Q)→(2)(R)→(1)(S)→(5)
C
(P)→(2)(Q)→(3)(R)→(4)(S)→(1)
D
(P)→(3)(Q)→(3)(R)→(5)(S)→(5)
Official Correct Answer:Option (A)
Step-by-Step Solution:
x134581011fi544223Σfi=20fixi151620162033Σfixi=120fi∣xi−xˉ∣15844815 sum =54fi∣xi−N∣104061018 sum =48
(P) Mean =ΣfiΣfixi=20120=6
(Q)
Median =2(10th +11th ) observation =25+5=5
(both observation are same)
(R) Mean deviation
=ΣfiΣfi∣xi−xˉ∣=2054=2.7
(S) Mean deviation about median
=ΣfiΣfi∣xi−M∣=2048=2.4
Q 37MathematicsSection B • Numericalellipse
+4 / -2
Let T1 and T2 be two distinct common tangents to the ellipse E:6x2+3y2=1 and the parabola P:y2=12x. Suppose that the tangent T1 touches P and E at the points A1 and A2, respectively and the tangent T2 touches P and E at the points A4 and A3, respectively. Then which of the following statements is(are) true?
⇒ Equation of common tangents y=x+3 and y=−x−3 point of contact for parabola is (m2a,m2a)
⇒A1≡(3,6),A4(3−6)
Let A2(x1,y1)⇒ tangent to E is 6xx1+3yy1=1
A3 is mirror image of A2 in x-axis ⇒A3(−2,−1)
Intersection point of T1=0 and T2=0 is (−3,0)
Area of quadrilateral A1A2A3A4=21(12+2)×5=35 square units
Q 38MathematicsSection B • Numericalinverse trigonometric functions
+4 / -0
Let tan−1(x)∈(−2π,2π), for x∈R. Then the number of real solutions of the equation 1+cos(2x)=2tan−1(tanx) in the set (−23π,−2π)∪(−2π,2π)∪(2π,23π) is equal to :
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 3
Let X={(x,y)∈Z×Z:8x2+20y2<1 and y2<5x}. Three distinct points P,Q and R are randomly chosen from X. Then the probability that P,Q and R form a triangle whose area is a positive integer, is :
A
22071
B
22073
C
22079
D
22083
Official Correct Answer:Option (B)
Step-by-Step Solution:
8x2+20y2<1 and y2<5x
Let 8x2+20y2=1 ........(1)
and
y2=5x .........(2)
On solving (1) and (2), we get
8x2+205x=18x2+4x=1
x2+2x=8⇒x2+2x−8=0Rightarrow(x+4)(x−2)=0⇒x=−4,2⇒x=2(−4 is not possible )⇒y2=10⇒y=±10
Re(A)=49+9cos2θ281(49−9sin2θ)=49+9×54281(49−9×5−4)=281(+ ve integer )
Q 41MathematicsSection B • Numericalapplication of integration
+4 / -0
Let n≥2 be a natural number and f:[0,1]→R be the function defined by
f(x)=⎩⎨⎧n(1−2nx)2n(2nx−1)4n(1−nx)n−1n(nx−1) if 0≤x≤2n1 if 2n1≤x≤4n3 if 4n3≤x≤n1 if n1≤x≤1
If n is such that the area of the region bounded by the curves x=0,x=1,y=0 and y=f(x) is 4 , then the maximum value of the function f is :
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 8
Official Correct Answer:8
Step-by-Step Solution:
f(x) is decreasing in [0,2n1]
increasing in [2n1,4n3]
decreasing in [4n3,n1]
increasing in [n1,1]
Area 444n=21×2n1×n+21×2n1×n+21×(1−n1)×n=41+41+2n−1=21+2n−1=2n=8
Q 42MathematicsSection A • MCQapplication of derivatives
+3 / -1
Let Q be the cube with the set of vertices {(x1,x2,x3)∈R3:x1,x2,x3∈{0,1}}. Let F be the set of all twelve lines containing the diagonals of the six faces of the cube Q. Let S be the set of all four lines containing the main diagonals of the cube Q; for instance, the line passing through the vertices (0,0,0) and (1,1,1) is in S. For lines ℓ1 and ℓ2, let d(ℓ1,ℓ2) denote the shortest distance between them. Then the maximum value of d(ℓ1,ℓ2), as ℓ1 varies over F and ℓ2 varies over S, is :
A
61
B
81
C
31
D
121
Official Correct Answer:Option (A)
Step-by-Step Solution:
DR′S of OG=1,1,1
DR'S of AF =−1,1,1
DR'S of CE = 1, 1, -1
DR′S of BD=1,−1,1
Equation of OG⇒1x=1y=1z
Equation of AB⇒1x−1=−1y=0z
Normal to both the line's
=i^11j^1−1k^10=i^+j^−2k^
OA=i^
S.D. =∣i^+j^−2k^∣∣i^⋅(i^+j^−2k^)∣=61
Q 43MathematicsSection B • Numericalfunctions
+4 / -2
Let f:[0,1]→[0,1] be the function defined by f(x)=3x3−x2+95x+3617. Consider the square region S=[0,1]×[0,1]. Let G={(x,y)∈S:y>f(x)} be called the green region and R={(x,y)∈S:y<f(x)} be called the red region. Let Lh={(x,h)∈S:x∈[0,1]} be the horizontal line drawn at a height h∈[0,1]. Then which of the following statements is(are) true?
