

Official solved question paper for Joint Entrance Examination (Advanced). Review all 54 questions, official answer keys, and detailed step-by-step solutions below, or attempt online with timer and negative marking.











The nitrogen containing compound produced in the reaction of HNO3 with P4O10
Treatment of compound O with KMnO4/H+ gave P, which on heating with ammonia gave Q. The compound Q on treatment with Br2/NaOH produced R. On strong heating, Q gave S, which on further treatment with ethyl 2-bromopropanoate in the presence of KOH following by acidification, gave a compound T.

The compound T is
The correct order of acidity for the following compounds is

For "invert sugar", the correct statement(s) is(are)
(Given : specific rotations of (+)-sucrose, (+)-maltose, L-()-glucose and L-(+)-fructose in aqueous solution are +66, +140, 52 and +92, respectively.)
In the following reaction, sequence in aqueous solution, the species X, Y and Z, respectively, are
{S_2}O_3^{2 - }\buildrel {A{g^ + }} \over \longrightarrow \mathop X\limits_{Clear\,solution} \buildrel {A{g^ + }} \over \longrightarrow \mathop Y\limits_{White\,precipitate} \buildrel {With\,time} \over \longrightarrow \mathop Z\limits_{Black\,precipitate}
Among the following reaction(s), which gives(give) tert-butyl benzene as the major product is(are)
Treatment of compound O with KMnO4/H+ gave P, which on heating with ammonia gave Q. The compound Q on treatment with Br2/NaOH produced R. On strong heating, Q gave S, which on further treatment with ethyl 2-bromopropanoate in the presence of KOH following by acidification, gave a compound T.

The compound R is




The qualitative sketches I, II and III given below show the variation of surface tension with molar concentration of three different aqueous solutions of KCl, CH3OH and CH3(CH2)11 OSO Na+ at room temperature. The correct assignment of the sketches is

I : KCl
II : CH3OH
III : CH3(CH2)11 OSO Na+
I. CH3(CH2)11 OSO Na+
II. CH3OH
III. KCl
I. KCl
II. CH3(CH2)11 OSO Na+
III. CH3OH
I. CH3OH
II. KCl
III. CH3(CH2)11 OSO Na+
The value of x is
Reagent(s) which can be used to bring about the following transformation is(are)

The major product of the following reaction sequence is:





The orthocentre of the triangle is
is
Let and be function defined by and , where [y] denotes the greatest integer less than or equal to y for . Then
If the tangents to the ellipse at and meet at and the normal to the parabola at meets the -axis at , then the ratio of area of the triangle to area of the quadrilateral is
Let P = \left[ {\matrix{ 1 & 0 & 0 \cr 4 & 1 & 0 \cr {16} & 4 & 1 \cr } } \right] and I be the identity matrix of order 3. If is a matrix such that and equals
Let bi > 1 for I = 1, 2, ......, 101. Suppose logeb1, logeb2, ......., logeb101 are in Arithmetic Progression (A.P.) with the common difference loge2. Suppose a1, a2, ......, a101 are in A.P. such that a1 = b1 and a51 = b51. If t = b1 + b2 + .... + b51 and s = a1 + a2 + ..... + a51, then
Let a, b R and f : R R be defined by . Then f is
is
Let a, , m R. Consider the system of linear equations
ax + 2y =
3x 2y =
Which of the following statements is(are) correct?