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
Given f:[0,1]f(x)f′(x)→[0,1]=3x3−x2+95x+3617=33x2−2x+95
f′(x)=09x2−18x+5=0⇒9x2−15x−3x+5=0⇒3x(3x−5)−1(3x−5)=0⇒(3x−5)(3x−1)=0⇒x=31 or 35f′′(x)=2x−2f′′(31)=32−2<0 point of maxima
Area red ∴( Area )green =∫01f(x)dx=[12x4−3x3+185x2+3617x]01=121−31+185+3617=363−12+10+17=3618=21=0.5=1−21=0.5
(A) 1−h=h−21⇒h=43,43>32 option (A) is incorrect
∴z=1±i3⇒z−z=±2i3⇒∣z−z∣=23⇒∣z−z∣2=12 Now z+1=2+i3∣z+1∣2=4+3=7∴P→2;Q→1;R→3;S→5∴ Option [B] is correct.
Q 45MathematicsSection A • MCQ3d geometry
+3 / -1
Let ℓ1 and ℓ2 be the lines r1=λ(i^+j^+k^) and r2=(j^−k^)+μ(i^+k^), respectively. Let X be the set of all the planes H that contain the line ℓ1. For a plane H, let d(H) denote the smallest possible distance between the points of ℓ2 and H. Let H0 be a plane in X for which d(H0) is the maximum value of d(H) as H varies over all planes in X.
Match each entry in List-I to the correct entries in List-II.
List - I
List - II
(P) The value of d(H0) is
(1) 3
(Q) The distance of the point (0,1,2) from H0 is
(2) 31
(R) The distance of origin from H0 is
(3) 0
(S) The distance of origin from the point of intersection of planes y=z,x=1 and H0 is
(4) 2
(5) 21
The correct option is:
A
(P)→(2)(Q)→(4)(R)→(5)(S)→(1)
B
(P)→(5)(Q)→(4)(R)→(3)(S)→(1)
C
(P)→(2)(Q)→(1)(R)→(3)(S)→(2)
D
(P)→(5)(Q)→(1)(R)→(4)(S)→(2)
Official Correct Answer:Option (B)
Step-by-Step Solution:
l1:r=λ(i^+j^+k^)l2:r=j^−k^+μ(i^+k^) For plane
d(H)= Smallest possible distance between the points of l2 and Plane.
d(H0)= Maximum value of d(H)
For d(H0)
l2 is Parallel to plane containing l1
Equation of plane
a(x)+by+cz=0
∵ It contain l1
∴a+b+c=0 ..........(1)
For largest possible distance between plane (1) and l2 the line l2 must be parallel to plane (1)
∴a+c=0 .........(2)
By (1) and (2) a=−c,b=0
∴ Equation of plane x−z=0
(P) d(H0)=PM=1+10−(−1)=21
(Q) Distance from (0,1,2)
=20−2=2
(R) Distance from origin (0,0,0)
=20=0
(S) Point of Intersection,
x−z=0
and
x=1,y=z∴x=1=z=y
∴ Point of intersection (1,1,1) Distance from origin
=12+12+12=3
Q 46MathematicsSection B • Numericalmathematical induction and binomial theorem
+4 / -0
Let a and b be two nonzero real numbers. If the coefficient of x5 in the expansion of (ax2+27bx70)4 is equal to the coefficient of x−5 in the expansion of (ax−bx21)7, then the value of 2b is :
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 3
For no solution Δ=0 and atleast one in Δx,Δy,Δz is non zero.
Δ=0
⇒β=21(7α−3)
(P) β=21(7α−3) and γ=28
then Δ=0,Δx=Δy=Δz=0
∴ Infinite solution
(Q) β=21(7α−3) and γ=28
∴Δ=0 and Δ2=0
⇒ No solution.
(R) β=21(7α−3),α=1,γ=28⇒Δ=0= unique solution (S) β=21(7α−3),α=1,γ=28∴Δ=0,Δ=4−2βΔx=44−22βΔy=4β−8Δz=0
∴x=11,y=−2,z=0 is the solution.
Q 48MathematicsSection B • Numericalvector algebra
+4 / -0
Let P be the plane 3x+2y+3z=16 and let
S={αi^+βj^+γk^:α2+β2+γ2=1 and the distance of (α,β,γ) from the plane P is 27}.
Let u,v and w be three distinct vectors in S such that ∣u−v∣=∣v−w∣=∣w−u∣. Let V be the volume of the parallelepiped determined by vectors u,v and w. Then the value of 380V is :
Answer Format:Enter numerical value rounded to the nearest integerOfficial Answer: 45
u,v,w are elements of set S and in set S magnitude of vector is 1
∴u,v,w are unit vectors and by equation (1) we can system u,v,w are equally inclined and vertices of equilateral triangle also lying on a circle which is intersection of sphere ∣r∣=1
Distance from origin to P,
d=3+4+9∣−16∣=416=4
∴ Plane containing u^,v^,w^ are at a distance
4−27=21 from origin and Parallel to 3x+2y+3z=16.
∴ Equation of the plane is
3x+2y+3z∴21=4γ⇒γ=±23x+2y+3z=2=γ
Equation of sphere x2+y2+z2=1
∴ Radius or circle
r then 2aa=1−41=23=23cos30∘=3×23=23
∴ Area or triangle
=23a2=23×49=1693
∴ Volume of Parallelepiped
V=2×21×1693=1693
∴ Volume of Parallelepiped
=V2×21×1693=1693
∴380V=380×1693=45
Q 49MathematicsSection A • MCQparabola
+3 / -1
Let P be a point on the parabola y2=4ax, where a>0. The normal to the parabola at P meets the x-axis at a point Q. The area of the triangle PFQ, where F is the focus of the parabola, is 120 . If the slope m of the normal and a are both positive integers, then the pair (a,m) is
A
(2,3)
B
(1,3)
C
(2,4)
D
(3,4)
Official Correct Answer:Option (A)
Step-by-Step Solution:
y2=4ax
Equation of normal
y=mx−2am−am3
Point of contact
P(am2,−2am)
and Point Q(2a+am2,0)
Area of
△PFQ120a=21×a+am2∣−2am∣=a2(1+m2)m=2,m=3
Satisfies the equation (1), hence (2,3) will be the correct answer.
Q 50MathematicsSection B • Numericalfunctions
+4 / -2
Let S=(0,1)∪(1,2)∪(3,4) and T={0,1,2,3}. Then which of the following statements is(are) true?
Official Correct Answer:Declared in Solution
Step-by-Step Solution:
S=(0,1)∪(1,2)∪(3,4) and T={0,1,2,3}.
Let domain and co-domain of a function y=f(x) are S and T respectively.
(A) There are infinitely many elements in domain and four elements in co-domain.
⇒ There are infinitely many functions from S to T.
⇒ Option (A) is correct
(B) If number of elements in domain is greater than number of elements in co-domain, then number of strictly increasing function is zero.
⇒ Option (B) is incorrect
(C) Maximum number of continuous functions = 4×4×4=64
(Every subset (0,1),(1,2),(3,4) has four choices)
∵64<120⇒ option (C) is correct.
(D) For every point at which f(x) is continuous, f(x)=0
⇒ Every continuous function from S to T is differentiable.
Option (D) is correct.
Q 51MathematicsSection A • MCQdefinite integration
+3 / -1
Let f:(0,1)→R be the function defined as f(x)=n if x∈[n+11,n1) where n∈N. Let g:(0,1)→R be a function such that x2∫xt1−tdt<g(x)<2x for all x∈(0,1).
Then x→0limf(x)g(x)